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Recent reviews see: a) P. J. Stang, V. V. Zhdankin, Chem. Rev. 1996, 96, 1123-1178; b) A. Varvoglis, Hypervalent Iodine in Organic Synthesis, Academic Press, San Diego, 1997; c) T. Kitamura, Y. Fujiwara, Org. Prep. Proc. Int. 1997, 29, 409-458; d) T. Wirth, U. H. Hirt, Synthesis 1999, 1271-1287.
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Recent reviews see: a) P. J. Stang, V. V. Zhdankin, Chem. Rev. 1996, 96, 1123-1178; b) A. Varvoglis, Hypervalent Iodine in Organic Synthesis, Academic Press, San Diego, 1997; c) T. Kitamura, Y. Fujiwara, Org. Prep. Proc. Int. 1997, 29, 409-458; d) T. Wirth, U. H. Hirt, Synthesis 1999, 1271-1287.
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18
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0000247985
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Our recent work: a) Y. Kita, H. Tohma, K. Hatanaka, T. Takada, S. Fujita, S. Mitoh, H. Sakurai, S. Oka, J. Am. Chem. Soc. 1994, 116, 3684-3691; b) Y. Kita, M. Arisawa, M. Gyoten, M. Nakajima, R. Hamada, H. Tohma, T. Takada, J. Org. Chem. 1998, 63, 6625-6633; c) T. Takada, M. Arisawa, M. Gyoten, R. Hamada, H. Tohma, Y. Kita, J. Org. Chem. 1998, 63, 7698-7706; d) Y. Kita, M. Egi, T. Takada, H. Tohma, Synthesis 1999, 885-897; e) M. Arisawa, S. Utsumi, M. Nakajima, N. G. Ramesh, H. Tohma, Y. Kita, Chem. Commun. 1999, 469-470, and references cited therein.
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19
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Our recent work: a) Y. Kita, H. Tohma, K. Hatanaka, T. Takada, S. Fujita, S. Mitoh, H. Sakurai, S. Oka, J. Am. Chem. Soc. 1994, 116, 3684-3691; b) Y. Kita, M. Arisawa, M. Gyoten, M. Nakajima, R. Hamada, H. Tohma, T. Takada, J. Org. Chem. 1998, 63, 6625-6633; c) T. Takada, M. Arisawa, M. Gyoten, R. Hamada, H. Tohma, Y. Kita, J. Org. Chem. 1998, 63, 7698-7706; d) Y. Kita, M. Egi, T. Takada, H. Tohma, Synthesis 1999, 885-897; e) M. Arisawa, S. Utsumi, M. Nakajima, N. G. Ramesh, H. Tohma, Y. Kita, Chem. Commun. 1999, 469-470, and references cited therein.
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Our recent work: a) Y. Kita, H. Tohma, K. Hatanaka, T. Takada, S. Fujita, S. Mitoh, H. Sakurai, S. Oka, J. Am. Chem. Soc. 1994, 116, 3684-3691; b) Y. Kita, M. Arisawa, M. Gyoten, M. Nakajima, R. Hamada, H. Tohma, T. Takada, J. Org. Chem. 1998, 63, 6625-6633; c) T. Takada, M. Arisawa, M. Gyoten, R. Hamada, H. Tohma, Y. Kita, J. Org. Chem. 1998, 63, 7698-7706; d) Y. Kita, M. Egi, T. Takada, H. Tohma, Synthesis 1999, 885-897; e) M. Arisawa, S. Utsumi, M. Nakajima, N. G. Ramesh, H. Tohma, Y. Kita, Chem. Commun. 1999, 469-470, and references cited therein.
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Synthesis
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and references cited therein
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Our recent work: a) Y. Kita, H. Tohma, K. Hatanaka, T. Takada, S. Fujita, S. Mitoh, H. Sakurai, S. Oka, J. Am. Chem. Soc. 1994, 116, 3684-3691; b) Y. Kita, M. Arisawa, M. Gyoten, M. Nakajima, R. Hamada, H. Tohma, T. Takada, J. Org. Chem. 1998, 63, 6625-6633; c) T. Takada, M. Arisawa, M. Gyoten, R. Hamada, H. Tohma, Y. Kita, J. Org. Chem. 1998, 63, 7698-7706; d) Y. Kita, M. Egi, T. Takada, H. Tohma, Synthesis 1999, 885-897; e) M. Arisawa, S. Utsumi, M. Nakajima, N. G. Ramesh, H. Tohma, Y. Kita, Chem. Commun. 1999, 469-470, and references cited therein.
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The reaction took longer (24 h) to complete when the concentration of 1u in water was 0.2 M
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The reaction took longer (24 h) to complete when the concentration of 1u in water was 0.2 M.
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The method for preparing PDAIS was originally reported by Okawara in 1961, and was also reported independently by Hallensleben; a) M. Okawara, K. Mizuta, Kogyo Kagaku Zasshi 1961, 64, 232-235; b) Y. Yamada, M. Okawara, Makromol. Chem. 1972, 152, 153-162; c) M. L. Hallensleben, Angew. Makromol. Chem. 1972, 27, 223-227.
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Even after stirring PDAIS in water for 4 days, the addition of 1e and KBr to this suspension gave 2e in 68% yield
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Even after stirring PDAIS in water for 4 days, the addition of 1e and KBr to this suspension gave 2e in 68% yield.
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note
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