Lignocellulosics as sustainable resources for production of bioplastics – A review

Journal of Cleaner Production

Volumn 162, Issue , 2017, Pages 646-664

  Brodin, Malin ^a   Vallejos, María ^b   Opedal, Mihaela Tanase ^a   Area, María Cristina ^b   Chinga Carrasco, Gary ^a  

^a Papir og fiberinstituttet AS   (Norway)

^b Materials Institute of Misiones IMAM (CONICET UNaM) University of Misiones   (Argentina)

Author keywords

Biomass; Bioplastics; Biorefinery; Forestry resources; Fractionation; Sustainability

Indexed keywords

BIOMASS; CELLULOSE; ELASTOMERS; FORESTRY; FRACTIONATION; LIGNIN; OILS AND FATS; PURIFICATION; SUSTAINABLE DEVELOPMENT; TIMBER;

BIO-PLASTICS; BIOPLASTICS PRODUCTION; BIOREFINERIES; FORESTRY RESOURCES; LIGNOCELLULOSIC RESOURCES; PURIFICATION PROCESS; SUSTAINABLE RESOURCES; SUSTAINABLE UTILIZATION;

REINFORCED PLASTICS;

BIOMASS; FORESTRY; FRACTIONATION; RESOURCES;

EID: 85024089375     PISSN: 09596526     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jclepro.2017.05.209     Document Type: Review

References (175)

