Challenges and Prospects in Solar Water Splitting and CO2 Reduction with Inorganic and Hybrid Nanostructures

ACS Catalysis

Volumn 8, Issue 4, 2018, Pages 3602-3635

  Stolarczyk, Jacek K ^a,b   Bhattacharyya, Santanu ^a,b   Polavarapu, Lakshminarayana ^a,b   Feldmann, Jochen ^a,b  

^a UNIVERSITY OF MUNICH   (Germany)

^b NANOSYSTEMS INITIATIVE MUNICH NIM   (Germany)

Author keywords

CO2 reduction; defect engineering; photocatalysis; semiconductor nanocrystals; Solar energy; water splitting

Indexed keywords

CARBON DIOXIDE; ENERGY DISSIPATION; GLOBAL WARMING; HYDROGEN STORAGE; LIGHT ABSORPTION; METHANOL FUELS; PEROVSKITE; PHOTOCATALYSIS; PHOTOELECTROCHEMICAL CELLS; PHOTOVOLTAIC CELLS; REDUCTION; REVERSE COMBUSTION; SELF ASSEMBLY; SOLAR ENERGY; SURFACE REACTIONS; SUSTAINABLE DEVELOPMENT;

CO2 REDUCTION; DEFECT ENGINEERING; ENERGY LOSS MECHANISMS; ENVIRONMENTAL SUSTAINABILITY; NANOSTRUCTURED SEMICONDUCTOR; PHOTOCATALYTIC WATER SPLITTING; SEMICONDUCTOR NANOCRYSTALS; WATER SPLITTING;

DEFECTS;

EID: 85045108296     PISSN: None     EISSN: 21555435     Source Type: Journal    
DOI: 10.1021/acscatal.8b00791     Document Type: Article

References (371)

1. Tans, P. NOAA/ESRL (www.esrl.noaa.gov/gmd/ccgg/trends/); Keeling, R. Scripps Institution of Oceanography (scrippsco2.ucsd.edu/) 2018.
2. 2 over the last 1000 years from air in Antarctic ice and firn. J. Geophys. Res. Atmos. 1996, 101, 4115-4128, 10.1029/95JD03410
3. 2. Adv. Mater. 2015, 27, 1957-1963, 10.1002/adma.201500116
4. Olah, G. A.; Prakash, G. K. S.; Goeppert, A. Anthropogenic Chemical Carbon Cycle for a Sustainable Future. J. Am. Chem. Soc. 2011, 133, 12881-12898, 10.1021/ja202642y
5. Intergovernmental Panel on Climate Change (IPCC). Fifth Assessment Report 2014; IPCC: Geneva, Switzerland. Available at the following: https://www.ipcc.ch/report/ar5/.
6. International Energy Agency. Medium-Term Renewable Energy Market Report 2016; International Energy Agency: Paris, France. Available at the following: https://www.iea.org/newsroom/news/2016/october/medium-term-renewable-energy-market-report-2016.html.
7. Tarascon, J. M.; Armand, M. Issues and challenges facing rechargeable lithium batteries. Nature 2001, 414, 359-367, 10.1038/35104644
8. 2 and Li-S Batteries with High Energy Storage. Nat. Mater. 2012, 11, 19-29, 10.1038/nmat3191
9. Dahl, S.; Chorkendorff, I. Solar-fuel generation: Towards practical implementation. Nat. Mater. 2012, 11, 100-101, 10.1038/nmat3233
10. Lewis, N. S.; Nocera, D. G. Powering the planet: Chemical challenges in solar energy utilization. Proc. Natl. Acad. Sci. U. S. A. 2006, 103, 15729-15735, 10.1073/pnas.0603395103
11. Mikkelsen, M.; Jorgensen, M.; Krebs, F. C. The teraton challenge. A review of fixation and transformation of carbon dioxide. Energy Environ. Sci. 2010, 3, 43-81, 10.1039/B912904A
12. 2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes. Energy Environ. Sci. 2013, 6, 3112-3135, 10.1039/c3ee41272e
13. Luo, J.; Im, J.-H.; Mayer, M. T.; Schreier, M.; Nazeeruddin, M. K.; Park, N.-G.; Tilley, S. D.; Fan, H. J.; Grätzel, M. Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts. Science 2014, 345, 1593, 10.1126/science.1258307
14. 2 using perovskite photovoltaics. Nat. Commun. 2015, 6, 7326, 10.1038/ncomms8326
15. Ager, J. W.; Shaner, M. R.; Walczak, K. A.; Sharp, I. D.; Ardo, S. Experimental demonstrations of spontaneous, solar-driven photoelectrochemical water splitting. Energy Environ. Sci. 2015, 8, 2811-2824, 10.1039/C5EE00457H
16. Khaselev, O.; Turner, J. A. A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting. Science 1998, 280, 425, 10.1126/science.280.5362.425
17. 2-Catalyzed AlGaAs/Si Photoelectrolysis. J. Phys. Chem. B 2000, 104, 8920-8924, 10.1021/jp002083b
18. Fujii, K.; Nakamura, S.; Sugiyama, M.; Watanabe, K.; Bagheri, B.; Nakano, Y. Characteristics of hydrogen generation from water splitting by polymer electrolyte electrochemical cell directly connected with concentrated photovoltaic cell. Int. J. Hydrogen Energy 2013, 38, 14424-14432, 10.1016/j.ijhydene.2013.07.010
19. Osterloh, F. E. Boosting the Efficiency of Suspended Photocatalysts for Overall Water Splitting. J. Phys. Chem. Lett. 2014, 5, 2510-2511, 10.1021/jz501342j
20. Walter, M. G.; Warren, E. L.; McKone, J. R.; Boettcher, S. W.; Mi, Q.; Santori, E. A.; Lewis, N. S. Solar Water Splitting Cells. Chem. Rev. 2010, 110, 6446-6473, 10.1021/cr1002326
21. Hisatomi, T.; Kubota, J.; Domen, K. Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting. Chem. Soc. Rev. 2014, 43, 7520-7535, 10.1039/C3CS60378D
22. Fujishima, A.; Honda, K. Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature 1972, 238, 37-38, 10.1038/238037a0
23. Joya, K. S.; Joya, Y. F.; Ocakoglu, K.; van de Krol, R. Water-Splitting Catalysis and Solar Fuel Devices: Artificial Leaves on the Move. Angew. Chem., Int. Ed. 2013, 52, 10426-10437, 10.1002/anie.201300136
24. Sivula, K.; van de Krol, R. Semiconducting materials for photoelectrochemical energy conversion. Nat. Rev. Mater. 2016, 1, 15010, 10.1038/natrevmats.2015.10
25. Bard, A. J. Photoelectrochemistry and heterogeneous photo-catalysis at semiconductors. J. Photochem. 1979, 10, 59-75, 10.1016/0047-2670(79)80037-4
26. 2 crystals. Nature 1975, 257, 383-386, 10.1038/257383a0
27. Osterloh, F. E. Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting. Chem. Soc. Rev. 2013, 42, 2294-2320, 10.1039/C2CS35266D
28. Walczak, K.; Chen, Y.; Karp, C.; Beeman, J. W.; Shaner, M.; Spurgeon, J.; Sharp, I. D.; Amashukeli, X.; West, W.; Jin, J.; Lewis, N. S.; Xiang, C. Modeling, Simulation, and Fabrication of a Fully Integrated, Acid-stable, Scalable Solar-Driven Water-Splitting System. ChemSusChem 2015, 8, 544-551, 10.1002/cssc.201402896
29. Osterloh, F. E. Photocatalysis versus Photosynthesis: A Sensitivity Analysis of Devices for Solar Energy Conversion and Chemical Transformations. ACS Energy Lett. 2017, 2, 445-453, 10.1021/acsenergylett.6b00665
30. Kudo, A.; Miseki, Y. Heterogeneous photocatalyst materials for water splitting. Chem. Soc. Rev. 2009, 38, 253-278, 10.1039/B800489G
31. Serpone, N.; Emeline, A. V. Semiconductor Photocatalysis-Past, Present, and Future Outlook. J. Phys. Chem. Lett. 2012, 3, 673-677, 10.1021/jz300071j
32. Chen, X.; Shen, S.; Guo, L.; Mao, S. S. Semiconductor-based Photocatalytic Hydrogen Generation. Chem. Rev. 2010, 110, 6503-6570, 10.1021/cr1001645
33. Kisch, H. Semiconductor Photocatalysis-Mechanistic and Synthetic Aspects. Angew. Chem., Int. Ed. 2013, 52, 812-847, 10.1002/anie.201201200
34. Vaneski, A.; Susha, A. S.; Rodríguez-Fernández, J.; Berr, M.; Jäckel, F.; Feldmann, J.; Rogach, A. L. Hybrid Colloidal Heterostructures of Anisotropic Semiconductor Nanocrystals Decorated with Noble Metals: Synthesis and Function. Adv. Funct. Mater. 2011, 21, 1547-1556, 10.1002/adfm.201002444
35. Costi, R.; Saunders, A. E.; Banin, U. Colloidal Hybrid Nanostructures: A New Type of Functional Materials. Angew. Chem., Int. Ed. 2010, 49, 4878-4897, 10.1002/anie.200906010
36. Fabian, D. M.; Hu, S.; Singh, N.; Houle, F. A.; Hisatomi, T.; Domen, K.; Osterloh, F. E.; Ardo, S. Particle suspension reactors and materials for solar-driven water splitting. Energy Environ. Sci. 2015, 8, 2825-2850, 10.1039/C5EE01434D
37. Pinaud, B. A.; Benck, J. D.; Seitz, L. C.; Forman, A. J.; Chen, Z.; Deutsch, T. G.; James, B. D.; Baum, K. N.; Baum, G. N.; Ardo, S.; Wang, H.; Miller, E.; Jaramillo, T. F. Technical and economic feasibility of centralized facilities for solar hydrogen production via photocatalysis and photoelectrochemistry. Energy Environ. Sci. 2013, 6, 1983-2002, 10.1039/c3ee40831k
38. Rajeshwar, K.; Thomas, A.; Janáky, C. Photocatalytic Activity of Inorganic Semiconductor Surfaces: Myths, Hype, and Reality. J. Phys. Chem. Lett. 2015, 6, 139-147, 10.1021/jz502586p
