Copper-catalyzed cyanomethylation of allylic alcohols with concomitant 1,2-aryl migration: Efficient synthesis of functionalized ketones containing an α-quaternary center

Angewandte Chemie - International Edition

Volumn 54, Issue 10, 2015, Pages 3132-3135

  Bunescu, Ala ^a   WangDr, Qian ^a   Zhu, Jieping ^a  

^a EPFL   (Switzerland)

Author keywords

Alkyl nitriles; Allylic alcohols; Copper triflate; Ketones; Neophyl rearrangement

Indexed keywords

CATALYSIS; COPPER; CYANIDES;

ALKYL NITRILES; ALLYLIC ALCOHOL; CARBONYL FUNCTIONALITY; COPPER TRIFLATE; EFFICIENT SYNTHESIS; INTERMOLECULAR ADDITIONS; MECHANISTIC STUDIES; NEOPHYL REARRANGEMENT;

KETONES;

EID: 85027934449     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201411657     Document Type: Article

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