1. Abidin, Z.Z., Awang Biak, D.R., Mohamed, H., Harun, M.Y., Solid-liquid extraction in biorefinery. Separation and Purification Technologies in Biorefineries, 2013, John Wiley & Sons, Ltd, Chichester, UK, 351–374.
2. Adekunle, A., Orsat, V., Raghavan, V., Lignocellulosic bioethanol: a review and design conceptualization study of production from cassava peels. Renew. Sustain. Energy Rev. 64 (2016), 518–530.
3. Aeschelmann, F., Carus, M., Bio-based Building Blocks and Polymers in the World – Capacities, Production and Applications: Status Quo and Trends toward 2020 (Short Version). 2015, Michael Carus (V.i.S.d.P.), nova-Institute.
4. Al-Dajani, W.W., Tschirner, U., Jensen, T., Pre-extraction of hemicelluloses and subsequent kraft pulping. Part II: acid- and autohydrolysis. Tappi J. 8:9 (2009), 30–37.
5. Almeida, J.R.M., Bertilsson, M., Gorwa-Grauslund, M.F., Gorsich, S., Liden, G., Metabolic effects of furaldehydes and impacts on biotechnological processes. Appl. Microbiol. Biotechnol. 82 (2009), 625–638.
6. Alonso, M.V., Oliet, M., Rodriquez, F., Astarola, G., Echeverria, J.M., Use of methylolated softwood ammonium lignosulfonate as partial substitute of phenol in resol resins manufacture. J. Appl. Polym. Sci. 94:2 (2004), 643–650.
7. Álvarez-Chávez, C.R., Edwards, S., Moure-Eraso, R., Geiser, K., Sustainability of bio-based plastics: general comparative analysis and recommendations for improvement. J. Clean. Prod. 23 (2012), 47–56.
8. Alvira, P., Tomás-Pejó, M.B., Ballesteros, M., Negro, M.J., Pretreatment technologies for an efficient bioethanol production process based on enzymatic hydrolysis: a review. Bioresour. Technol. 101 (2010), 4851–4861.
9. Arikan, E.B., Ozsoy, H.D., A review: investigation of bioplastics. J. Civ. Eng. Arch. 9 (2015), 188–192.
10. Auras, R., Harte, B., Selke, S., An overview of polylactides as packaging materials. Macromol. Biosci. 4 (2004), 835–864.
11. Auvergne, R., Caillol, S., David, G., Boutevin, B., Pascault, J.-P., Biobased thermosetting epoxy: present and future. Chem. Rev. 114 (2014), 1082–1115.
12. Bajpai, P., Pretreatment of lignocellulosic biomass for biofuel production. Bajpai, P., (eds.) SpringerBriefs in Molecular Science, 2016, Springer Singapore, Singapore.
13. Banerjee, S., Mudliar, S., Sen, R., Giri, B., Satpute, D., Chakrabarti, T., Pandey, R.A., Review: Commercializing lignocellulosic bioethanol: technology bottlenecks and possible remedies. Biofuels, Bioprod. Biorefin 4 (2010), 77–93.
14. Banerjee, S., Sen, R., Pandey, R.A., Chakrabarti, T., Evaluation of wet air oxidation as a pretreatment strategy for bioethanol production from rice husk and process optimization. Biomass Bioenergy 33 (2009), 1680–1686.
15. Bechthold, I., Bretz, K., Kabasci, S., Kopitzky, R., Springer, A., Succinic acid: a new platform chemical for biobased polymers from renewable resources. Chem. Eng. Technol. 31:5 (2008), 647–654.
16. Berrios, M., Siles, J.A., Martín, M.A., Martín, A., Ion exchange. Separation and Purification Technologies in Biorefineries, 2013, John Wiley & Sons, Ltd, Chichester, UK, 149–165.
17. Bozell, J.J., Petersen, G.R., Technology development for the production of biobased products from biorefinery carbohydrates – the US department of energy's “Top 10” revisited. Green Chem. 12 (2010), 539–554.
18. Brandt, A., Gräsvik, J., Hallett, J.P., Welton, T., Deconstruction of lignocellulosic biomass with ionic liquids. Green Chem. 15 (2013), 550–583.
19. Briassoulis, D., Dejean, C., Critical review of norms and standards for biodegradable agricultural plastics part I. Biodegradation in soil. J. Polym. Environ. 18:3 (2010), 384–400.
20. Brodeur, G., Yau, E., Badal, K., Collier, J., Ramachandran, K.B., Ramakrishnan, S., Chemical and physicochemical pretreatment of lignocellulosic biomass: a review. Enz. Res., 2011, 1–17.
21. Brodin, M., Johnsen, P.O., Hindersland, L.K., Chinga-Carrasco, G., The biocomposite structure of decorative laminates. 10th International Conference on Composite Science and Technology, 2–4 September, Lisboa, Portugal, 2015.
22. Broeren, M., Production of Bio-ethylene. Technology Brief. Energy Technology Systems Analysis Programme (ETSAP). 2013, International Energy Agency (IEA) www.irena.org/Publications.
23. Brunner, G., Brunner, Gerd, (eds.) Hydrothermal and Supercritical Water Processes, 2014, Elsevier B.V.
24. Buntara, T., Noel, S., Phua, P.H., Melián-Cabrera, I., de Vries, J.G., Heeres, H.J., Caprolactam from renewable resources: catalytic conversion of 5-hydroxymethylfurfural into caprolactone. Angew. Chem. Int. Ed. 50 (2011), 7083–7087.
