Stable polymer-bound iodine azide

Angewandte Chemie - International Edition

Volumn 38, Issue 17, 1999, Pages 2594-2596

  Kirschning, Andreas ^a   Monenschein, Holger ^a   Schmeck, Carsten ^b  

^a CLAUSTHAL UNIVERSITY OF TECHNOLOGY   (Germany)

^b BAYER AG   (Germany)

Author keywords

Alkenes; Azides; Electrophilic additions; Polymer supported reagents; Synthetic methods

Indexed keywords

AZIDE; IODINE DERIVATIVE; POLYMER;

ARTICLE; CHEMICAL BOND; ELECTRON TRANSPORT; INFRARED SPECTROMETRY; IODINATION; ISOLATION PROCEDURE; ISOMER; LIGAND BINDING; NUCLEAR OVERHAUSER EFFECT; REACTION ANALYSIS; STEREOSPECIFICITY; STOICHIOMETRY; SYNTHESIS;

EID: 0033520316     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990903)38:17<2594::AID-ANIE2594>3.0.CO;2-U     Document Type: Article

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32. Most β-iodoazides described in Table 1 were conveniently prepared by means of automated parallel synthesis.
33. In fact, in some cases we observed that aqueous work-up led to back reaction of the β-iodoazides to the starting alkenes, an obstacle which is completely avoided when employing our new polymer-bound reagent 3a.
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