39. Kubacka, A.; Fernández-García, M.; Colón, G. Advanced Nanoarchitectures for Solar Photocatalytic Applications. Chem. Rev. 2012, 112, 1555-614, 10.1021/cr100454n
40. 2 Nanoparticles as Functional Building Blocks. Chem. Rev. 2014, 114, 9283-9318, 10.1021/cr400629p
41. 2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: A review. Appl. Catal., B 2004, 49, 1-14, 10.1016/j.apcatb.2003.11.010
42. Braslavsky, S. E.; Braun, A. M.; Cassano, A. E.; Emeline, A. V.; Litter, M. I.; Palmisano, L.; Parmon, V. N.; Serpone, N. Glossary of terms used in photocatalysis and radiation catalysis (IUPAC Recommendations 2011). Pure Appl. Chem. 2011, 83, 931-1014, 10.1351/PAC-REC-09-09-36
43. 2 over Heterostructure Semiconductors into Value-Added Chemicals. Chem. Rec. 2016, 16, 1918-1933, 10.1002/tcr.201600008
44. 2 into Renewable Hydrocarbon Fuels: State-of-the-Art Accomplishment, Challenges, and Prospects. Adv. Mater. 2014, 26, 4607-4626, 10.1002/adma.201400087
45. 2O on various titanium oxide photocatalysts. RSC Adv. 2012, 2, 3165-3172, 10.1039/c2ra01332k
46. Chen, X.; Mao, S. S. Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications. Chem. Rev. 2007, 107, 2891-2959, 10.1021/cr0500535
47. Newman, R.; Chrenko, R. M. Optical Properties of Nickel Oxide. Phys. Rev. 1959, 114, 1507-1513, 10.1103/PhysRev.114.1507
48. Sokolov, V. I.; Pustovarov, V. A.; Churmanov, V. N.; Ivanov, V. Y.; Gruzdev, N. B.; Sokolov, P. S.; Baranov, A. N.; Moskvin, A. S. Unusual x-ray excited luminescence spectra of NiO suggest self-trapping of the d-d charge-transfer exciton. Phys. Rev. B: Condens. Matter Mater. Phys. 2012, 86, 115128, 10.1103/PhysRevB.86.115128
49. 4 and Its Implications for Water Splitting Activity in the Wolframite Structure Type. Inorg. Chem. 2012, 51, 6096-6103, 10.1021/ic202715c
50. Shockley, W.; Queisser, H. J. Detailed Balance Limit of Efficiency of p-n Junction Solar Cells. J. Appl. Phys. 1961, 32, 510-519, 10.1063/1.1736034
51. Shalom, M.; Inal, S.; Fettkenhauer, C.; Neher, D.; Antonietti, M. Improving Carbon Nitride Photocatalysis by Supramolecular Preorganization of Monomers. J. Am. Chem. Soc. 2013, 135, 7118-7121, 10.1021/ja402521s
52. 2 Generation with CdSe/CdS Core-Shell Nanocrystals. Z. Phys. Chem. 2015, 229, 205-219, 10.1515/zpch-2014-0635
53. Chen, S.; Wang, L.-W. Thermodynamic Oxidation and Reduction Potentials of Photocatalytic Semiconductors in Aqueous Solution. Chem. Mater. 2012, 24, 3659-3666, 10.1021/cm302533s
54. Aldana, J.; Wang, Y. A.; Peng, X. Photochemical Instability of CdSe Nanocrystals Coated by Hydrophilic Thiols. J. Am. Chem. Soc. 2001, 123, 8844-8850, 10.1021/ja016424q
55. Meissner, D.; Memming, R.; Kastening, B. Photoelectrochemistry of cadmium sulfide. 1. Reanalysis of photocorrosion and flat-band potential. J. Phys. Chem. 1988, 92, 3476-3483, 10.1021/j100323a032
56. Berr, M. J.; Wagner, P.; Fischbach, S.; Vaneski, A.; Schneider, J.; Susha, A. S.; Rogach, A. L.; Jackel, F.; Feldmann, J. Hole Scavenger Redox Potentials Determine Quantum Efficiency and Stability of Pt-decorated CdS Nanorods for Photocatalytic Hydrogen Generation. Appl. Phys. Lett. 2012, 100, 223903-3, 10.1063/1.4723575
57. Tarafder, K.; Surendranath, Y.; Olshansky, J. H.; Alivisatos, A. P.; Wang, L.-W. Hole Transfer Dynamics from a CdSe/CdS Quantum Rod to a Tethered Ferrocene Derivative. J. Am. Chem. Soc. 2014, 136, 5121-5131, 10.1021/ja500936n
58. 2 Generation Efficiency in CdS-Pt and CdSe/CdS-Pt Semiconductor Nanorod-Metal Tip Heterostructures. J. Am. Chem. Soc. 2014, 136, 7708-7716, 10.1021/ja5023893
59. Kalisman, P.; Nakibli, Y.; Amirav, L. Perfect Photon-to-Hydrogen Conversion Efficiency. Nano Lett. 2016, 16, 1776-1781, 10.1021/acs.nanolett.5b04813
60. 2 Generation on Pt-Decorated CdS Nanorods. ACS Energy Lett. 2016, 1, 1137-1142, 10.1021/acsenergylett.6b00468
61. 2 Generation on Ni-decorated CdS Nanorods. Nat. Mater. 2014, 13, 1013-1018, 10.1038/nmat4049
62. 3 during Water Splitting. J. Phys. Chem. Lett. 2011, 2, 1900-1903, 10.1021/jz200839n
63. 4+ as electron acceptors. Appl. Catal., A 2001, 205, 117-128, 10.1016/S0926-860X(00)00549-4
64. Hitoki, G.; Takata, T.; Kondo, J. N.; Hara, M.; Kobayashi, H.; Domen, K. An oxynitride, TaON, as an efficient water oxidation photocatalyst under visible light irradiation (λ ≤ 500 nm). Chem. Commun. 2002, 1698-1699, 10.1039/B202393H
65. 3 Photocatalysts with High Crystallinity and Surface Nanostructure. J. Am. Chem. Soc. 2003, 125, 3082-3089, 10.1021/ja027751g
66. 2. Chem. Commun. 2011, 47, 5632-5634, 10.1039/c1cc10513b
67. Marcus, R. A. On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. I. J. Chem. Phys. 1956, 24, 966-978, 10.1063/1.1742723
68. 2 and Other Semiconductors. Angew. Chem., Int. Ed. 2013, 52, 7372-7408, 10.1002/anie.201207199
69. Tong, H.; Ouyang, S.; Bi, Y.; Umezawa, N.; Oshikiri, M.; Ye, J. Nano-photocatalytic Materials: Possibilities and Challenges. Adv. Mater. 2012, 24, 229-251, 10.1002/adma.201102752
70. Larson, D. R.; Zipfel, W. R.; Williams, R. M.; Clark, S. W.; Bruchez, M. P.; Wise, F. W.; Webb, W. W. Water-Soluble Quantum Dots for Multiphoton Fluorescence Imaging in Vivo. Science 2003, 300, 1434, 10.1126/science.1083780
71. Yong, K.-T.; Qian, J.; Roy, I.; Lee, H. H.; Bergey, E. J.; Tramposch, K. M.; He, S.; Swihart, M. T.; Maitra, A.; Prasad, P. N. Quantum Rod Bioconjugates as Targeted Probes for Confocal and Two-Photon Fluorescence Imaging of Cancer Cells. Nano Lett. 2007, 7, 761-765, 10.1021/nl063031m
72. Zhou, B.; Shi, B.; Jin, D.; Liu, X. Controlling upconversion nanocrystals for emerging applications. Nat. Nanotechnol. 2015, 10, 924-936, 10.1038/nnano.2015.251
73. Haase, M.; Schäfer, H. Upconverting Nanoparticles. Angew. Chem., Int. Ed. 2011, 50, 5808-5829, 10.1002/anie.201005159
74. 2 core/shell nanoparticles. Chem. Commun. 2010, 46, 2304-2306, 10.1039/b924052g
75. 2 system: Dual up-conversion and electronic role of the lanthanide. J. Catal. 2013, 299, 298-306, 10.1016/j.jcat.2012.12.021
76. Cui, C.; Tou, M.; Li, M.; Luo, Z.; Xiao, L.; Bai, S.; Li, Z. Heterogeneous Semiconductor Shells Sequentially Coated on Upconversion Nanoplates for NIR-Light Enhanced Photocatalysis. Inorg. Chem. 2017, 56, 2328-2336, 10.1021/acs.inorgchem.6b03079
77. Zhang, J.; Huang, Y.; Jin, L.; Rosei, F.; Vetrone, F.; Claverie, J. P. Efficient Upconverting Multiferroic Core@Shell Photocatalysts: Visible-to-Near-Infrared Photon Harvesting. ACS Appl. Mater. Interfaces 2017, 9, 8142-8150, 10.1021/acsami.7b00158
78. 2 Core-Shell Nanoparticles. ACS Catal. 2013, 3, 405-412, 10.1021/cs300808r
79. 2. ACS Appl. Mater. Interfaces 2014, 6, 340-348, 10.1021/am404389g
80. Fan, W.; Bai, H.; Shi, W. Semiconductors with NIR driven upconversion performance for photocatalysis and photoelectrochemical water splitting. CrystEngComm 2014, 16, 3059-3067, 10.1039/c3ce42337a
81. Zhuo, S.; Shao, M.; Lee, S.-T. Upconversion and Downconversion Fluorescent Graphene Quantum Dots: Ultrasonic Preparation and Photocatalysis. ACS Nano 2012, 6, 1059-1064, 10.1021/nn2040395
82. Xu, X.; Randorn, C.; Efstathiou, P.; Irvine, J. T. S. A red metallic oxide photocatalyst. Nat. Mater. 2012, 11, 595-598, 10.1038/nmat3312
83. 3 Hybrid Conductor Material. Nano Lett. 2015, 15, 7199-7203, 10.1021/acs.nanolett.5b01581
84. 2 films. Nature 1991, 353, 737-740, 10.1038/353737a0
85. Youngblood, W. J.; Lee, S.-H. A.; Maeda, K.; Mallouk, T. E. Visible Light Water Splitting Using Dye-Sensitized Oxide Semiconductors. Acc. Chem. Res. 2009, 42, 1966-1973, 10.1021/ar9002398
86. 2 Photocatalysis under UV/Visible Light: Selected Results and Related Mechanisms on Interfacial Charge Carrier Transfer Dynamics. J. Phys. Chem. A 2011, 115, 13211-13241, 10.1021/jp204364a
87. 2/Pt Hybrid Systems. Chem.-Eur. J. 2012, 18, 15368-15381, 10.1002/chem.201201500
88. 2 on Hydrogen Production under Visible Light. J. Phys. Chem. B 2006, 110, 14792-14799, 10.1021/jp062540+