25. Carlson, T.R., Cheng, Y.-T., Jae, J., Huber, G.W., Production of green aromatics and olefins by catalytic fast pyrolysis of wood sawdust. Energy Environ. Sci., 4, 2011, 145.
26. Carrillo, C.A., Laine, J., Rojas, O.J., Microemulsion systems for fiber deconstruction into cellulose nanofibrils. ACS Appl. Mater. Interfaces 6 (2014), 22622–22627.
27. Carrillo, C.A., Saloni, D., Lucia, L.A., Hubbe, M.A., Rojas, O.J., Capillary flooding of wood with microemulsions from Winsor I systems. J. Colloid Interface Sci. 381 (2012), 171–179.
28. Carrillo, C.A., Saloni, D., Rojas, O.J., Evaluation of O/W microemulsions to penetrate the capillary structure of woody biomass: interplay between composition and formulation in green processing. Green Chem., 15, 2013, 3377.
29. Carriquiry, M.A., Du, X., Timilsina, G.R., Second-Generation Biofuels Economics and Policies. Policy Research Working Paper 5406, 2010, 57 http://www.globalbioenergy.org/uploads/media/1008_WB_-_Second-generation_biofuels.pdf (Accessed 2 April 2017).
30. Carus, M., Bio-based materials – technical, economic and market data on the bio-based economy. Technology and Polymerdagene, September 20–21 Gjøvik, Norway, 2016.
31. Cateto, A.C., Barreiro, M.F., Rodrigues, A.E., Belgacem, M.N., Optimization study of lignin oxypropylation in view of the preparation of polyurethane rigid foams. Ind. Eng. Chem. Res. 48:5 (2009), 2583–2589.
32. Cetin, N.S., Özmen, N., Use of organosolv lignin in phenol-formaldehyde resins for particle board production I. Organosolv lignin modified resins. Int. J. Adhes. Adhes. 22:6 (2002), 477–480.
33. Cetin, N.S., Özmen, N., Use of organosolv lignin in phenol-formaldehyde resins for particle board production II. Particleboard production and properties. Int. J. Adhes. Adhes. 22:6 (2002), 481–486.
34. Chen, G.-Q., A microbial polyhydroxyalkanoates (PHA) based vio- and materials industry. Chem. Soc. Rev. 38 (2009), 2434–2446.
35. Chen, H., Chen, H., (eds.) Lignocellulose Biorefinery Engineering: Principles and Applications, 2015, Elsevier Ltd., Cambridge, U.K.
36. Chen, M.-J., Li, R.-M., Zhang, X.-Q., Feng, J., Feng, J., Liu, C.-F., Shi, Q.-S., Homogeneous transesterification of sugar cane bagasse towards sustainable plastics. ACS Sustain. Chem. Eng. 5:1 (2017), 360–366.
37. Chirat, C., Lachenal, D., Dufresne, A., Biorefinery in a kraft pulp mill: from bioethanol to celullose nanocrystals. Cellul. Chem. Technol. 44:1–3 (2010), 59–64.
38. Choi, J., Lee, S.Y., Factors affecting the economics of polyhydroxyalkanoate production by bacterial fermentation. Appl. Microbiol. Biotechnol. 51 (1999), 13–21.
39. Christopher, L.P., Integrated forest biorefineries: current state and development potential. Christopher, L.P., (eds.) Integrated Forest Biorefineries: Challenges and Opportunities, 2013, Royal Society of Chemistry, Cambridge, UK (Chapter 1).
40. Conde-Mejía, C., Jiménez-Gutiérreza, A., El-Halwagi, A.A., Comparison of pretreatment methods for bioethanol production from lignocellulosic materials. Process Saf. Environ. Prot. 90:3 (2012), 189–202.
41. Costa Lopes, A.M., João, K.G., Morais, A.R.C., Bogel-Łukasik, E., Bogel-Łukasik, R., Ionic liquids as a tool for lignocellulosic biomass fractionation. Sustain. Chem. Process, 1, 2013, 3.
42. Dros, A.B., Larue, O., Reimond, A., De Campo, F., Pera-Titus, M., Hexamethylenediamine (HDMA) fossil- vs. bio-based routes: an economic and life cycle assessment comparative study. Green Chem. 17:11 (2015), 4760–4772.
43. Du, X., Lucia, L.A., Ghiladi, R.A., A novel approach for rapid preparation of monophasic microemulsions that facilitates penetration of woody biomass. ACS Sustain. Chem. Eng. 4 (2016), 1665–1672.
44. Eerhart, A.J.J.E., Faaij, A.P.C., Patel, M.K., Replacing fossil based PET with biobased PEF, process analysis, energy and GHG balance. Energy Environ. Sci. 5 (2012), 6407–6422.
45. European Bioplastics, Oxo-biodegradable Plastics and Other Plastics with Additives for Degradation. 2015 http://docs.european-bioplastics.org/2016/publications/bp/EUBP_bp_additive-mediated_plastics.pdf Publication Date: October 2015. (Accessed 22 February 2017).
46. Fache, M., Boutevin, B., Caillol, S., Vanillin, a key-intermediate of biobased polymers. Eur. Polym. J. 68 (2015), 488–502.
47. Fang, X.M., Simone, C.D., Vaccaro, E., Huang, S.J., Scola, D.A., Ring-opening polymerization of epsilon-caprolactam and epsilon-caprolactone via microwave irradiation. J. Polym. Sci. Part A Polym. Chem. 40 (2002), 2264–2275.
48. Feldman, D., Banu, D., Natansohn, A., Wang, J., Structure-properties relations of thermally cured epoxy-lignin polyphenols. J. Appl. Polym. Sci. 42 (1991), 1537–1550.
