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Volumn 126, Issue 16, 2004, Pages 5119-5129

Photoelectron Spectroscopy of the Doubly-Charged Anions [M IVO(mnt)2]2- (M = Mo, W; mnt = S 2C2(CN)22-): Access to the Ground and Excited States of the [MVO(mnt)2]- Anion

Author keywords

[No Author keywords available]

Indexed keywords

BINDING ENERGY; CHARGE TRANSFER; COMPLEXATION; ELECTRON ENERGY LEVELS; ELECTRONIC STRUCTURE; ENZYMES; PHOTOELECTRON SPECTROSCOPY;

EID: 1942456787     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039652o     Document Type: Article
Times cited : (26)

References (85)
  • 1
    • 0004186170 scopus 로고    scopus 로고
    • Sigel, A., Sigel, H., Eds.: Metal Ions in Biological Systems 39: Marcel Dekker: New York
    • Molybdenum and Tungsten, Their Roles in Biological Processes; Sigel, A., Sigel, H., Eds.: Metal Ions in Biological Systems 39: Marcel Dekker: New York, 2002.
    • (2002) Molybdenum and Tungsten, Their Roles in Biological Processes
  • 2
    • 0000273676 scopus 로고    scopus 로고
    • Hille, R. Chem. Rev. 1996, 96, 2757-2816.
    • (1996) Chem. Rev. , vol.96 , pp. 2757-2816
    • Hille, R.1
  • 7
    • 0003521768 scopus 로고    scopus 로고
    • Biomimetic Chemistry of Molybdenum
    • Meunier, B., Ed.; Imperial College Press: London
    • Young, C. G. Biomimetic Chemistry of Molybdenum. In Biomimetic Oxidations Catalyzed by Transition Metal Complexes; Meunier, B., Ed.; Imperial College Press: London, 2000; pp 415-459.
    • (2000) Biomimetic Oxidations Catalyzed by Transition Metal Complexes , pp. 415-459
    • Young, C.G.1
  • 47
    • 0036441190 scopus 로고    scopus 로고
    • and ref 51
    • 2- is approximately -0.7 eV, suggesting that this dianion is likely to be thermodynamically unstable with respect to electron autodetachment. This is true for many multiply charged anions that are stabilized in solution by solvation. See, for example: Dreuw, A.; Cederbaum, L. S. Chem. Rev. 2002, 102, 181 and ref 51.
    • (2002) Chem. Rev. , vol.102 , pp. 181
    • Dreuw, A.1    Cederbaum, L.S.2
  • 51
    • 1942524782 scopus 로고    scopus 로고
    • note
    • xy.
  • 80
    • 1942428491 scopus 로고    scopus 로고
    • See also ref 37
    • (b) See also ref 37.
  • 81
    • 1942428493 scopus 로고    scopus 로고
    • note
    • -, refs 12, 22.
  • 82
    • 1942524784 scopus 로고    scopus 로고
    • note
    • + (M = Mo, W; dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate); see ref 67d.
  • 83
    • 1942492785 scopus 로고    scopus 로고
    • note
    • ip(nb) (ip = in-plane, nb = nonbonding). This orbital has been relabeled under the coordinate system and nomenclature of the present study.
  • 84
    • 1942492786 scopus 로고    scopus 로고
    • note
    • -; ref 29.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.