89. Maeda, K.; Eguchi, M.; Youngblood, W. J.; Mallouk, T. E. Niobium Oxide Nanoscrolls as Building Blocks for Dye-Sensitized Hydrogen Production from Water under Visible Light Irradiation. Chem. Mater. 2008, 20, 6770-6778, 10.1021/cm801807b
90. 2 Nanoparticles Using Visible Light. J. Am. Chem. Soc. 2010, 132, 2132-2133, 10.1021/ja910091z
91. 2 photoreduction at enzyme-modified metal oxide nanoparticles. Energy Environ. Sci. 2011, 4, 2393-2399, 10.1039/c0ee00780c
92. Kamat, P. V. Manipulation of Charge Transfer Across Semiconductor Interface. A Criterion That Cannot Be Ignored in Photocatalyst Design. J. Phys. Chem. Lett. 2012, 3, 663-672, 10.1021/jz201629p
93. 2 semiconductor nanoclusters. Phys. Chem. Chem. Phys. 2002, 4, 198-203, 10.1039/b107544f
94. 2 Nanostructures for Photoelectrochemical Solar Hydrogen Generation. Nano Lett. 2010, 10, 478-483, 10.1021/nl903217w
95. Wang, G.; Yang, X.; Qian, F.; Zhang, J. Z.; Li, Y. Double-Sided CdS and CdSe Quantum Dot Co-Sensitized ZnO Nanowire Arrays for Photoelectrochemical Hydrogen Generation. Nano Lett. 2010, 10, 1088-1092, 10.1021/nl100250z
96. 2 heterostructured photocatalysts. J. Mater. Chem. 2011, 21, 13452-13457, 10.1039/c1jm12367j
97. Liao, F.; Zeng, Z.; Eley, C.; Lu, Q.; Hong, X.; Tsang, S. C. E. Electronic Modulation of a Copper/Zinc Oxide Catalyst by a Heterojunction for Selective Hydrogenation of Carbon Dioxide to Methanol. Angew. Chem., Int. Ed. 2012, 51, 5832-5836, 10.1002/anie.201200903
98. Linic, S.; Christopher, P.; Ingram, D. B. Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy. Nat. Mater. 2011, 10, 911-921, 10.1038/nmat3151
99. Polavarapu, L.; Mourdikoudis, S.; Pastoriza-Santos, I.; Perez-Juste, J. Nanocrystal engineering of noble metals and metal chalcogenides: controlling the morphology, composition and crystallinity. CrystEngComm 2015, 17, 3727-3762, 10.1039/C5CE00112A
100. Liz-Marzán, L. M. Tailoring Surface Plasmons through the Morphology and Assembly of Metal Nanoparticles. Langmuir 2006, 22, 32-41, 10.1021/la0513353
101. Hou, W.; Cronin, S. B. A Review of Surface Plasmon Resonance-Enhanced Photocatalysis. Adv. Funct. Mater. 2013, 23, 1612-1619, 10.1002/adfm.201202148
102. Wang, M.; Ye, M.; Iocozzia, J.; Lin, C.; Lin, Z. Plasmon-Mediated Solar Energy Conversion via Photocatalysis in Noble Metal/Semiconductor Composites. Adv. Sci. 2016, 3, 1600024, 10.1002/advs.201600024
103. Zhou, N.; Lopez-Puente, V.; Wang, Q.; Polavarapu, L.; Pastoriza-Santos, I.; Xu, Q.-H. Plasmon-enhanced light harvesting: applications in enhanced photocatalysis, photodynamic therapy and photovoltaics. RSC Adv. 2015, 5, 29076-29097, 10.1039/C5RA01819F
104. Yan, L.; Wang, F.; Meng, S. Quantum Mode Selectivity of Plasmon-Induced Water Splitting on Gold Nanoparticles. ACS Nano 2016, 10, 5452-5458, 10.1021/acsnano.6b01840
105. Ueno, K.; Oshikiri, T.; Misawa, H. Plasmon-Induced Water Splitting Using Metallic-Nanoparticle-Loaded Photocatalysts and Photoelectrodes. ChemPhysChem 2016, 17, 199-215, 10.1002/cphc.201500761
106. Maeda, K.; Domen, K. New Non-Oxide Photocatalysts Designed for Overall Water Splitting under Visible Light. J. Phys. Chem. C 2007, 111, 7851-7861, 10.1021/jp070911w
107. 5: Electronic Band Structures and Absolute Band Edges. J. Phys. Chem. C 2017, 121, 3241-3251, 10.1021/acs.jpcc.6b12370
108. 2 Reduction with Visible Light Using a Hybrid of a Perovskite Tantalum Oxynitride and a Binuclear Ruthenium(II) Complex. ACS Appl. Mater. Interfaces 2015, 7, 13092-13097, 10.1021/acsami.5b03509
109. x/TaON Photoanode. J. Am. Chem. Soc. 2016, 138, 14152-14158, 10.1021/jacs.6b09212
110. 2 Reduction. Inorg. Chem. 2015, 54, 5096-5104, 10.1021/ic502675a
111. Yuliati, L.; Yang, J.-H.; Wang, X.; Maeda, K.; Takata, T.; Antonietti, M.; Domen, K. Highly active tantalum(v) nitride nanoparticles prepared from a mesoporous carbon nitride template for photocatalytic hydrogen evolution under visible light irradiation. J. Mater. Chem. 2010, 20, 4295-4298, 10.1039/c0jm00341g
112. Li, X.; Kikugawa, N.; Ye, J. Nitrogen-doped Lamellar Niobic Acid with Visible Light-responsive Photocatalytic Activity. Adv. Mater. 2008, 20, 3816-3819, 10.1002/adma.200702975
113. 2 photoreduction under visible light. Chem. Commun. 2012, 48, 1269-1271, 10.1039/C2CC16900B
114. 4 under visible light after nitridation. J. Mater. Chem. 2012, 22, 2033-2038, 10.1039/C1JM14122H
115. 2 Reduction. Eur. J. Inorg. Chem. 2017, 2017, 2195-2200, 10.1002/ejic.201700044
116. x): origin of visible light absorption. Chem. Commun. 2010, 46, 2379-2381, 10.1039/b922008a
117. 3 (M: Ta and Nb) with the Perovskite Structure. J. Phys. Chem. B 2002, 106, 12441-12447, 10.1021/jp025974n
118. 3. Dalton Trans. 2009, 8519-8524, 10.1039/b906799j
119. x with Modulated Band Structure and Enhanced Visible-Light Photocatalytic Activity. J. Phys. Chem. C 2009, 113, 3785-3792, 10.1021/jp807393a
120. x. Int. J. Hydrogen Energy 2014, 39, 7705-7712, 10.1016/j.ijhydene.2014.03.102
121. Sullivan, I.; Zoellner, B.; Maggard, P. A. Copper(I)-Based p-Type Oxides for Photoelectrochemical and Photovoltaic Solar Energy Conversion. Chem. Mater. 2016, 28, 5999-6016, 10.1021/acs.chemmater.6b00926
122. Joshi, U. A.; Palasyuk, A.; Arney, D.; Maggard, P. A. Semiconducting Oxides to Facilitate the Conversion of Solar Energy to Chemical Fuels. J. Phys. Chem. Lett. 2010, 1, 2719-2726, 10.1021/jz100961d
123. 3 Photocathode. J. Phys. Chem. C 2011, 115, 13534-13539, 10.1021/jp204631a
124. 4: Elucidating the Role of the Bi s and V d Orbitals. Chem. Mater. 2009, 21, 547-551, 10.1021/cm802894z
125. 6 Nanoplates as High-Activity Visible-Light-Driven Photocatalysts. Chem. Mater. 2005, 17, 3537-3545, 10.1021/cm0501517
126. 4 Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting. Science 2014, 343, 990, 10.1126/science.1246913
127. 3 electrodes for enhanced photoactivity of water oxidation. Energy Environ. Sci. 2011, 4, 1781-1787, 10.1039/c0ee00743a
128. 4 Photocatalyst for Sun-Driven Water Oxidation: Top-Performing Photoanodes and Scale-Up Challenges. Catalysts 2017, 7, 13, 10.3390/catal7010013
129. 4. ACS Appl. Mater. Interfaces 2016, 8, 28607-28614, 10.1021/acsami.6b09076
130. 4 with Scheelite Structure and Their Photocatalytic Properties. Chem. Mater. 2001, 13, 4624-4628, 10.1021/cm0103390
131. 4. Nat. Commun. 2013, 4, 1432, 10.1038/ncomms2401
132. 4 photocatalyst. Catal. Commun. 2009, 11, 210-213, 10.1016/j.catcom.2009.10.010
133. 6 Improved Photocatalytic Water Oxidation with Zn Doping. J. Phys. Chem. C 2013, 117, 9633-9640, 10.1021/jp308629q
134. 6 Inverse Opals: Facile Fabrication and Efficient Visible-Light-Driven Photocatalytic and Photoelectrochemical Water-Splitting Activity. Small 2011, 7, 2714-2720, 10.1002/smll.201101152
135. 2 into Renewable Hydrocarbon Fuel under Visible Light. ACS Appl. Mater. Interfaces 2011, 3, 3594-3601, 10.1021/am2008147
136. 2 reduction. Nano Energy 2017, 32, 359-366, 10.1016/j.nanoen.2016.12.054
137. Chen, X.; Liu, L.; Yu, P. Y.; Mao, S. S. Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals. Science 2011, 331, 746, 10.1126/science.1200448
138. 2 for the Photocatalytic Splitting of Water. Angew. Chem., Int. Ed. 2012, 51, 12410-12412, 10.1002/anie.201206375
139. Huang, Z.-F.; Song, J.; Pan, L.; Zhang, X.; Wang, L.; Zou, J.-J. Tungsten Oxides for Photocatalysis, Electrochemistry, and Phototherapy. Adv. Mater. 2015, 27, 5309-5327, 10.1002/adma.201501217
140. Liu, F.; Chen, X.; Xia, Q.; Tian, L.; Chen, X. Ultrathin tungsten oxide nanowires: oleylamine assisted nonhydrolytic growth, oxygen vacancies and good photocatalytic properties. RSC Adv. 2015, 5, 77423-77428, 10.1039/C5RA12993A
141. 49 Nanowires with Diameters below 1 nm: Synthesis, Near-Infrared Absorption, Photoluminescence, and Photochemical Reduction of Carbon Dioxide. Angew. Chem., Int. Ed. 2012, 51, 2395-2399, 10.1002/anie.201107681