49. Feng, P., Chen, F., Preparation and characterization of acetic acid lignin-based epoxy blends. BioResour 7:3 (2012), 2860–2870.
50. Fengel, D., Wegener, G., Wood - Chemistry, Ultrastructure, Reactions. 1989, Walter de Gruyter, Berlin.
51. Foyer, G., Chanfi, B.-H., Boutevin, B., Caillol, S., David, G., New method for the synthesis of formaldehyde-free phenolic resins from lignin-based aldehyde precursors. Eur. Polym. J. 74 (2016), 296–309.
52. Frost, J. W., 2005. Synthesis of caprolactam from lysine. Patent, WO2005123669.
53. Gallezot, P., Conversion of biomass to selected chemical products. Chem. Soc. Rev. 41 (2012), 1538–1558.
54. Garça, J., Pereira, H., Diglycerol alkenedioates in suberin: building units of a poly(acylglycerol) polyester. Biomacromol 1 (2000), 519–522.
55. García Cubero, M.T., González-Benito, G., Indacoechea, I., Coca, M., Bolado, S., Effect of ozonolysis pretreatment on enzymatic digestibility of wheat and rye straw. Bioresour. Technol. 100:4 (2009), 1608–1613.
56. Grand View Research, Inc, Lactic Acid and Poly Lactic Acid (PLA) Market Analysis by Application (Packaging, Agriculture, Transport, Electronics, Textiles) and Segment Forecasts to 2020. 2015.
57. Groeger, C., Sabra, W., Zeng, A.-P., Introduction to bioconversion and downstream processing: principles and process examples. Aresta, M., Dibenedetto, A., Dumeignil, F., (eds.) Biorefineries, 2015, De Gruyter, Berlin, München, Boston, 81–108.
58. Gröndahl, M., Eriksson, L., Gatenholm, P., Material properties of plastisized hardwood xylans for potential application as oxygen barrier films. Biomacromol 5 (2004), 1528–1535.
59. 2 and ionic liquids for the pretreatment of lignocellulosic biomass in bioethanol production. Environ. Technol. 34:13–14 (2013), 1735–1749.
60. Gu, T., Pretreatment of lignocellulosic biomass using supercritical carbon dioxide as a green solvent. Gu, T., (eds.) Green Biomass Pretreatment for Biofuels Production, 2013, Spinger.
61. Gulbrandsen, T., Johnsen, I., Opedal, M.T., Toven, K., Øyaas, K., Pranovich, A., Mikkola, J.-P., Hoff, B.H., Extracting hemicelluloses from softwood and bagasse as oligosaccharides using pure water and mictowave heating. Cellul. Chem. Technol. 49:2 (2015), 117–126.
62. Haro, P., Ollero, P., Trippe, F., Technoeconomic assessment of potential processes for bio-ethylene production. Fuel Process. Technol. 114 (2013), 35–48.
63. Hartman, J., Albertsson, A.-C., Söderqvist Lindblad, M., Sjöberg, J., Oxygen barrier materials from renewable sources: material properties of softwood hemicellulose-based films. J. Appl. Polym. Sci. 100 (2006), 2985–2991.
64. Heggset, E.B., Syverud, K., Øyaas, K., Novel pretreatment pathways for dissolution of lignocellulosic biomass based on ionic liquid and low temperature alkaline treatment. Biomass Bioenergy 93 (2016), 194–200.
65. Hidalgo-Ruz, V., Gutow, L., Thompson, R.C., Thiel, M., Microplastics in the marine environment: a review og the methods used for identification and quantification. Environ. Sci. Technol. 46 (2012), 3060–3075.
66. Hofmann, K., Glasser, W.G., Engineering plastics from lignin. 21. Synthesis and properties of epoxidized lignin-poly(propylene oxide) copolymers. J. Wood Chem. Technol. 13:1 (1993), 73–95.
67. Hosseinaei, O., Wang, S., Enayati, A.A., Rials, G.T., Effects of hemicellulose extraction on properties of wood flour and wood-plastic composites. Compos. Part A Appl. Sci. Manuf. 43:4 (2012), 686–694.
68. Huang, H.J., Ramaswamy, S., Al-Dajani, W.W., Tschirner, U., Process modeling and analysis of pulp mill-based integrated biorefinery with hemicellulose pre-extraction for ethanol production: a comparative study. Bioresour. Technol. 101:2 (2010), 624–631.
69. Huang, H.-J., Ramaswamy, S., Overview of biomass conversion processes and separation and purification technologies in biorefineries. Separation and Purification Technologies in Biorefineries, 2013, John Wiley & Sons, Ltd, Chichester, UK, 1–36.
70. Hutley, T.J., Ouederni, M., Polyolefins – the history and economic impact. Al-Ali AlMa'adeed, M., Krupa, I., (eds.) Polyolefin Compounds and Materials, 2016, Springer International Publishing Switzerland.
71. Ibeh, C.C., Phenol-formaldehyde resins. Goodman, S.H., (eds.) Handbook of Thermoset Plastics, second ed., 1999, Elsevier Inc.
72. IfBB report, Biopolymers, Facts and Statistics 2016. third ed., 2016, 46 ISSN (Online) 2510-3431.
73. Iles, A., Martin, A.N., Expanding bioplastics production: sustainable business innovation in the chemical industry. J. Clean. Prod. 45 (2013), 38–49.
