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Volumn 43, Issue 23, 2004, Pages 7389-7395

Modulation of molybdenum-centered redox potentials and electron-transfer rates by sulfur versus oxygen ligation

Author keywords

[No Author keywords available]

Indexed keywords

MOLYBDENUM COMPLEX; OXYGEN; SULFUR;

EID: 8644265342     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic040082i     Document Type: Article
Times cited : (17)

References (58)
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    • Organic peroxide and perester reduction: (a) Donkers, R. L.; Maran, F.; Wayner, D. D. M.; Workentin, M. S. J. Am. Chem. Soc. 1999, 121, 7239. (b) Antonello, S.; Formaggio, F.; Moretto, A.; Toniolo, C.; Maran, F. J. Am. Chem. Soc. 2001, 123, 9577.
    • (1999) J. Am. Chem. Soc. , vol.121 , pp. 7239
    • Donkers, R.L.1    Maran, F.2    Wayner, D.D.M.3    Workentin, M.S.4
  • 28
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    • Compton, R. G., Ed.; Elsevier: Amsterdam
    • (b) Weaver, M. J. In Comprehensive Chemical Kinetics; Compton, R. G., Ed.; Elsevier: Amsterdam, 1987; Vol. 27, pp 1-60.
    • (1987) Comprehensive Chemical Kinetics , vol.27 , pp. 1-60
    • Weaver, M.J.1
  • 41
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    • For comparison of O versus S ligation see: (a) Bond, A. M.; Martin, R. L.; Masters, A. F. J. Electroanal. Chem. 1976, 72, 187. (b) Schultz, F. A.; Ott, V. R.; Rolison, D. S.; Bravard, D. C.; McDonald, J. W.; Newton, W. E. Inorg. Chem. 1978, 17, 1758. (c) Lukat, G. S.; Kurtz, D. M., Jr. Biochemistry 1985, 24, 3464. (d) Reference 8b.
    • (1976) J. Electroanal. Chem. , vol.72 , pp. 187
    • Bond, A.M.1    Martin, R.L.2    Masters, A.F.3
  • 42
    • 33947092853 scopus 로고
    • For comparison of O versus S ligation see: (a) Bond, A. M.; Martin, R. L.; Masters, A. F. J. Electroanal. Chem. 1976, 72, 187. (b) Schultz, F. A.; Ott, V. R.; Rolison, D. S.; Bravard, D. C.; McDonald, J. W.; Newton, W. E. Inorg. Chem. 1978, 17, 1758. (c) Lukat, G. S.; Kurtz, D. M., Jr. Biochemistry 1985, 24, 3464. (d) Reference 8b.
    • (1978) Inorg. Chem. , vol.17 , pp. 1758
    • Schultz, F.A.1    Ott, V.R.2    Rolison, D.S.3    Bravard, D.C.4    McDonald, J.W.5    Newton, W.E.6
  • 43
    • 0021837827 scopus 로고
    • For comparison of O versus S ligation see: (a) Bond, A. M.; Martin, R. L.; Masters, A. F. J. Electroanal. Chem. 1976, 72, 187. (b) Schultz, F. A.; Ott, V. R.; Rolison, D. S.; Bravard, D. C.; McDonald, J. W.; Newton, W. E. Inorg. Chem. 1978, 17, 1758. (c) Lukat, G. S.; Kurtz, D. M., Jr. Biochemistry 1985, 24, 3464. (d) Reference 8b.
    • (1985) Biochemistry , vol.24 , pp. 3464
    • Lukat, G.S.1    Kurtz Jr., D.M.2
  • 44
    • 6844266957 scopus 로고    scopus 로고
    • Reference 8b
    • For comparison of O versus S ligation see: (a) Bond, A. M.; Martin, R. L.; Masters, A. F. J. Electroanal. Chem. 1976, 72, 187. (b) Schultz, F. A.; Ott, V. R.; Rolison, D. S.; Bravard, D. C.; McDonald, J. W.; Newton, W. E. Inorg. Chem. 1978, 17, 1758. (c) Lukat, G. S.; Kurtz, D. M., Jr. Biochemistry 1985, 24, 3464. (d) Reference 8b.
  • 45
    • 0020766701 scopus 로고    scopus 로고
    • For comparison of aromatic versus aliphatic ligand frameworks see: (a) Hagen, K. S.; Watson, A. D.; Holm, R. H. J. Am. Chem. Soc. 1983, 105, 3905. (b) Zanello, P. Coord. Chem. Rev. 1988, 87, 1. (c) Reference 8a.
    • (1983) J. Am. Chem. Soc. , vol.105 , pp. 3905
    • Hagen, K.S.1    Watson, A.D.2    Holm, R.H.3
  • 46
    • 33749085218 scopus 로고
    • For comparison of aromatic versus aliphatic ligand frameworks see: (a) Hagen, K. S.; Watson, A. D.; Holm, R. H. J. Am. Chem. Soc. 1983, 105, 3905. (b) Zanello, P. Coord. Chem. Rev. 1988, 87, 1. (c) Reference 8a.
    • (1988) Coord. Chem. Rev. , vol.87 , pp. 1
    • Zanello, P.1
  • 47
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    • Reference 8a
    • For comparison of aromatic versus aliphatic ligand frameworks see: (a) Hagen, K. S.; Watson, A. D.; Holm, R. H. J. Am. Chem. Soc. 1983, 105, 3905. (b) Zanello, P. Coord. Chem. Rev. 1988, 87, 1. (c) Reference 8a.
  • 54
    • 8644259315 scopus 로고    scopus 로고
    • note
    • xy orbital, which speaks against a highly localized model of inner-shell reorganization.
  • 56
    • 0037191855 scopus 로고    scopus 로고
    • 0/2- (M = Mo, W), and surmise that a parallel explanation may apply in this case: Uhrhammer, D.; Schultz, F. A. J. Phys. Chem. A 2002, 106, 11630.
    • (2002) J. Phys. Chem. A , vol.106 , pp. 11630
    • Uhrhammer, D.1    Schultz, F.A.2
  • 57
    • 8644280558 scopus 로고    scopus 로고
    • note
    • ‡ in eq 3) is near zero (ref 16b).


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