142. 2 Particles: Size Quantization versus Direct Transitions in This Indirect Semiconductor?. J. Phys. Chem. 1995, 99, 16646-16654, 10.1021/j100045a026
143. 2 Particles: Reactivity of Free and Trapped Holes. J. Phys. Chem. B 1997, 101, 4265-4275, 10.1021/jp9639915
144. Berr, M. J.; Vaneski, A.; Mauser, C.; Fischbach, S.; Susha, A. S.; Rogach, A. L.; Jäckel, F.; Feldmann, J. Delayed Photoelectron Transfer in Pt-Decorated CdS Nanorods under Hydrogen Generation Conditions. Small 2012, 8, 291-297, 10.1002/smll.201101317
145. 2. Reaction of Water with Photoholes, Importance of Charge Carrier Dynamics, and Evidence for Four-Hole Chemistry. J. Am. Chem. Soc. 2008, 130, 13885-13891, 10.1021/ja8034637
146. White, J. L.; Baruch, M. F.; Pander, J. E., III; Hu, Y.; Fortmeyer, I. C.; Park, J. E.; Zhang, T.; Liao, K.; Gu, J.; Yan, Y.; Shaw, T. W.; Abelev, E.; Bocarsly, A. B. Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes. Chem. Rev. 2015, 115, 12888-12935, 10.1021/acs.chemrev.5b00370
147. Maeda, K.; Domen, K. Photocatalytic Water Splitting: Recent Progress and Future Challenges. J. Phys. Chem. Lett. 2010, 1, 2655-2661, 10.1021/jz1007966
148. 2 Evolution. J. Phys. Chem. C 2013, 117, 11584-11591, 10.1021/jp400010z
149. Wang, Y.; Wang, Q.; Zhan, X.; Wang, F.; Safdar, M.; He, J. Visible light driven type II heterostructures and their enhanced photocatalysis properties: a review. Nanoscale 2013, 5, 8326-8339, 10.1039/c3nr01577g
150. 2 crystalline photocatalyst. Chem. Commun. 2003, 1552-1553, 10.1039/b302418k
151. Teranishi, T.; Sakamoto, M. Charge Separation in Type-II Semiconductor Heterodimers. J. Phys. Chem. Lett. 2013, 4, 2867-2873, 10.1021/jz4013504
152. Koppenol, W. H.; Rush, J. D. Reduction potential of the carbon dioxide/carbon dioxide radical anion: a comparison with other C1 radicals. J. Phys. Chem. 1987, 91, 4429-4430, 10.1021/j100300a045
153. 2 by supported Cu clusters. Phys. Chem. Chem. Phys. 2017, 19, 28788-28807, 10.1039/C7CP05718K
154. 2 activation and reaction on surfaces of photocatalysts. Energy Environ. Sci. 2016, 9, 2177-2196, 10.1039/C6EE00383D
155. Coridan, R. H.; Nielander, A. C.; Francis, S. A.; McDowell, M. T.; Dix, V.; Chatman, S. M.; Lewis, N. S. Methods for comparing the performance of energy-conversion systems for use in solar fuels and solar electricity generation. Energy Environ. Sci. 2015, 8, 2886-2901, 10.1039/C5EE00777A
156. Centi, G.; Perathoner, S. Opportunities and prospects in the chemical recycling of carbon dioxide to fuels. Catal. Today 2009, 148, 191-205, 10.1016/j.cattod.2009.07.075
157. 2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries. Energy Environ. Sci. 2013, 6, 1711-1731, 10.1039/c3ee00056g
158. Thampi, K. R.; Kiwi, J.; Grätzel, M. Methanation and photo-methanation of carbon dioxide at room temperature and atmospheric pressure. Nature 1987, 327, 506, 10.1038/327506a0
159. 2 conversion to liquid fuels. RSC Adv. 2016, 6, 49675-49691, 10.1039/C6RA05414E
160. 2 to CO Conversion. ACS Catal. 2017, 7, 4613-4620, 10.1021/acscatal.7b00903
161. 2 reduction through mechanistic understanding. Nat. Commun. 2017, 8, 513, 10.1038/s41467-017-00558-9
162. Bezemer, G. L.; Bitter, J. H.; Kuipers, H. P. C. E.; Oosterbeek, H.; Holewijn, J. E.; Xu, X.; Kapteijn, F.; van Dillen, A. J.; de Jong, K. P. Cobalt Particle Size Effects in the Fischer-Tropsch Reaction Studied with Carbon Nanofiber Supported Catalysts. J. Am. Chem. Soc. 2006, 128, 3956-3964, 10.1021/ja058282w
163. 2 Reduction Selectivity. J. Am. Chem. Soc. 2015, 137, 3076-3084, 10.1021/ja5128133
164. 2 Reduction. Chem. Mater. 2016, 28, 4160-4168, 10.1021/acs.chemmater.6b00301
165. 2 Reduction. J. Am. Chem. Soc. 2016, 138, 1206-1214, 10.1021/jacs.5b10179
166. 2 reduction of Ti-oxide-based nanomaterials. Appl. Surf. Sci. 2017, 396, 1696-1711, 10.1016/j.apsusc.2016.11.240
167. 2-Based Catalysts: Fact or Fiction?. J. Am. Chem. Soc. 2010, 132, 8398-8406, 10.1021/ja101318k
168. 2-based photocatalysts. Catal. Today 2017, 281 (Part 1), 214-220, 10.1016/j.cattod.2016.05.040
169. y Nanocrystal Superstructures for Enhanced Gas-Phase Photocatalytic Activity. ACS Nano 2016, 10, 5578-5586, 10.1021/acsnano.6b02346
170. 2 reduction. Proc. Natl. Acad. Sci. U. S. A. 2016, 113, E8011-E8020, 10.1073/pnas.1609374113
171. Sun, W.; Qian, C.; He, L.; Ghuman, K. K.; Wong, A. P. Y.; Jia, J.; Jelle, A. A.; O'Brien, P. G.; Reyes, L. M.; Wood, T. E.; Helmy, A. S.; Mims, C. A.; Singh, C. V.; Ozin, G. A. Heterogeneous reduction of carbon dioxide by hydride-terminated silicon nanocrystals. Nat. Commun. 2016, 7, 12553, 10.1038/ncomms12553
172. 2 Util. 2016, 16, 194-203, 10.1016/j.jcou.2016.07.004
173. 2 nanofibers: Understanding the reduction pathway. Nano Res. 2016, 9, 1956-1968, 10.1007/s12274-016-1087-9
174. 2(101) Surface: The Essential Role of Oxygen Vacancy. J. Am. Chem. Soc. 2016, 138, 15896-15902, 10.1021/jacs.6b05695
175. 2(110) in Water: An Ab Initio Molecular Dynamics Study. J. Phys. Chem. C 2017, 121, 10476-10483, 10.1021/acs.jpcc.7b02777
176. Peterson, A. A.; Abild-Pedersen, F.; Studt, F.; Rossmeisl, J.; Norskov, J. K. How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels. Energy Environ. Sci. 2010, 3, 1311-1315, 10.1039/c0ee00071j
177. Janáky, C.; Hursán, D.; EndroÌdi, B.; Chanmanee, W.; Roy, D.; Liu, D.; de Tacconi, N. R.; Dennis, B. H.; Rajeshwar, K. Electro- and Photoreduction of Carbon Dioxide: The Twain Shall Meet at Copper Oxide/Copper Interfaces. ACS Energy Lett. 2016, 1, 332-338, 10.1021/acsenergylett.6b00078
178. 2 Electroreduction Reactions. ChemSusChem 2017, 10, 387-393, 10.1002/cssc.201601144
179. 2 Activation: A Dispersion-Corrected DFT+U Study. J. Phys. Chem. C 2016, 120, 2198-2214, 10.1021/acs.jpcc.5b10431
180. 2 Reduction in Artificial Photosynthesis. ACS Catal. 2016, 6, 6444-6454, 10.1021/acscatal.6b01455
181. 2. J. Am. Chem. Soc. 2016, 138, 13818-13821, 10.1021/jacs.6b08824
182. 3 nanorod thin film. Chem. Phys. Lett. 2016, 658, 309-314, 10.1016/j.cplett.2016.06.062
183. 4. ACS Sustainable Chem. Eng. 2015, 3, 2381-2388, 10.1021/acssuschemeng.5b00724
184. 2 Reduction into Methane Using Solar Irradiation: Sunlight into Fuel. ACS Omega 2016, 1, 868-875, 10.1021/acsomega.6b00164
185. Zhai, Q.; Xie, S.; Fan, W.; Zhang, Q.; Wang, Y.; Deng, W.; Wang, Y. Photocatalytic Conversion of Carbon Dioxide with Water into Methane: Platinum and Copper(I) Oxide Co-catalysts with a Core-Shell Structure. Angew. Chem., Int. Ed. 2013, 52, 5776-5779, 10.1002/anie.201301473
186. 2 Reduction. J. Am. Chem. Soc. 2015, 137, 14007-14010, 10.1021/jacs.5b06778
187. 2 photoreduction. Nanoscale 2014, 6, 14305-14318, 10.1039/C4NR05371K
188. 2 Reduction by Water. J. Am. Chem. Soc. 2014, 136, 15969-15976, 10.1021/ja506433k
189. 4 Nanotube Arrays. Environ. Sci. Technol. 2015, 49, 5828-5835, 10.1021/acs.est.5b00066
190. Amirav, L.; Alivisatos, A. P. Photocatalytic Hydrogen Production with Tunable Nanorod Heterostructures. J. Phys. Chem. Lett. 2010, 1, 1051-1054, 10.1021/jz100075c
191. Xu, Y.; Xu, R. Nickel-based cocatalysts for photocatalytic hydrogen production. Appl. Surf. Sci. 2015, 351, 779-793, 10.1016/j.apsusc.2015.05.171
192. Hong, D.; Yamada, Y.; Sheehan, M.; Shikano, S.; Kuo, C.-H.; Tian, M.; Tsung, C.-K.; Fukuzumi, S. Mesoporous Nickel Ferrites with Spinel Structure Prepared by an Aerosol Spray Pyrolysis Method for Photocatalytic Hydrogen Evolution. ACS Sustainable Chem. Eng. 2014, 2, 2588-2594, 10.1021/sc500484b
193. 4 nanoparticles and its visible-light-driven photoactivity for hydrogen production. Catal. Commun. 2012, 28, 116-119, 10.1016/j.catcom.2012.08.031
194. Cao, S.; Chen, Y.; Hou, C.-C.; Lv, X.-J.; Fu, W.-F. Cobalt phosphide as a highly active non-precious metal cocatalyst for photocatalytic hydrogen production under visible light irradiation. J. Mater. Chem. A 2015, 3, 6096-6101, 10.1039/C4TA07149B