74. Jabeen, N., Majid, I., Nayik, G.A., Bioplastics and food packaging: a review. Cogent Food Agric., 1, 2015 1117749, 1–6.
75. Jacquet, N., Maniet, G., Vanderghem, C., Delvigne, F., Richel, A., Application of steam explosion as pretreatment on lignocellulosic material: a review. Ind. Eng. Chem. Res. 54:10 (2015), 2593–2598.
76. Jiang, H., Chen, Q., Ge, J., Zhang, Y., Efficient extraction and characterization of polymeric hemicelluloses from hybrid poplar. Carbohydr. Polym. 101 (2014), 1005–1012.
77. Jin, Y., Ruan, X., Cheng, X., Lü, Q., Liquefaction of lignin by polyethylene glycol and glycerol. Bioresour. Technol. 102 (2011), 3581–3583.
78. Kale, G., Kijchavengkul, T., Auras, R., Rubino, M., Selke, S.E., Singh, S.P., Compostability of bioplastic packaging materials: an overview. Macromol. Biosci. 7 (2007), 255–277.
79. Kawaguchi, H., Hasunuma, T., Ogino, C., Kondo, A., Bioprocessing of bio-based chemicals produced from lignocellulosic feedstocks. Curr. Opin. Biotechnol. 42 (2016), 30–39.
80. Keenan, T.M., Nakas, J.P., Tanenbaum, S.W., Polyhydroxyalkanoate copolymers from forest biomass. J. Ind. Microbiol. Biotechnol. 33 (2006), 616–626.
81. Kim, J.S., Lee, Y.Y., Kim, T.H., A review on alkaline pretreatment technology for bioconversion of lignocellulosic biomass. Bioresour. Technol. 199 (2016), 42–48.
82. Kimura, K., Horikoshi, Y., Bio-based polymers. Fujitsu Sci. Tech. J. 41:2 (2005), 173–180.
83. Koike, T., Progress in development of epoxy resin systems based on wood biomass in Japan. Polym. Eng. Sci. 52 (2012), 701–717.
84. Kouisni, L., Fang, Y., Paleologou, M., Behzad, A., Jalal, H., Zhang, Y., Wang, X., Kraft lignin recovery and its use in the preparation of lignin-based phenol formaldehyde resins for plywood. Cell. Chem. Technol. 45:7–8 (2011), 515–520.
85. Kumar, P., Barrett, D.M., Delwiche, M.J., Stroeve, P., Methods for pretreatment of lignocellulosic biomass for efficient hydrolysis and biofuel production. Ind. Eng. Chem. Res. 48 (2009), 3713–3729.
86. Kuo, P.-Y., Sain, M., Yan, N., Synthesis and characterization of an extractive-based bio-epoxy resin from beetle infested Pinus contorta bark. Green Chem. 16 (2014), 3483–3493.
87. Labet, M., Thielemans, W., Synthesis of polycaprolactone: a review. Chem. Soc. Rev. 38 (2009), 3484–3504.
88. Lasprilla, A.J.R., Martinez, G.A.R., Lunelli, B.H., Jardini, A.L., Filho, R.M., Poly-lactic acid synthesis for application in biomedical devices – a review. Biotechnol. Adv. 30:1 (2012), 321–328.
89. Laurichesse, S., Avérous, L., Chemical modification of lignins: towards biobased polymers. Prog. Polym. Sci. 39 (2014), 1266–1290.
90. Lei, H., Pizzi, A., Du, G., Environmentally friendly mixed tannin/lignin wood resins. J. Appl. Polym. Sci. 107:1 (2008), 203–209.
91. Lei, Z., Chen, B., Distillation. Separation and Purification Technologies in Biorefineries, 2013, John Wiley & Sons, Ltd, Chichester, UK, 37–60.
92. Li, Y., Ragauskas, A.J., Kraft lignin-based rigid polyurethane foam. J. Wood Chem. Technol. 32:3 (2012), 210–224.
93. Lim, L.-T., Auras, R., Rubino, M., Processing technologies for poly(lactic acid). Prog. Polym. Sci. 33 (2008), 820–852.
94. Liu, S., Wang, Y., Buyondo, J.P., Wang, Y., Garver, M., Biochemical conversion. Stuart, P.R., El-Halwagi, M.M., (eds.) Integrated Biorefineries. Design, Analysis, and Optimization, 2013, CRC Press, Taylor & Francis Group, 591–649.
95. Lovett, J., de Bie, F., Sustainable Sourcing of Feedstocks for Bioplastics. Corbion Whitepaper, 2016, 17 Accessed at: http://www.corbion.com/media/550170/corbion_whitepaper_feedstock_sourcing_11.pdf.
96. Mancera, C., El Mansouri, N.-E., Vilaseca, F., Ferrando, F., Salvado, J., The effect of lignin as a natural adhesive on the physico-mechanical properties of Vitis vinifera fiberboards. BioResour 6:3 (2011), 2851–2860.
97. Martín Medina, C.O., Marcet, M., Thomsen, A.B., Comparison between wet oxidation and steam explosion as pretreatment methods for enzymatic hydrolysis of sugarcane bagasse. Bioresour 3:3 (2008), 670–683.
98. Mehta, R., Kumar, V., Bhunia, H., Upadhyay, S.N., Synthesis of poly(lactic acid): a review. J. Macromol. Sci. Part C. Polym. Rev. 45 (2005), 325–349.
99. Meikleham, N., Pizzi, A., Stephanou, A., Induced accelerated autocondensation of polyflavonoid tannins for phenolic polycondensates. I. 13C-NMR, 29Si-NMR, x-ray, and polarimetry studies and mechanism. J. Appl. Polym. Sci. 54:12 (1994), 1827–1845.
100. Miller, J., Faleiros, M., Lignin: technology, applications, and markets. RISI Latin American Pulp & Paper Outlook Conference, São Paulo, August 15–17, 2016.
