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Volumn 121, Issue 1, 1999, Pages 14-27

Conformational control of intramolecular electron transfer in calix[4]diquinones and their cationic complexes

Author keywords

[No Author keywords available]

Indexed keywords

BARIUM PERCHLORATE; CATION; QUINONE DERIVATIVE; RUTHENIUM COMPLEX;

EID: 0033550506     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982786v     Document Type: Article
Times cited : (58)

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    • The rate of charge recombination becomes much slower in nonpolar solvents, such as benzene, because of the increased driving force and reduced reorganization energy. For details, see: Mataga, N.; Miyasaka, H. Prog. React. Kinet. 1994, 19, 317.
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    • In fluid solution, it is often considered that bimolecular electron transfer proceeds only at orbital contact, by way of a precursor complex, but recent models indicate that noncontact electron transfer cannot be neglected. For details, see: Burshtein, A. I.; Shokhirev, N. V. J. Phys. Chem. A 1997, 101, 25.
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    • note
    • T) is likely to be much closer to the apex of a Marcus rate vs energy-gap plot. Solely on thermodynamic grounds, complexation of barium perchlorate is expected to increase the rate of forward electron transfer but decrease the rate of charge recombination. This behavior is not observed experimentally.
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    • note
    • Structural studies were not attempted with these other cations, but it is known that complexation of sodium to calix[4]diquinones favors the cone conformation. See refs 62 and 64 for details.
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    • note
    • The nature of any other ligands bound to zinc(II) is unknown, and it is important to stress that trace amounts of water are present in the system since the salt is hydrated.
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    • 3Cl], and it was found that complexation of barium perchlorate caused an increase in the rate of light-induced electron transfer. See ref 67 for details.


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