195. Cao, S.; Chen, Y.; Wang, C.-J.; Lv, X.-J.; Fu, W.-F. Spectacular photocatalytic hydrogen evolution using metal-phosphide/CdS hybrid catalysts under sunlight irradiation. Chem. Commun. 2015, 51, 8708-8711, 10.1039/C5CC01799H
196. Wu, K.; Lian, T. Quantum Confined Colloidal Nanorod Heterostructures for Solar-to-Fuel Conversion. Chem. Soc. Rev. 2016, 45, 3781-810, 10.1039/C5CS00472A
197. Utterback, J. K.; Grennell, A. N.; Wilker, M. B.; Pearce, O. M.; Eaves, J. D.; Dukovic, G. Observation of Trapped-hole Diffusion on the Surfaces of CdS nanorods. Nat. Chem. 2016, 8, 1061-1066, 10.1038/nchem.2566
198. Sun, K.; Moreno-Hernandez, I. A.; Schmidt, W. C.; Zhou, X.; Crompton, J. C.; Liu, R.; Saadi, F. H.; Chen, Y.; Papadantonakis, K. M.; Lewis, N. S. A comparison of the chemical, optical and electrocatalytic properties of water-oxidation catalysts for use in integrated solar-fuel generators. Energy Environ. Sci. 2017, 10, 987-1002, 10.1039/C6EE03563A
199. Serpone, N.; Emeline, A. V.; Ryabchuk, V. K.; Kuznetsov, V. N.; Artem'ev, Y. M.; Horikoshi, S. Why do Hydrogen and Oxygen Yields from Semiconductor-Based Photocatalyzed Water Splitting Remain Disappointingly Low? Intrinsic and Extrinsic Factors Impacting Surface Redox Reactions. ACS Energy Lett. 2016, 1, 931-948, 10.1021/acsenergylett.6b00391
200. 3 Anode for Efficient Photoelectrochemical Water Oxidation. ACS Catal. 2017, 7, 1841-1845, 10.1021/acscatal.7b00022
201. 10 -related electronic configurations. Energy Environ. Sci. 2009, 2, 364-386, 10.1039/b816677n
202. 10 Configuration. J. Phys. Chem. B 2004, 108, 4369-4375, 10.1021/jp0373189
203. Kalisman, P.; Kauffmann, Y.; Amirav, L. Photochemical oxidation on nanorod photocatalysts. J. Mater. Chem. A 2015, 3, 3261-3265, 10.1039/C4TA06164K
204. 2 Nanocrystals under Visible and UV Light. J. Am. Chem. Soc. 2011, 133, 7264-7267, 10.1021/ja200144w
205. Toroker, M. C.; Carter, E. A. Transition metal oxide alloys as potential solar energy conversion materials. J. Mater. Chem. A 2013, 1, 2474-2484, 10.1039/c2ta00816e
206. Friebel, D.; Louie, M. W.; Bajdich, M.; Sanwald, K. E.; Cai, Y.; Wise, A. M.; Cheng, M.-J.; Sokaras, D.; Weng, T.-C.; Alonso-Mori, R.; Davis, R. C.; Bargar, J. R.; Nørskov, J. K.; Nilsson, A.; Bell, A. T. Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting. J. Am. Chem. Soc. 2015, 137, 1305-1313, 10.1021/ja511559d
207. Trotochaud, L.; Young, S. L.; Ranney, J. K.; Boettcher, S. W. Nickel-Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation. J. Am. Chem. Soc. 2014, 136, 6744-6753, 10.1021/ja502379c
208. 3 in Overall Water Splitting. ACS Catal. 2017, 7, 1610-1614, 10.1021/acscatal.6b03662
209. 2 by metal oxides: defect engineering-perfecting imperfection. Chem. Soc. Rev. 2017, 46, 4631-4644, 10.1039/C7CS00026J
210. 2 with oxygen vacancies: synthesis, properties and photocatalytic applications. Nanoscale 2013, 5, 3601-3614, 10.1039/c3nr00476g
211. 2 Nanorods in Organic Solvent. J. Phys. Chem. C 2014, 118, 25215-25222, 10.1021/jp507383w
212. Li, L.; Yan, J.; Wang, T.; Zhao, Z.-J.; Zhang, J.; Gong, J.; Guan, N. Sub-10 nm rutile titanium dioxide nanoparticles for efficient visible-light-driven photocatalytic hydrogen production. Nat. Commun. 2015, 6, 5881, 10.1038/ncomms6881
213. 4. J. Mater. Chem. A 2017, 5, 6686-6694, 10.1039/C7TA00737J
214. 2 Hydrogenation. Angew. Chem., Int. Ed. 2016, 55, 9548-9552, 10.1002/anie.201602512
215. Kalisman, P.; Houben, L.; Aronovitch, E.; Kauffmann, Y.; Bar-Sadan, M.; Amirav, L. The golden gate to photocatalytic hydrogen production. J. Mater. Chem. A 2015, 3, 19679-19682, 10.1039/C5TA05784A
216. Aronovitch, E.; Kalisman, P.; Mangel, S.; Houben, L.; Amirav, L.; Bar-Sadan, M. Designing Bimetallic Co-Catalysts: A Party of Two. J. Phys. Chem. Lett. 2015, 6, 3760-3764, 10.1021/acs.jpclett.5b01687
217. 2 Reduction. ACS Catal. 2017, 7, 6600-6608, 10.1021/acscatal.7b01648
218. 4. J. Am. Chem. Soc. 2017, 139, 4486-4492, 10.1021/jacs.7b00452
219. Maeda, K. Z-Scheme Water Splitting Using Two Different Semiconductor Photocatalysts. ACS Catal. 2013, 3, 1486-1503, 10.1021/cs4002089
220. 2 evolution. Nat. Commun. 2015, 6, 8647, 10.1038/ncomms9647
221. - shuttle redox mediator. Chem. Commun. 2005, 3829-3831, 10.1039/b505646b
222. Higashi, M.; Abe, R.; Ishikawa, A.; Takata, T.; Ohtani, B.; Domen, K. Z-scheme Overall Water Splitting on Modified-TaON Photocatalysts under Visible Light (λ<500 nm). Chem. Lett. 2008, 37, 138-139, 10.1246/cl.2008.138
223. Zhou, P.; Yu, J.; Jaroniec, M. All-Solid-State Z-Scheme Photocatalytic Systems. Adv. Mater. 2014, 26, 4920-4935, 10.1002/adma.201400288
224. 4, and a Reduced Graphene Oxide Electron Mediator. J. Am. Chem. Soc. 2016, 138, 10260-10264, 10.1021/jacs.6b05304
225. 2 Reduction Activity. Small 2015, 11, 5262-5271, 10.1002/smll.201500926
226. 4: An efficient visible-light-driven photocatalyst for hydrogen evolution. Appl. Catal., B 2016, 198, 154-161, 10.1016/j.apcatb.2016.05.046
227. Qian, K.; Sweeny, B. C.; Johnston-Peck, A. C.; Niu, W.; Graham, J. O.; DuChene, J. S.; Qiu, J.; Wang, Y.-C.; Engelhard, M. H.; Su, D.; Stach, E. A.; Wei, W. D. Surface Plasmon-Driven Water Reduction: Gold Nanoparticle Size Matters. J. Am. Chem. Soc. 2014, 136, 9842-9845, 10.1021/ja504097v
228. Golubev, A. A.; Khlebtsov, B. N.; Rodriguez, R. D.; Chen, Y.; Zahn, D. R. T. Plasmonic Heating Plays a Dominant Role in the Plasmon-Induced Photocatalytic Reduction of 4-Nitrobenzenethiol. J. Phys. Chem. C 2018, 122, 5657-5663, 10.1021/acs.jpcc.7b12101
229. Yu, Y.; Sundaresan, V.; Willets, K. A. Hot Carriers vs. Thermal Effects: Resolving the Enhancement Mechanisms for Plasmon-Mediated Photoelectrochemical Reactions. J. Phys. Chem. C 2018, 122, 5040-5048, 10.1021/acs.jpcc.7b12080
230. Schaadt, D. M.; Feng, B.; Yu, E. T. Enhanced semiconductor optical absorption via surface plasmon excitation in metal nanoparticles. Appl. Phys. Lett. 2005, 86, 063106, 10.1063/1.1855423
231. Jia, C.; Li, X.; Xin, N.; Gong, Y.; Guan, J.; Meng, L.; Meng, S.; Guo, X. Interface-Engineered Plasmonics in Metal/Semiconductor Heterostructures. Adv. Energy Mater. 2016, 6, 1600431, 10.1002/aenm.201600431
232. Li, X.; Zhu, J.; Wei, B. Hybrid nanostructures of metal/two-dimensional nanomaterials for plasmon-enhanced applications. Chem. Soc. Rev. 2016, 45, 3145-3187, 10.1039/C6CS00195E
233. Wang, P.; Huang, B.; Dai, Y.; Whangbo, M.-H. Plasmonic photocatalysts: harvesting visible light with noble metal nanoparticles. Phys. Chem. Chem. Phys. 2012, 14, 9813-9825, 10.1039/c2cp40823f
234. Cushing, S. K.; Li, J.; Meng, F.; Senty, T. R.; Suri, S.; Zhi, M.; Li, M.; Bristow, A. D.; Wu, N. Photocatalytic Activity Enhanced by Plasmonic Resonant Energy Transfer from Metal to Semiconductor. J. Am. Chem. Soc. 2012, 134, 15033-15041, 10.1021/ja305603t
235. 2 onto Gold Nanorods for Plasmon-Enhanced Hydrogen Production from Water Reduction. J. Am. Chem. Soc. 2016, 138, 1114-1117, 10.1021/jacs.5b11341
236. Lou, Z.; Fujitsuka, M.; Majima, T. Pt-Au Triangular Nanoprisms with Strong Dipole Plasmon Resonance for Hydrogen Generation Studied by Single-Particle Spectroscopy. ACS Nano 2016, 10, 6299-6305, 10.1021/acsnano.6b02494
237. 2 coated Au/Ag nanorods with enhanced photocatalytic activity under visible light irradiation. Nanoscale 2013, 5, 4236-4241, 10.1039/c3nr00517h
238. 2/Au nanorod plasmonic photocatalysts with enhanced visible-light photocatalytic activity. Dalton Trans. 2017, 46, 3887-3894, 10.1039/C7DT00345E
239. 4 interface for photoactivity enhancement. Nano Energy 2015, 15, 625-633, 10.1016/j.nanoen.2015.05.024
240. Govorov, A. O.; Richardson, H. H. Generating heat with metal nanoparticles. Nano Today 2007, 2, 30-38, 10.1016/S1748-0132(07)70017-8
241. 2 Photocatalysts with Strong Localization of Plasmonic Near-Fields for Efficient Visible-Light Hydrogen Generation. Adv. Mater. 2012, 24, 2310-2314, 10.1002/adma.201104241