101. Mohammad, A.W., Teow, Y.H., Ang, W.L., Chung, Y.T., Oatley-Radcliffe, D.L., Hilal, N., Nanofiltration membranes review: recent advances and future prospects. Desalination 356 (2015), 226–254, 10.1016/j.desal.2014.10.043.
102. Mordor Intelligence LLP, Global Thermoplastics Market – Segmented by Type, Application and Geography – Trends and Forecast (2015-2020). 2016.
103. Mordor Intelligence LLP, Global Thermosetting Plastics Market – Segmented by Type, Industry and Geography – Trends and Forecasts (2015-2020). 2016.
104. Mosiewicki, M., Aranguren, M.I., Burrajo, J., Thermal and mechanical properties of woodflour/tannin adhesive composites. J. Appl. Polym. Sci. 91:5 (2004), 3074–3082.
105. Moubarik, A., Charrier, B., Allal, A., Charrier, F., Pizzi, A., Development and optimization of a new formaldehyde-free cornstarch and tanninwood adhesive. Eur. J. Wood Prod. 68 (2010), 167–177.
106. Mozheiko, L.N., Gromova, M.F., Bakalo, L.A., Sergeyeva, V.N., Polyurethanes prepared from oxypropylates lignin. Polym. Sci. U.S.S.R 23:1 (1981), 141–149.
107. Nanda, S., Azargohar, R., Dalai, A.K., Kozinski, J.A., An assessment on the sustainability of lignocellulosic biomass for biorefining. Renew. Sust. Energy Rev. 50 (2015), 925–941.
108. Narayan, R., Biobased and Biodegradable plastics: rationale, drivers, and technology exemplars., second ed. Khemani, K., Scholz, C., (eds.) Degradable Polymers and Materials: Principles and Practice, vol. 1114, 2012, American Chemical Society, 13–31 (Chapter 2).
109. Nhien, L.C., Long, N.V.D., Kim, S., Lee, M., Design and optimization of intensified biorefinery process for furfural production through a systematic procedure. Biochem. Eng. J. 116 (2016), 166–175.
110. Nhien, L.C., Long, N.V.D., Lee, M., Novel heat–integrated and intensified biorefinery process for cellulosic ethanol production from lignocellulosic biomass. Energy Convers. Manag., 2016, 10.1016/j.enconman.2016.09.077 (in press).
111. Nitzsche, R., Budzinski, M., Gröngröft, A., Techno-economic assessment of a wood-based biorefinery concept for the production of polymer-grade ethylene, organosolv lignin and fuel. Bioresour. Technol. 200 (2016), 928–939.
112. Obruca, S., Benesova, P., Marsalek, L., Marova, I., Use of lignocellulosic materials for PHA production. Chem. Biochem. Eng. Q. 29 (2015), 135–144.
113. OECD, Policies for Bioplastics in the Context of a Bioeconomy. OECD Science, Technology and Industry Policy Papers, No. 10, 2013, OECD Publishing, 10.1787/5k3xpf9rrw6d-en.
114. Ogunwusi, A.A., Potentials of industrial utilization of bark. J. Nat. Sci. Res. 3:5 (2013), 106–115.
115. Olivier-Bourbigou, H., Magna, L., Morvan, D., Ionic liquids and catalysis: recent progress from knowledge to applications. Appl. Catal. A Gen. 373 (2010), 1–56.
116. Olsson, A., Lindström, M., Iversen, T., Lipase-catalyzed synthesis of an epoxy-functionalized polyester from the suberin monomer cis-9,10-epoxy-18-hydroxyoctadecanoic acid. Biomacromol 8 (2007), 757–760.
117. Ooshima, H., Aso, K., Harano, Y., Yamamoto, T., Microwave treatment of cellulosic materials for their enzymatic hydrolysis. Biotechnol. Lett. 6 (1984), 289–294.
118. Paunonen, S., Strength and barrier enhancement of cellophane and cellulose derivative films: a review. BioResour 8:2 (2013), 3098–3121.
119. Peleteiro, S., Rivas, S., Alonso, J.L., Santos, V., Parajó, J.C., Utilization of ionic liquids in lignocellulose biorefineries as agents for separation, derivatization, fractionation, or pretreatment. J. Agric. Food Chem. 63:37 (2015), 8093–8102.
120. Perez, J.M., Rodríguez, F., Alonso, M.V., Oliet, M., Time-temperature-transformation cure diagrams of phenol-formaldehyde and lignin-phenol-formaldehyde novolac resins. J. Appl. Polym. Sci. 119:4 (2011), 2275–2282.
121. Philp, J.C., Bartsev, A., Ritchie, R.J., Baucher, M.A., Guy, K., Bioplastics science from a policy vantage point. New Biotechnol. 30:6 (2013), 635–646.
122. Philp, J.C., Ritchie, R.J., Guy, K., Biobased plastics in a bioeconomy. Trends Biotechnol. 31:2 (2013), 65–67.
123. Pizzi, A., Recent developments in eco-efficient bio-based adhesives for wood bonding: opportunities and issues. J. Adhes. Sci. Technol. 20:8 (2006), 829–846.
124. Puls, J., Wilson, S.A., Hölter, D., Degradation of cellulose acetate-based materials: a review. J. Polym. Environ. 19 (2011), 152–165.
125. Raquez, J.-M., Deléglise, M., Lacrampe, M.-F., Krawczak, P., Thermosetting (bio)materials derived from renewable resources: a critical review. Prog. Polym. Sci. 35:4 (2010), 487–509.
126. Rasal, R.M., Janorkar, A.V., Hirt, D.E., Poly(lactic acid) modifications. Prog. Polym. Sci., 2010, 338–356.
