Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges

Chemical Reviews

Volumn 117, Issue 5, 2017, Pages 4287-4341

  Canepa, Pieremanuele ^a,b   Sai Gautam, Gopalakrishnan ^a,b,c   Hannah, Daniel C ^a   Malik, Rahul ^b   Liu, Miao ^a   Gallagher, Kevin G ^d   Persson, Kristin A ^a   Ceder, Gerbrand ^a,b,c  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b Massachusetts Institute of Technology Cambridge   (United States)

^c Lawrence Berkeley National Laboratory   (United States)

^d ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARACTERIZATION; ELECTRIC BATTERIES; ELECTRODES; INORGANIC COMPOUNDS; LITHIUM-ION BATTERIES; SYSTEMS ANALYSIS;

CATH-ODE MATERIALS; FUTURE CHALLENGES; INTERCALATION BATTERIES; INTERCALATION CATHODES; INTERCALATION MECHANISMS; MATERIAL CHEMISTRY; RIGOROUS ANALYSIS; STATE OF THE ART;

CATHODES;

EID: 85014713058     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/acs.chemrev.6b00614     Document Type: Article

References (341)

1. Nykvist, B.; Nilsson, M. Rapidly falling costs of battery packs for electric vehicles Nat. Clim. Change 2015, 5, 329-332 10.1038/nclimate2564
2. Diouf, B.; Pode, R. Potential of lithium-ion batteries in renewable energy Renewable Energy 2015, 76, 375-380 10.1016/j.renene.2014.11.058
3. Whittingham, M. S. Ultimate Limits to Intercalation Reactions for Lithium Batteries Chem. Rev. 2014, 114, 11414-11443 10.1021/cr5003003
4. Andre, D.; Kim, S.-J.; Lamp, P.; Lux, S. F.; Maglia, F.; Paschos, O.; Stiaszny, B. Future generations of cathode materials: an automotive industry perspective J. Mater. Chem. A 2015, 3, 6709-6732 10.1039/C5TA00361J
5. Thackeray, M. M.; Wolverton, C.; Isaacs, E. D. Electrical energy storage for transportation-approaching the limits of, and going beyond, lithium-ion batteries Energy Environ. Sci. 2012, 5, 7854-7863 10.1039/c2ee21892e
6. Grey, C. P.; Tarascon, J. M. Sustainability and in situ monitoring in battery development Nat. Mater. 2016, 16, 45-56 10.1038/nmat4777
7. Peled, E.; Gorenshtein, A.; Segal, M.; Sternberg, Y. Rechargeable lithium-sulfur battery (extended abstract) J. Power Sources 1989, 26, 269-271 10.1016/0378-7753(89)80133-8
8. Yang, Z.; Zhang, J.; Kintner-Meyer, M. C. W.; Lu, X.; Choi, D.; Lemmon, J. P.; Liu, J. Electrochemical Energy Storage for Green Grid Chem. Rev. 2011, 111, 3577-3613 10.1021/cr100290v
9. 2 and Li-S batteries with high energy storage Nat. Mater. 2011, 11, 19-29 10.1038/nmat3191
10. Nazar, L. F.; Cuisinier, M.; Pang, Q. Lithium-sulfur batteries MRS Bull. 2014, 39, 436-442 10.1557/mrs.2014.86
11. Manthiram, A.; Fu, Y.; Chung, S.-H.; Zu, C.; Su, Y.-S. Rechargeable Lithium-Sulfur Batteries Chem. Rev. 2014, 114, 11751-11787 10.1021/cr500062v
12. Aurbach, D.; Lu, Z.; Schechter, A.; Gofer, Y.; Gizbar, H.; Turgeman, R.; Cohen, Y.; Moshkovich, M.; Levi, E. Prototype systems for rechargeable magnesium batteries Nature 2000, 407, 724-727 10.1038/35037553
13. Yoo, H. D.; Shterenberg, I.; Gofer, Y.; Gershinsky, G.; Pour, N.; Aurbach, D. Mg rechargeable batteries: an on-going challenge Energy Environ. Sci. 2013, 6, 2265-2279 10.1039/c3ee40871j
14. Besenhard, J. O.; Winter, M. Advances in Battery Technology: Rechargeable Magnesium Batteries and Novel Negative-Electrode Materials for Lithium Ion Batteries ChemPhysChem 2002, 3, 155-159 10.1002/1439-7641(20020215)3:2<155::AID-CPHC155>3.0.CO;2-S