242. Zhang, Y., He, S., Guo, W., Hu, Y., Huang, J., Mulcahy, J. R., Wei, W. D. Surface-Plasmon-Driven Hot Electron Photochemistry. Chem. Rev. 2017, DOI: 10.1021/acs.chemrev.7b00430
243. Kong, X.-T.; Wang, Z.; Govorov, A. O. Plasmonic Nanostars with Hot Spots for Efficient Generation of Hot Electrons under Solar Illumination. Adv. Opt. Mater. 2017, 5, 1600594, 10.1002/adom.201600594
244. Zhang, H.; Govorov, A. O. Optical Generation of Hot Plasmonic Carriers in Metal Nanocrystals: The Effects of Shape and Field Enhancement. J. Phys. Chem. C 2014, 118, 7606-7614, 10.1021/jp500009k
245. Manjavacas, A.; Liu, J. G.; Kulkarni, V.; Nordlander, P. Plasmon-Induced Hot Carriers in Metallic Nanoparticles. ACS Nano 2014, 8, 7630-7638, 10.1021/nn502445f
246. Xie, W.; Schlücker, S. Hot electron-induced reduction of small molecules on photorecycling metal surfaces. Nat. Commun. 2015, 6, 7570, 10.1038/ncomms8570
247. Zheng, Z.; Tachikawa, T.; Majima, T. Single-Particle Study of Pt-Modified Au Nanorods for Plasmon-Enhanced Hydrogen Generation in Visible to Near-Infrared Region. J. Am. Chem. Soc. 2014, 136, 6870-6873, 10.1021/ja502704n
248. Lou, Z.; Fujitsuka, M.; Majima, T. Two-Dimensional Au-Nanoprism/Reduced Graphene Oxide/Pt-Nanoframe as Plasmonic Photocatalysts with Multiplasmon Modes Boosting Hot Electron Transfer for Hydrogen Generation. J. Phys. Chem. Lett. 2017, 8, 844-849, 10.1021/acs.jpclett.6b03045
249. Lou, Z.; Kim, S.; Zhang, P.; Shi, X.; Fujitsuka, M.; Majima, T. In Situ Observation of Single Au Triangular Nanoprism Etching to Various Shapes for Plasmonic Photocatalytic Hydrogen Generation. ACS Nano 2017, 11, 968-974, 10.1021/acsnano.6b07581
250. Hung, S.-F.; Yu, Y.-C.; Suen, N.-T.; Tzeng, G.-Q.; Tung, C.-W.; Hsu, Y.-Y.; Hsu, C.-S.; Chang, C.-K.; Chan, T.-S.; Sheu, H.-S.; Lee, J.-F.; Chen, H. M. The synergistic effect of a well-defined Au@Pt core-shell nanostructure toward photocatalytic hydrogen generation: interface engineering to improve the Schottky barrier and hydrogen-evolved kinetics. Chem. Commun. 2016, 52, 1567-1570, 10.1039/C5CC08547K
251. Maeda, K. Photocatalytic water splitting using semiconductor particles: History and recent developments. J. Photochem. Photobiol., C 2011, 12, 237-268, 10.1016/j.jphotochemrev.2011.07.001
252. Gomes Silva, C.; Juárez, R.; Marino, T.; Molinari, R.; García, H. Influence of Excitation Wavelength (UV or Visible Light) on the Photocatalytic Activity of Titania Containing Gold Nanoparticles for the Generation of Hydrogen or Oxygen from Water. J. Am. Chem. Soc. 2011, 133, 595-602, 10.1021/ja1086358
253. 2 Nanoparticles. J. Am. Chem. Soc. 2007, 129, 14852-14853, 10.1021/ja076134v
254. Wu, K.; Chen, J.; McBride, J. R.; Lian, T. Efficient hot-electron transfer by a plasmon-induced interfacial charge-transfer transition. Science 2015, 349, 632-635, 10.1126/science.aac5443
255. Kriegel, I.; Scotognella, F.; Manna, L. Plasmonic doped semiconductor nanocrystals: Properties, fabrication, applications and perspectives. Phys. Rep. 2017, 674, 1-52, 10.1016/j.physrep.2017.01.003
256. Mubeen, S.; Lee, J.; Singh, N.; Krämer, S.; Stucky, G. D.; Moskovits, M. An autonomous photosynthetic device in which all charge carriers derive from surface plasmons. Nat. Nanotechnol. 2013, 8, 247, 10.1038/nnano.2013.18
257. 2 with Surface Plasmons. Nano Lett. 2015, 15, 2132-2136, 10.1021/acs.nanolett.5b00111
258. 2 Nanohybrids via Whispering Gallery Mode Resonances for Photocatalytic Water Splitting. ACS Nano 2016, 10, 4496-4503, 10.1021/acsnano.6b00263
259. Ma, L.; Chen, K.; Nan, F.; Wang, J. H.; Yang, D. J.; Zhou, L.; Wang, Q. Q. Improved Hydrogen Production of Au-Pt-CdS Hetero-Nanostructures by Efficient Plasmon-Induced Multipathway Electron Transfer. Adv. Funct. Mater. 2016, 26, 6076-6083, 10.1002/adfm.201601651
260. 2 Yolk-Shell as Plasmonic Photocatalyst Boosting Multi-Scattering with Enhanced Hydrogen Evolution. ACS Appl. Mater. Interfaces 2016, 8, 31738-31745, 10.1021/acsami.6b12940
261. Sigle, D. O.; Zhang, L.; Ithurria, S.; Dubertret, B.; Baumberg, J. J. Ultrathin CdSe in Plasmonic Nanogaps for Enhanced Photocatalytic Water Splitting. J. Phys. Chem. Lett. 2015, 6, 1099-1103, 10.1021/acs.jpclett.5b00279
262. 2 to Hydrocarbon Fuels via Plasmon-Enhanced Absorption and Metallic Interband Transitions. ACS Catal. 2011, 1, 929-936, 10.1021/cs2001434
263. Ye, W.; Long, R.; Huang, H.; Xiong, Y. Plasmonic nanostructures in solar energy conversion. J. Mater. Chem. C 2017, 5, 1008-1021, 10.1039/C6TC04847A
264. Zheng, X.; Zhang, L. Photonic nanostructures for solar energy conversion. Energy Environ. Sci. 2016, 9, 2511-2532, 10.1039/C6EE01182A
265. 2 Reduction Catalyzed by Metal-Organic-Framework-Derived Iron Nanoparticles Encapsulated by Ultrathin Carbon Layers. Adv. Mater. 2016, 28, 3703-3710, 10.1002/adma.201505187
266. 2 Conversion within Metal-Organic Frameworks under Visible Light. J. Am. Chem. Soc. 2017, 139, 356-362, 10.1021/jacs.6b11027
267. 2 into solar fuel. APL Mater. 2015, 3, 104416, 10.1063/1.4930043
268. 2 to solar fuel via a local electromagnetic field. Nanoscale 2015, 7, 14232-14236, 10.1039/C5NR02943K
269. 2 Nanofibers with Plasmon-Enhanced Photocatalytic Activities for Solar-to-Fuel Conversion. J. Phys. Chem. C 2013, 117, 25939-25947, 10.1021/jp409311x
270. 2 Hydrogenation. Small 2017, 13, 1602583, 10.1002/smll.201602583
271. Huang, C.; Li, Z.; Zou, Z. A perspective on perovskite oxide semiconductor catalysts for gas phase photoreduction of carbon dioxide. MRS Commun. 2016, 6, 216-225, 10.1557/mrc.2016.32
272. Kanhere, P.; Chen, Z. A Review on Visible Light Active Perovskite-Based Photocatalysts. Molecules 2014, 19, 19995, 10.3390/molecules191219995
273. Moriya, Y.; Takata, T.; Domen, K. Recent progress in the development of (oxy)nitride photocatalysts for water splitting under visible-light irradiation. Coord. Chem. Rev. 2013, 257, 1957-1969, 10.1016/j.ccr.2013.01.021
274. Shi, J.; Guo, L. ABO3-based photocatalysts for water splitting. Prog. Nat. Sci. 2012, 22, 592-615, 10.1016/j.pnsc.2012.12.002
275. Wang, W.; Tade, M. O.; Shao, Z. Research progress of perovskite materials in photocatalysis- and photovoltaics-related energy conversion and environmental treatment. Chem. Soc. Rev. 2015, 44, 5371-5408, 10.1039/C5CS00113G
276. Zhang, G.; Liu, G.; Wang, L.; Irvine, J. T. S. Inorganic perovskite photocatalysts for solar energy utilization. Chem. Soc. Rev. 2016, 45, 5951-5984, 10.1039/C5CS00769K
277. Weng, B.; Xiao, Z.; Meng, W.; Grice, C. R.; Poudel, T.; Deng, X.; Yan, Y. Bandgap Engineering of Barium Bismuth Niobate Double Perovskite for Photoelectrochemical Water Oxidation. Adv. Energy Mater. 2017, 7, 1602260, 10.1002/aenm.201602260
278. Zhu, Y.; Zhou, W.; Zhong, Y.; Bu, Y.; Chen, X.; Zhong, Q.; Liu, M.; Shao, Z. A Perovskite Nanorod as Bifunctional Electrocatalyst for Overall Water Splitting. Adv. Energy Mater. 2017, 7, 1602122, 10.1002/aenm.201602122
279. 2 over niobate and titanate photocatalysts with (111) plane-type layered perovskite structure. Energy Environ. Sci. 2009, 2, 306-314, 10.1039/b818922f
280. 3. J. Phys. Chem. C 2012, 116, 7621-7628, 10.1021/jp210106b
281. 3 under visible-light irradiation: an insight from hybrid density-functional calculations. Phys. Chem. Chem. Phys. 2012, 14, 1876-1880, 10.1039/c2cp23348g
282. 3 under Visible Light Irradiation. J. Phys. Chem. B 2004, 108, 8992-8995, 10.1021/jp049556p
283. Eng, H. W.; Barnes, P. W.; Auer, B. M.; Woodward, P. M. Investigations of the electronic structure of d0 transition metal oxides belonging to the perovskite family. J. Solid State Chem. 2003, 175, 94-109, 10.1016/S0022-4596(03)00289-5
284. 3) powder. 1. Structure of the catalysts. J. Phys. Chem. 1986, 90, 292-295, 10.1021/j100274a018
285. 3 Thin Film for Efficient Water Splitting. Adv. Funct. Mater. 2010, 20, 4287-4294, 10.1002/adfm.201000931