127. Rødsrud, G., Borregaard's Orchestrating Biorefinery Concepts Process Chemistry and Biotechnology in a Symphonic Interaction. 2012 http://www.indbiotech.no/sites/default/files/Gudbrand%20R%C3%B8dserud%20IBNW%2011%20June%2012%20-%20Borregaard.pdf (Accessed 22 February 2017).
128. TM demo plant for co-production of bioethanol and green chemicals. Nordic Baltic Bioenergy Conference, May 21-22, Oslo, 2013 Accessed: http://nobio.no/upload_dir/pics/GudbrandRoedsrud.pdf (Accessed 22 February 2017).
129. Sadhukhan, J., Ng, K.S., Martinez, E., Biorefneries and chemical processes: design, integration and sustainability analysis. Sadhukhan, J., Ng, K.S., Martinez, E., (eds.) Biorefneries and Chemical Processes: Design, Integration and Sustainability Analysis, 2014, John Wiley & Sons, Ltd., 425–473.
130. Saini, A., Aggarwal, N.K., Sharma, A., Yadav, A., Prospects for irradiation in cellulosic ethanol production. Biotechnol. Res. Int., 2015 Article ID 157139.
131. Schild, G., Sixta, H., Testova, L., Multifunctional Alkaline Pulping, delignification and hemicellulose extraction. Cellul. Chem. Technol. 44:1–3 (2010), 35–45.
132. Shao, P., Huang, R.Y.M., Polymeric membrane pervaporation. J. Membr. Sci. 287:2 (2007), 162–179, 10.1016/j.memsci.2006.10.043.
133. Sheldon, A., Green and sustainable manufacture of chemicals from biomass: state of the art. Green Chem. 16 (2014), 950–963.
134. Silva, J.A., Tobella, L.M., Becerra, J., Godoy, F., Matrínez, M.A., Biosynthesis of poly-β-hydroxyalkanoate by Brevundimonas vesicularis LMG P-23615 and Sphingopyxis macrogoltabida LMG 17324 using acid-hydrolyzed sawdust as carbon source. J. Biosci. Bioeng. 103:6 (2007), 542–546.
135. Singh, J., Suhag, M., Dhaka, A., Augmented digestion of lignocellulose by steam explosion, acid and alkaline pretreatment methods: a review. Carbohydr. Polym. 117 (2015), 624–631.
136. Sjöström, E., Wood Chemistry, Fundamentals and Applications. second ed., 1993, Academic Press, New York/London.
137. Snell, K.D., Peoples, O.P., PHA bioplastic: a value-added coproduct for biomass biorefineries. Biofuels, Bioprod. Biorefining 3 (2009), 456–467.
138. Song, J.H., Murphy, R.J., Narayan, R., Davies, G.B.H., Biodegradable and compostable alternatives to conventional plastics. Phil. Trans. R. Soc. B 364 (2009), 2127–2139.
139. Sousa, A.F., Gandini, A., Silvestre, A.J.D., Pascoal Neto, C., Cruz Pinto, J.J.C., Eckerman, C., Holmbom, B., Novel suberin-based biopolyesters: from synthesis to properties. J. Polym. Sci. Part A Polym. Chem. 49 (2011), 2281–2291.
140. Stoffel, R.B., Felissia, F.E., Silva Curvelo, A.A., Gassa, L.M., Area, M.C., Optimization of sequential alkaline–acid fractionation of pine sawdust for a biorefinery. Ind. Crops Prod. 61 (2014), 160–168.
141. Su, Y., Brown, H.M., Huang, X., Zhou, X., Amonette, J.E., Zhang, Z.C., Single-step conversion of cellulose to 5-hydroxymethylfurfural (HMF), a versatile platform chemical. Appl. Catal. A Gen. 361 (2009), 117–177.
142. Sugimoto, T., Magara, K., Hosoya, S., Osawa, S., Shimoda, T., Nishibori, K., Ozone pretreatment of lignocellulosic materials for ethanol production: improvement of enzymatic susceptibility of softwood. Holzforschung 63:5 (2009), 537–543.
143. Suriyamongkol, P., Weselake, R., Narine, S., Moloney, M., Shah, S., Biotechnological approaches for the production of polyhydroxyalkanoates in microorganisms and plants – a review. Biotechnol. Adv., 2007, 148–175.
144. Thompson, R.C., Swan, S.H., Moore, C.J., vom Saal, F.S., Our plastic age. Phil. Trans. R. Soc. B 364 (2009), 1973–1976.
145. Thring, R.W., Vanderlaan, M.N., Griffin, S.L., Polyurethanes from Alcell® lignin. Biomass Bioenergy 13:3 (1997), 125–132.
146. Torron, S., Semlitsch, S., Martinelle, M., Johansson, M., Polymer thermosets from multifunctional polyester resins based on renewable monomers. Macromol. Chem. Phys. 215 (2014), 2198–2206.
147. Turunen, M., Alvila, L., Pakkanen, T.T., Rainio, J., Modification of phenol-formaldehyde resol resins by lignin, starch and urea. J. Appl. Polym. Sci. 88 (2003), 582–588.
148. Ur Rehman, M.S., Kim, I., Chisti, Y., Han, J.I., Use of ultrasound in the production of bioethanol from lignocellulosic biomass. Energy Educ. Sci. Technol. Part A Energy Sci. Res. 30 (2013), 1391–1410.
149. Valles, G., Second Generation Biofuels Market: State of Play, Trade and Developing Country Perspectives. UNCTAD/DITC/TED/2015/8, 2015, United Nations Publication, 69 http://unctad.org/en/PublicationsLibrary/ditcted2015d8_en.pdf (Accessed 3 April 2017).
150. Vallejos, M.E., Felissia, F.E., Area, M.C., Hydrothermal treatments applied to agro- and forest-industrial waste to produce high added-value compounds. Bioresour, 12(1), 2016.