15. Ponrouch, A.; Frontera, C.; Bardé, F.; Palacín, M. R. Towards a calcium-based rechargeable battery Nat. Mater. 2015, 15, 169-172 10.1038/nmat4462
16. Aurbach, D. Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries J. Power Sources 2000, 89, 206-218 10.1016/S0378-7753(00)00431-6
17. Aurbach, D.; Zinigrad, E.; Cohen, Y.; Teller, H. A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions Solid State Ionics 2002, 148, 405-416 10.1016/S0167-2738(02)00080-2
18. Larcher, D.; Beattie, S.; Morcrette, M.; Edström, K.; Jumas, J.-C.; Tarascon, J.-M. Recent findings and prospects in the field of pure metals as negative electrodes for Li-ion batteries J. Mater. Chem. 2007, 17, 3759-3772 10.1039/b705421c
19. Dahn, J. http://www.almaden.ibm.com/institute/2009/resources/2009/presentations/JeffDahn-AlmadenInstitute2009.pdf (accessed March 15, 2016).
20. Pour, N.; Gofer, Y.; Major, D. T.; Aurbach, D. Structural analysis of electrolyte solutions for rechargeable Mg batteries by stereoscopic means and DFT calculations J. Am. Chem. Soc. 2011, 133, 6270-6278 10.1021/ja1098512
21. Aurbach, D.; Suresh, G. S.; Levi, E.; Mitelman, A.; Mizrahi, O.; Chusid, O.; Brunelli, M. Progress in Rechargeable Magnesium Battery Technology Adv. Mater. 2007, 19, 4260-4267 10.1002/adma.200701495
22. Aurbach, D.; Gizbar, H.; Schechter, A.; Chusid, O.; Gottlieb, H. E.; Gofer, Y.; Goldberg, I. Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries J. Electrochem. Soc. 2002, 149, A115-A121 10.1149/1.1429925
23. Kim, H. S.; Arthur, T. S.; Allred, G. D.; Zajicek, J.; Newman, J. G.; Rodnyansky, A. E.; Oliver, A. G.; Boggess, W. C.; Muldoon, J. Structure and compatibility of a magnesium electrolyte with a sulphur cathode Nat. Commun. 2011, 2, 427 10.1038/ncomms1435
24. Muldoon, J.; Bucur, C. B.; Oliver, A. G.; Sugimoto, T.; Matsui, M.; Kim, H. S.; Allred, G. D.; Zajicek, J.; Kotani, Y. Electrolyte roadblocks to a magnesium rechargeable battery Energy Environ. Sci. 2012, 5, 5941-5950 10.1039/c2ee03029b
25. Guo, Y.-S.; Zhang, F.; Yang, J.; Wang, F.-F.; NuLi, Y.; Hirano, S.-i. Boron-based electrolyte solutions with wide electrochemical windows for rechargeable magnesium batteries Energy Environ. Sci. 2012, 5, 9100-9106 10.1039/c2ee22509c
26. Guo, Y.-S.; Zhang, F.; Yang, J.; Wang, F.-F. Electrochemical performance of novel electrolyte solutions based on organoboron magnesium salts Electrochem. Commun. 2012, 18, 24-27 10.1016/j.elecom.2012.01.026
27. Doe, R. E.; Han, R.; Hwang, J.; Gmitter, A. J.; Shterenberg, I.; Yoo, H. D.; Pour, N.; Aurbach, D. Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries Chem. Commun. 2014, 50, 243-245 10.1039/C3CC47896C
28. 2+ electrolytes for rechargeable Mg batteries J. Mater. Chem. A 2014, 2, 3430-3438 10.1039/c3ta14825d
29. Barile, C. J.; Barile, E. C.; Zavadil, K. R.; Nuzzo, R. G.; Gewirth, A. A. Electrolytic Conditioning of a Magnesium Aluminum Chloride Complex for Reversible Magnesium Deposition J. Phys. Chem. C 2014, 118, 27623-27630 10.1021/jp506951b
30. Barile, C. J.; Spatney, R.; Zavadil, K. R.; Gewirth, A. A. Investigating the Reversibility of in Situ Generated Magnesium Organohaloaluminates for Magnesium Deposition and Dissolution J. Phys. Chem. C 2014, 118, 10694-10699 10.1021/jp503506c
31. Canepa, P.; Gautam, G. S.; Malik, R.; Jayaraman, S.; Rong, Z.; Zavadil, K. R.; Persson, K.; Ceder, G. Understanding the Initial Stages of Reversible Mg Deposition and Stripping in Inorganic Nonaqueous Electrolytes Chem. Mater. 2015, 27, 3317-3325 10.1021/acs.chemmater.5b00389