286. 3 Catalyst for the Photocatalytic Splitting of Water. Angew. Chem., Int. Ed. 2006, 45, 1420-1422, 10.1002/anie.200503316
287. 3 (A = Li, Na, and K). J. Phys. Chem. B 2001, 105, 4285-4292, 10.1021/jp004386b
288. Pan, C.; Takata, T.; Nakabayashi, M.; Matsumoto, T.; Shibata, N.; Ikuhara, Y.; Domen, K. A Complex Perovskite-Type Oxynitride: The First Photocatalyst for Water Splitting Operable at up to 600 nm. Angew. Chem., Int. Ed. 2015, 54, 2955-2959, 10.1002/anie.201410961
289. 8Cl: A Stable Visible Light Responsive Photocatalyst for Water Splitting. J. Am. Chem. Soc. 2016, 138, 2082-2085, 10.1021/jacs.5b11191
290. Takata, T.; Furumi, Y.; Shinohara, K.; Tanaka, A.; Hara, M.; Kondo, J. N.; Domen, K. Photocatalytic Decomposition of Water on Spontaneously Hydrated Layered Perovskites. Chem. Mater. 1997, 9, 1063-1064, 10.1021/cm960612b
291. 7 (M = Nb and Ta) Photocatalysts with Layered Perovskite Structures: Factors Affecting the Photocatalytic Activity. J. Phys. Chem. B 2000, 104, 571-575, 10.1021/jp9919056
292. Crespo-Quesada, M.; Pazos-Outón, L. M.; Warnan, J.; Kuehnel, M. F.; Friend, R. H.; Reisner, E. Metal-encapsulated organolead halide perovskite photocathode for solar-driven hydrogen evolution in water. Nat. Commun. 2016, 7, 12555, 10.1038/ncomms12555
293. Kuang, P.-Y.; Zheng, P.-X.; Liu, Z.-Q.; Lei, J.-L.; Wu, H.; Li, N.; Ma, T.-Y. Embedding Au Quantum Dots in Rimous Cadmium Sulfide Nanospheres for Enhanced Photocatalytic Hydrogen Evolution. Small 2016, 12, 6735-6744, 10.1002/smll.201602870
294. Li, X.; Yu, J.; Jaroniec, M. Hierarchical photocatalysts. Chem. Soc. Rev. 2016, 45, 2603-2636, 10.1039/C5CS00838G
295. Tee, S. Y.; Win, K. Y.; Teo, W. S.; Koh, L.-D.; Liu, S.; Teng, C. P.; Han, M.-Y. Recent Progress in Energy-Driven Water Splitting. Adv. Sci. 2017, 4, 1600337, 10.1002/advs.201600337
296. Jafari, T.; Moharreri, E.; Amin, A.; Miao, R.; Song, W.; Suib, S. Photocatalytic Water Splitting-The Untamed Dream: A Review of Recent Advances. Molecules 2016, 21, 900, 10.3390/molecules21070900
297. Zhao, H.; Jin, L.; Zhou, Y.; Bandar, A.; Fan, Z.; Govorov, A. O.; Mi, Z.; Sun, S.; Rosei, F.; Vomiero, A. Green synthesis of near infrared core/shell quantum dots for photocatalytic hydrogen production. Nanotechnology 2016, 27, 495405, 10.1088/0957-4484/27/49/495405
298. Martindale, B. C. M.; Hutton, G. A. M.; Caputo, C. A.; Reisner, E. Solar Hydrogen Production Using Carbon Quantum Dots and a Molecular Nickel Catalyst. J. Am. Chem. Soc. 2015, 137, 6018-6025, 10.1021/jacs.5b01650
299. Zhang, Z.; Zheng, T.; Li, X.; Xu, J.; Zeng, H. Progress of Carbon Quantum Dots in Photocatalysis Applications. Part. Part. Syst. Char. 2016, 33, 457-472, 10.1002/ppsc.201500243
300. Li, X.; Rui, M.; Song, J.; Shen, Z.; Zeng, H. Carbon and Graphene Quantum Dots for Optoelectronic and Energy Devices: A Review. Adv. Funct. Mater. 2015, 25, 4929-4947, 10.1002/adfm.201501250
301. 2 hybrid modified with hydrogenase for visible light driven hydrogen production. Chem. Sci. 2015, 6, 5690-5694, 10.1039/C5SC02017D
302. 4-based photocatalysts. Appl. Surf. Sci. 2017, 391, 72-123, 10.1016/j.apsusc.2016.07.030
303. Zhou, L.; Zhang, H.; Sun, H.; Liu, S.; Tade, M. O.; Wang, S.; Jin, W. Recent advances in non-metal modification of graphitic carbon nitride for photocatalysis: a historic review. Catal. Sci. Technol. 2016, 6, 7002-7023, 10.1039/C6CY01195K
304. 2 Conversion to Solar Fuels. ACS Catal. 2016, 6, 7485-7527, 10.1021/acscatal.6b02089
305. Wang, X.; Maeda, K.; Thomas, A.; Takanabe, K.; Xin, G.; Carlsson, J. M.; Domen, K.; Antonietti, M. A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater. 2009, 8, 76, 10.1038/nmat2317
306. Thomas, A.; Fischer, A.; Goettmann, F.; Antonietti, M.; Muller, J.-O.; Schlogl, R.; Carlsson, J. M. Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts. J. Mater. Chem. 2008, 18, 4893-4908, 10.1039/b800274f
307. Lotsch, B. V.; Döblinger, M.; Sehnert, J.; Seyfarth, L.; Senker, J.; Oeckler, O.; Schnick, W. Unmasking Melon by a Complementary Approach Employing Electron Diffraction, Solid-State NMR Spectroscopy, and Theoretical Calculations-Structural Characterization of a Carbon Nitride Polymer. Chem.-Eur. J. 2007, 13, 4969-4980, 10.1002/chem.200601759
308. Zhang, M.; Duan, Y.; Jia, H.; Wang, F.; Wang, L.; Su, Z.; Wang, C. Defective graphitic carbon nitride synthesized by controllable co-polymerization with enhanced visible light photocatalytic hydrogen evolution. Catal. Sci. Technol. 2017, 7, 452-458, 10.1039/C6CY02318E
309. Li, X.; Hartley, G.; Ward, A. J.; Young, P. A.; Masters, A. F.; Maschmeyer, T. Hydrogenated Defects in Graphitic Carbon Nitride Nanosheets for Improved Photocatalytic Hydrogen Evolution. J. Phys. Chem. C 2015, 119, 14938-14946, 10.1021/acs.jpcc.5b03538
310. 4 realizing an efficient photoreactivity. Nanoscale 2015, 7, 5152-5156, 10.1039/C4NR07645A
311. 4 Nanostructured Flowers with Superior Photocatalytic Hydrogen Evolution Performance. ACS Appl. Mater. Interfaces 2015, 7, 16850-16856, 10.1021/acsami.5b04947
312. 4 photocatalyst. Phys. Chem. Chem. Phys. 2016, 18, 19457-19463, 10.1039/C6CP02832B
313. 4 for Efficient Visible Light Photocatalytic Hydrogen Production. Chem. Mater. 2015, 27, 4930-4933, 10.1021/acs.chemmater.5b02344
314. 2 Generation Efficiencies. ACS Catal. 2016, 6, 3365-3371, 10.1021/acscatal.6b00879
315. Lau, V. W.-h.; Moudrakovski, I.; Botari, T.; Weinberger, S.; Mesch, M. B.; Duppel, V.; Senker, J.; Blum, V.; Lotsch, B. V. Rational design of carbon nitride photocatalysts by identification of cyanamide defects as catalytically relevant sites. Nat. Commun. 2016, 7, 12165, 10.1038/ncomms12165
316. Lau, V. W.-h.; Yu, V. W.-z.; Ehrat, F.; Botari, T.; Moudrakovski, I.; Simon, T.; Duppel, V.; Medina, E.; Stolarczyk, J.; Feldmann, J.; Blum, V.; Lotsch, B. V. Urea-Modified Carbon Nitrides: Enhancing Photocatalytic Hydrogen Evolution by Rational Defect Engineering. Adv. Energy Mater. 2017, 7, 1602251, 10.1002/aenm.201602251
317. 2 production. Energy Environ. Sci. 2015, 8, 3708-3717, 10.1039/C5EE02650D
318. Zhang, G.; Zhang, M.; Ye, X.; Qiu, X.; Lin, S.; Wang, X. Iodine Modified Carbon Nitride Semiconductors as Visible Light Photocatalysts for Hydrogen Evolution. Adv. Mater. 2014, 26, 805-809, 10.1002/adma.201303611
319. Huang, Z.-F.; Song, J.; Pan, L.; Wang, Z.; Zhang, X.; Zou, J.-J.; Mi, W.; Zhang, X.; Wang, L. Carbon nitride with simultaneous porous network and O-doping for efficient solar-energy-driven hydrogen evolution. Nano Energy 2015, 12, 646-656, 10.1016/j.nanoen.2015.01.043
320. Guo, S.; Deng, Z.; Li, M.; Jiang, B.; Tian, C.; Pan, Q.; Fu, H. Phosphorus-Doped Carbon Nitride Tubes with a Layered Micro-nanostructure for Enhanced Visible-Light Photocatalytic Hydrogen Evolution. Angew. Chem., Int. Ed. 2016, 55, 1830-1834, 10.1002/anie.201508505
321. Li, X.; Masters, A. F.; Maschmeyer, T. Polymeric carbon nitride for solar hydrogen production. Chem. Commun. 2017, 53, 7438-7446, 10.1039/C7CC02532G
322. 4/NiS Hybrid Photocatalysts with Enhanced Hydrogen Evolution Activity. J. Phys. Chem. C 2014, 118, 7801-7807, 10.1021/jp5000232
323. 4 nanocomposite: an artificial Z-scheme visible-light photocatalytic system using nanocarbon as the electron mediator. Chem. Commun. 2015, 51, 17144-17147, 10.1039/C5CC05323D
324. 2 nanocomposite. J. Mater. Chem. A 2014, 2, 7960-7966, 10.1039/C4TA00275J
325. Yang, X.; Tang, H.; Xu, J.; Antonietti, M.; Shalom, M. Silver Phosphate/Graphitic Carbon Nitride as an Efficient Photocatalytic Tandem System for Oxygen Evolution. ChemSusChem 2015, 8, 1350-1358, 10.1002/cssc.201403168
326. Liu, J.; Liu, Y.; Liu, N.; Han, Y.; Zhang, X.; Huang, H.; Lifshitz, Y.; Lee, S.-T.; Zhong, J.; Kang, Z. Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Science 2015, 347, 970-974, 10.1126/science.aaa3145