151. van Heiningen, A., Converting a kraft pulp mill into an integrated forest biorefinery. Pulp Pap. Can. 107:6 (2006), 38–43.
152. van Plutten, R.-J., van der Waal, J.C., de Jong, E., Rasrendra, C.B., Heeres, H.J., de Vries, J.G., Hydroxymethylfurfural, a versatile platform chemical made from renewable resources. Chem. Rev. 113 (2013), 1499–1597.
153. Vardon, D.R., Franden, M.A., Johnson, C.W., Karp, E.M., Guarnieri, M.T., Linger, J.G., Salm, M.J., Strathmann, T.J., Beckham, G.T., Adipic acid production from lignin. Energy Environ. Sci. 8 (2015), 617–628.
154. Vázquez, G., González, J., Freire, S., Antorrena, G., Effect of chemical modification of lignin on the gluebond performance of lignin-phenolic resins. Bioresour. Technol. 60:3 (1997), 191–198.
155. Venkatesan, S., Adsorption. Separation and Purification Technologies in Biorefineries, 2013, John Wiley & Sons, Ltd, Chichester, UK, 101–148.
156. Vilela, C., Sousa, A.F., Fonseca, A.C., Serra, A.C., Coelho, J.F.J., Freire, C.S.R., Silvestre, A.J.D., The quest for sustainable polyesters – insights into the future. Polym. Chem. 5 (2014), 3119–3141.
157. Vink, E.T.H., Rábago, K.R., Glassner, D.A., Gruber, P.R., Application of life cycle assessment to NatureWorksTM polylactic (PLA) production. Polym. Degrad. Stab. 80 (2003), 403–419.
158. Wang, Q., Cai, J., Zhang, L., Xu, M., Cheng, H., Han, C.C., Kuga, S., Xiao, J., Xiao, R., A bioplastic with high strength constructed from a cellulose hydrogel by changing the aggregated structure. J. Mater. Chem. A 1 (2013), 6678–6686.
159. Wang, Y., Widjojo, N., Sukitpaneenit, P., Chung, T.-S., Membrane pervaporation. Separation and Purification Technologies in Biorefineries, 2013, John Wiley & Sons, Ltd, Chichester, UK, 259–299.
160. Wang, Y., Yin, J., Chen, G.-Q., Polyhydroxyalkanoates, challenges and opportunities. Curr. Opin. Biotechnol. 30 (2014), 59–65.
161. Xue, B.-L., Wen, J.-L., Xu, F., Sun, R.-C., Polyols production by chemical modification of autocatalyzed ethanol-water lignin from Betula alnoides. J. Appl. Polym. Sci. 129:1 (2013), 434–442.
162. Yang, S.-T., Lu, C., Extraction-fermentation hybrid (extractive fermentation). Ramaswamy, S., Huang, H.-J., Ramarao, B.V., (eds.) Separation and Purification Technologies in Biorefineries, 2013, John Wiley & Sons, Chichester, UK, 409–437.
163. Yano, H., Sugiyama, J., Nakagaito, A.N., Nogi, M., Matsuura, T., Hikita, M., Handa, K., Optically transparent composites reinforced with networks of bacterial nanofibers. Adv. Mater. 17:2 (2005), 153–155.
164. Yates, M.R., Claire, Y., Barlow, C.Y., Life cycle assessments of biodegradable, commercial biopolymers— a critical review. Resour. Conserv. Recy 78 (2013), 54–66.
165. Yoon, S., Cullinan, H., Krishnagopalan, G., Reductive modification of alkaline pulping of southern pine, integrated with hydrothermal pre-extraction of hemicelluloses. Ind. Eng. Chem. Res. 49 (2010), 5969–5976.
166. Yoon, S., Tunc, S.M., Van Heiningen, A., Near-neutral pre-extraction of hemicelluloses and subsequent kraft pulping of southern mixed hardwoods. Tappi J., 2011, 7–15.
167. Zhang, B., Shahbazi, A., Recent developments in pretreatment technologies for production of lignocellulosic biofuels. J. Pet. Environ. Biotechnol., 2(108), 2011.
168. Zhang, Z., Harrison, M.D.D., Rackemann, W., Dohertya, W.O.S., O'Hara, M., Organosolv pretreatment of plant biomass for enhanced enzymatic saccharification. Green Chem. 18 (2016), 360–381.
169. Zhao, B., Chen, G., Liu, Y., Hu, K., Wu, R., Synthesis of lignin base epoxy resin and its characterization. J. Mater. Sci. Lett. 20 (2001), 859–862.
170. Zhao, H., Holladay, J.E., Brown, H., Zhang, Z.C., Metal chloride in ionic liquid solvents convert sugars to 5-hydroxymethylfurfural. Science 316 (2007), 1597–1600.
171. Zhao, X., Cheng, K., Liu, D., Organosolv pretreatment of lignocellulosic biomass for enzymatic hydrolysis. Appl. Microbiol. Biotechnol. 82 (2009), 815–827.
172. Zhao, Y., Yan, N., Feng, M.W., Bark extractives-based phenol-formaldehyde resins from beetle-infested lodgepole pine. J. Adhes. Sci. Technol. 27:17–18 (2013), 2112–2126.
173. Zheng, Y., Pan, Z., Zhang, R., Overview of biomass pretreatment for cellulosic ethanol. Int. J. Agric. Biol. Eng. 2 (2009), 51–68.
174. Zhu, S., Wu, Y., Chen, Q., Yu, Z., Wang, C., Jin, S., Ding, Y., Wu, G., Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem. 8 (2006), 325–327.
175. Zhu, S., Wu, Y., Yu, Z., Liao, J., Zhang, Y., Pretreatment by microwave/alkali of rice straw and its enzymic hydrolysis. Process Biochem. 40 (2005), 3082–3086.