Evaluation of molybdenum-sulfur interactions in molybdoenzyme model complexes by gas-phase photoelectron spectroscopy. The 'electronic buffer' effect

Journal of the American Chemical Society

Volumn 120, Issue 14, 1998, Pages 3382-3386

  Westcott, Barry L ^a,b   Gruhn, Nadine E ^b   Enemark, John H ^b  

^a CENTRAL CONNECTICUT STATE UNIVERSITY   (United States)

^b University of Arizona ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BUFFER; ENZYME; MOLYBDENUM; MOLYBDENUM COMPLEX; SULFUR;

ARTICLE; COMPLEX FORMATION; GAS; IONIZATION; OXIDATION; PHYSICAL PHASE; SPECTROSCOPY;

EID: 0032522216     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja972674o     Document Type: Article

References (31)

1. Kisker, C.; Schindelin, H.; Rees, D. C. Annu. Rev. Biochem. 1997, 66, 233.
2. Rees, D. C.; Younglin, H.; Kisker, C.; Schindelin, H. J. Chem. Soc., Dalton Trans. 1997, 3909-3914.
3. Hille, R. Chem. Rev. 1996, 96, 2757.
4. The term ene-dithiolates is meant to specifically denote ene-1,2-dithiolates, which are also frequently called dithiolenes. For a more detailed discussion of this nomenclature and that for the associated pterin (molybdopterin) in molybdoenzymes, see: Stiefel, E. I. J. Chem. Soc., Dalton Trans. 1997, 3915-3923.
5. Rajagopalan, K. V. Adv. Enzymol. Relat. Areas Mol. Biol. 1991, 64, 215-289.
6. Kisker, C.; Schindelin, H.; Pacheco, A.; Wehbi, W.; Garrett, R. M.; Rajagopalan, K. V.; Enemark, J. H.; Rees, D. C. Cell 1997, 91, 973-983.
7. Kubas, G. J.; Ryan, R. R.; Swanson, B. I.; Vergamini, P. J.; Wasserman, H. J. J. Am. Chem. Soc. 1986, 108, 1000.
8. Chevrel, R.; Hirrien, M.; Sergent, M. Polyhedron 1986, 5, 87.
9. Schneemeyer, L. F.; Wrighton, M. S. J. Am. Chem. Soc. 1979, 101, 6496.
10. Wittingham, M. S. Prog. Solid State Chem. 1978, 12, 41.
11. Stiefel, E. I.; Halbert, T. R.; Coyle, C. L.; Wei, L.; Pan, W.-H.; Ho, T. C.; Chianelli, R. R.; Daage, M. Polyhedron 1989, 8, 1625.
12. Sellman, D.; Grasser, F.; Knoch, F.; Moll, M. Inorg. Chim. Acta 1992, 195, 25.
13. Lee, C. C.; Halbert, T. R.; Pan, W.-H.; Harmer, M. A.; Wei, L.; Leonowicz, M. E.; Dim, C. O. B.; Miller, K. F.; Bruce, A. E.; McKenna, S.; Corbin, J. L.; Wherland, S.; Stiefel, E. I. Inorg. Chim. Acta 1996, 243, 147.
14. Shibahara, T.; Kobayashi, S.; Tsuji, N.; Sakane, G.; Fukuhara, M. Inorg. Chem. 1997, 36, 1702.
15. (a) Kang, D.-X.; Poor, M.; Blinn, E. L. Inorg. Chim. Acta 1990, 168, 209.
16. (b) Sellman, D.; Ruf, R.; Knoch, F.; Moll, M. Inorg. Chem. 1995, 34, 4745.
17. Bristow, S.; Garner, C. D.; Pickett, C. J. J. Chem. Soc., Dalton Trans. 1983, 1617.
18. Dhawan, I. K.; Enemark, J. H. Inorg. Chem. 1996, 35, 4873.
19. Carducci, M. D.; Brown, C.; Solomon, E. I.; Enemark, J. H. J. Am. Chem. Soc. 1994, 116, 11856.
20. Green, J. C. Acc. Chem. Res. 1994, 27, 131.
21. Westcott, B. L.; Enemark, J. H., Inorg. Chem. 1997, 36, 5404.
22. Bursten, B. E.; Cayton, R. H. Organometallics 1987, 6, 2004.
23. Cleland, W. E., Jr.; Bamhart, K. M.; Yamanouchi, K.; Collison, D.; Mabbs, F. E.; Ortega, R. B.; Enemark, J. H. Inorg. Chem. 1987, 26, 1017-1025.
24. Alobaidi, N.; Jones, C. J.; McCleverty, J. A. Polyhedron 1989, 8, 1033-1037.
25. Lichtenberger, D. L.; Kellogg, G. E.; Kristofzski, J. G.; Page, D.; Turner, S.; Klinger, G.; Lorenzen, J. Rev. Sci. Instrum. 1986, 57, 2366.
26. Turner, D. W.; Baker, C.; Baker, A. D.; Brundle, C. R. Molecular Photoelectron Spectroscopy; Wiley-Interscience: London, 1970.
27. Lichtenberger, D. L.; Copenhaver, A. S. J. Electron. Spectrosc. Relat. Phenom. 1990, 50, 335.
28. Lichtenberger, D. L.; Gruhn, N. E.; Renshaw, S. K. J. Mol. Struct. 1997, 405, 79.
29. Yeh, J. J.; Lindau, I. At. Data Nucl. Data Tables 1985, 32, 1.
30. Lichtenberger, D. L.; Kellogg, G. E. Acc. Chem. Res. 1987, 20, 379 and references therein.
31. Westcott, B. L. Ph.D. Dissertation, The University of Arizona, 1997.