327. 4 nanosheet hybrid with reinforced photocurrent for photocatalyst applications. Dalton Trans. 2014, 43, 6295-6299, 10.1039/c3dt53106f
328. 4 and Graphene Oxide Nanosheets with Excellent Visible-Light Photocatalytic Performance. ACS Appl. Mater. Interfaces 2015, 7, 25693-25701, 10.1021/acsami.5b09503
329. Yeh, T.-F.; Teng, C.-Y.; Chen, S.-J.; Teng, H. Nitrogen-Doped Graphene Oxide Quantum Dots as Photocatalysts for Overall Water-Splitting under Visible Light Illumination. Adv. Mater. 2014, 26, 3297-3303, 10.1002/adma.201305299
330. Chen, L.-C.; Teng, C.-Y.; Lin, C.-Y.; Chang, H.-Y.; Chen, S.-J.; Teng, H. Architecting Nitrogen Functionalities on Graphene Oxide Photocatalysts for Boosting Hydrogen Production in Water Decomposition Process. Adv. Energy Mater. 2016, 6, 1600719, 10.1002/aenm.201600719
331. Yang, P.; Zhao, J.; Wang, J.; Cui, H.; Li, L.; Zhu, Z. Pure carbon nanodots for excellent photocatalytic hydrogen generation. RSC Adv. 2015, 5, 21332-21335, 10.1039/C5RA01924A
332. Zhu, S.; Song, Y.; Zhao, X.; Shao, J.; Zhang, J.; Yang, B. The photoluminescence mechanism in carbon dots (graphene quantum dots, carbon nanodots, and polymer dots): current state and future perspective. Nano Res. 2015, 8, 355-381, 10.1007/s12274-014-0644-3
333. Fu, M.; Ehrat, F.; Wang, Y.; Milowska, K. Z.; Reckmeier, C.; Rogach, A. L.; Stolarczyk, J. K.; Urban, A. S.; Feldmann, J. Carbon Dots: A Unique Fluorescent Cocktail of Polycyclic Aromatic Hydrocarbons. Nano Lett. 2015, 15, 6030-6035, 10.1021/acs.nanolett.5b02215
334. Wang, Q.; Li, J.; Bai, Y.; Lian, J.; Huang, H.; Li, Z.; Lei, Z.; Shangguan, W. Photochemical preparation of Cd/CdS photocatalysts and their efficient photocatalytic hydrogen production under visible light irradiation. Green Chem. 2014, 16, 2728-2735, 10.1039/C3GC42466A
335. Reckmeier, C. J.; Schneider, J.; Susha, A. S.; Rogach, A. L. Luminescent colloidal carbon dots: optical properties and effects of doping. Opt. Express 2016, 24, A312-A340, 10.1364/OE.24.00A312
336. Kozák, O.; Sudolská, M.; Pramanik, G.; Cígler, P.; Otyepka, M.; Zbořil, R. Photoluminescent Carbon Nanostructures. Chem. Mater. 2016, 28, 4085-4128, 10.1021/acs.chemmater.6b01372
337. Bhattacharyya, S.; Ehrat, F.; Urban, P.; Teves, R.; Wyrwich, R.; Döblinger, M.; Feldmann, J.; Urban, A. S.; Stolarczyk, J. K. Effect of nitrogen atom positioning on the trade-off between emissive and photocatalytic properties of carbon dots. Nat. Commun. 2017, 8, 1401, 10.1038/s41467-017-01463-x
338. Martindale, B. C. M.; Hutton, G. A. M.; Caputo, C. A.; Prantl, S.; Godin, R.; Durrant, J. R.; Reisner, E. Enhancing Light Absorption and Charge Transfer Efficiency in Carbon Dots through Graphitization and Core Nitrogen Doping. Angew. Chem., Int. Ed. 2017, 56, 6459-6463, 10.1002/anie.201700949
339. Hutton, G. A. M.; Martindale, B. C. M.; Reisner, E. Carbon dots as photosensitisers for solar-driven catalysis. Chem. Soc. Rev. 2017, 46, 6111-6123, 10.1039/C7CS00235A
340. 2-based photocatalysts and dye-sensitized solar cells. Nano Energy 2013, 2, 545-552, 10.1016/j.nanoen.2013.07.010
341. Yu, H.; Shi, R.; Zhao, Y.; Waterhouse, G. I. N.; Wu, L.-Z.; Tung, C.-H.; Zhang, T. Smart Utilization of Carbon Dots in Semiconductor Photocatalysis. Adv. Mater. 2016, 28, 9454-9477, 10.1002/adma.201602581
342. Singh, A. K.; Mathew, K.; Zhuang, H. L.; Hennig, R. G. Computational Screening of 2D Materials for Photocatalysis. J. Phys. Chem. Lett. 2015, 6, 1087-1098, 10.1021/jz502646d
343. Li, Y.; Li, Y.-L.; Sa, B.; Ahuja, R. Review of two-dimensional materials for photocatalytic water splitting from a theoretical perspective. Catal. Sci. Technol. 2017, 7, 545-559, 10.1039/C6CY02178F
344. Luo, B.; Liu, G.; Wang, L. Recent advances in 2D materials for photocatalysis. Nanoscale 2016, 8, 6904-6920, 10.1039/C6NR00546B
345. Rahman, M. Z.; Kwong, C. W.; Davey, K.; Qiao, S. Z. 2D phosphorene as a water splitting photocatalyst: fundamentals to applications. Energy Environ. Sci. 2016, 9, 709-728, 10.1039/C5EE03732H
346. 2 Nanoparticles. J. Am. Chem. Soc. 2012, 134, 6575-6578, 10.1021/ja302846n
347. 2. Nanoscale 2017, 9, 1520-1526, 10.1039/C6NR07740D
348. 2 Ultrathin Nanosheets for Efficient Photocatalytic Hydrogen Evolution. ACS Appl. Mater. Interfaces 2017, 9, 23635-23646, 10.1021/acsami.7b03673
349. Zhu, M.; Osakada, Y.; Kim, S.; Fujitsuka, M.; Majima, T. Black phosphorus: A promising two dimensional visible and near-infrared-activated photocatalyst for hydrogen evolution. Appl. Catal., B 2017, 217, 285-292, 10.1016/j.apcatb.2017.06.002
350. Zhukovskyi, M.; Tongying, P.; Yashan, H.; Wang, Y.; Kuno, M. Efficient Photocatalytic Hydrogen Generation from Ni Nanoparticle Decorated CdS Nanosheets. ACS Catal. 2015, 5, 6615-6623, 10.1021/acscatal.5b01812
351. 2 Nanosheets. J. Am. Chem. Soc. 2015, 137, 7365-7370, 10.1021/jacs.5b01732
352. 2 photocatalysis in hydrogen evolution. Nanoscale 2015, 7, 4482-4488, 10.1039/C4NR07303G
353. 2 hybrid structures for efficient photocatalytical hydrogen production via strongly plasmonic coupling effect. Nano Energy 2016, 30, 549-558, 10.1016/j.nanoen.2016.10.047
354. 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction. J. Am. Chem. Soc. 2011, 133, 7296-7299, 10.1021/ja201269b
355. 2/AlN(GaN) Heterostructures. J. Phys. Chem. C 2014, 118, 17594-17599, 10.1021/jp5038014
356. 2 as Cocatalyst under Visible Light Irradiation. J. Am. Chem. Soc. 2008, 130, 7176-7177, 10.1021/ja8007825
357. 2 Nanoparticles as Catalyst for Hydrogen Evolution. J. Am. Chem. Soc. 2005, 127, 5308-5309, 10.1021/ja0504690
358. Zhu, M.; Osakada, Y.; Kim, S.; Fujitsuka, M.; Majima, T. Black phosphorus: A promising two dimensional visible and near-infrared-activated photocatalyst for hydrogen evolution. Appl. Catal., B 2017, 217, 285-292, 10.1016/j.apcatb.2017.06.002
359. Guo, Z.; Zhou, J.; Zhu, L.; Sun, Z. MXene: a promising photocatalyst for water splitting. J. Mater. Chem. A 2016, 4, 11446-11452, 10.1039/C6TA04414J
360. 2 reduction. J. Mater. Chem. A 2017, 5, 12899-12903, 10.1039/C7TA03557H
361. 2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production. Nat. Commun. 2017, 8, 13907, 10.1038/ncomms13907
362. 2C (MXene) Composites and Their Use as Photocatalysts for Hydrogen Evolution. ChemSusChem 2018, 11, 688-699, 10.1002/cssc.201702317
363. Stolarczyk, J. K.; Deak, A.; Brougham, D. F. Nanoparticle Clusters: Assembly and Control Over Internal Order, Current Capabilities, and Future Potential. Adv. Mater. 2016, 28, 5400-5424, 10.1002/adma.201505350
364. 2 and ZnO Nanoparticles. Environ. Sci. Technol. 2012, 46, 6934-6941, 10.1021/es202009h
365. Hotze, E. M.; Bottero, J.-Y.; Wiesner, M. R. Theoretical Framework for Nanoparticle Reactivity as a Function of Aggregation State. Langmuir 2010, 26, 11170-11175, 10.1021/la9046963
366. 2 Nanoparticles. J. Phys. Chem. C 2008, 112, 20451-20457, 10.1021/jp808541v
367. 2 Crystalline Nanoparticles Yields Effective Conduction Pathways for Photogenerated Charges. J. Phys. Chem. Lett. 2012, 3, 1422-1427, 10.1021/jz3005128
368. 2. J. Phys. Chem. Lett. 2013, 4, 189-194, 10.1021/jz301881d
369. Li, X.-B.; Gao, Y.-J.; Wang, Y.; Zhan, F.; Zhang, X.-Y.; Kong, Q.; Zhao, N.-J.; Guo, Q.; Wu, H.-L.; Li, Z.-J.; Tao, Y.; Zhang, J.-P.; Chen, B.; Tung, C.-H.; Wu, L.-Z. Self-assembled Framework Enhances Electronic Communication of Ultra-small Sized Nanoparticles for Exceptional Solar Hydrogen Evolution. J. Am. Chem. Soc. 2017, 139, 4789-4796, 10.1021/jacs.6b12976
370. Wang, H.; Miao, J.-J.; Zhu, J.-M.; Ma, H.-M.; Zhu, J.-J.; Chen, H.-Y. Mesoporous Spherical Aggregates of Anatase Nanocrystals with Wormhole-like Framework Structures: Their Chemical Fabrication, Characterization, and Photocatalytic Performance. Langmuir 2004, 20, 11738-11747, 10.1021/la0477892
371. 4 supraparticles: construction of dual-level pores for Pt-catalyzed enantioselective hydrogenation. Polym. Chem. 2015, 6, 2892-2899, 10.1039/C4PY01611D