32. Canepa, P.; Jayaraman, S.; Cheng, L.; Rajput, N.; Richards, W. D.; Gautam, G. S.; Curtiss, L. A.; Persson, K.; Ceder, G. Elucidating the Structure of the Magnesium Aluminum Chloride Complex electrolyte for Magnesium-ion batteries Energy Environ. Sci. 2015, 8, 3718-3730 10.1039/C5EE02340H
33. See, K. A.; Chapman, K. W.; Zhu, L.; Wiaderek, K. M.; Borkiewicz, O. J.; Barile, C. J.; Chupas, P. J.; Gewirth, A. A. The Interplay of Al and Mg Speciation in Advanced Mg Battery Electrolyte Solutions J. Am. Chem. Soc. 2016, 138, 328-337 10.1021/jacs.5b10987
34. Carter, T. J.; Mohtadi, R.; Arthur, T. S.; Mizuno, F.; Zhang, R.; Shirai, S.; Kampf, J. W. Boron Clusters as Highly Stable Magnesium-Battery Electrolytes Angew. Chem., Int. Ed. 2014, 53, 3173-3177 10.1002/anie.201310317
35. Tutusaus, O.; Mohtadi, R.; Arthur, T. S.; Mizuno, F.; Nelson, E. G.; Sevryugina, Y. V. An Efficient Halogen-Free Electrolyte for Use in Rechargeable Magnesium Batteries Angew. Chem., Int. Ed. 2015, 54, 7900-7904 10.1002/anie.201412202
36. Lapidus, S. H.; Rajput, N. N.; Qu, X.; Chapman, K. W.; Persson, K. A.; Chupas, P. J. Solvation structure and energetics of electrolytes for multivalent energy storage Phys. Chem. Chem. Phys. 2014, 16, 21941-21945 10.1039/C4CP03015J
37. -(TFSI) Based Electrolyte Solutions for Mg Batteries J. Electrochem. Soc. 2015, 162, A7118-A7128 10.1149/2.0161513jes
38. Rajput, N. N.; Qu, X.; Sa, N.; Burrell, A. K.; Persson, K. A. The Coupling between Stability and Ion Pair Formation in Magnesium Electrolytes from First-Principles Quantum Mechanics and Classical Molecular Dynamics J. Am. Chem. Soc. 2015, 137, 3411-3420 10.1021/jacs.5b01004
39. Song, J.; Sahadeo, E.; Noked, M.; Lee, S. B. Mapping the Challenges of Magnesium Battery J. Phys. Chem. Lett. 2016, 7, 1736-1749 10.1021/acs.jpclett.6b00384
40. Lipson, A. L.; Han, S.-D.; Pan, B.; See, K. A.; Gewirth, A. A.; Liao, C.; Vaughey, J. T.; Ingram, B. J. Practical Stability Limits of Magnesium Electrolytes J. Electrochem. Soc. 2016, 163, A2253-A2257 10.1149/2.0451610jes
41. Muldoon, J.; Bucur, C. B.; Oliver, A. G.; Zajicek, J.; Allred, G. D.; Boggess, W. C. Corrosion of magnesium electrolytes: chlorides - the culprit Energy Environ. Sci. 2013, 6, 482-487 10.1039/C2EE23686A
42. Mohtadi, R.; Matsui, M.; Arthur, T. S.; Hwang, S.-J. Magnesium Borohydride: From Hydrogen Storage to Magnesium Battery Angew. Chem., Int. Ed. 2012, 51, 9780-9783 10.1002/anie.201204913
43. Muldoon, J.; Bucur, C. B.; Gregory, T. D. Quest for Nonaqueous multivalent Secondary batteries: Magnesium and Beyond Chem. Rev. 2014, 114, 11683-11720 10.1021/cr500049y
44. Bucur, C. B.; Gregory, T.; Oliver, A. G.; Muldoon, J. Confession of a Magnesium Battery J. Phys. Chem. Lett. 2015, 6, 3578-3591 10.1021/acs.jpclett.5b01219
45. Bucur, C. B.; Gregory, T.; Muldoon, J. Why Grignard’s Century Old Nobel Prize Should Spark Your Curiosity Green Energy and Technology 2015, 611-635 10.1007/978-3-319-15458-9_22
46. Ha, J. H.; Adams, B.; Cho, J.-H.; Duffort, V.; Kim, J. H.; Chung, K. Y.; Cho, B. W.; Nazar, L. F.; Oh, S. H. A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries J. Mater. Chem. A 2016, 4, 7160-7164 10.1039/C6TA01684G
47. Sa, N.; Pan, B.; Saha-Shah, A.; Hubaud, A. A.; Vaughey, J. T.; Baker, L. A.; Liao, C.; Burrell, A. K. Role of Chloride for a Simple, Non-Grignard Mg Electrolyte in Ether-Based Solvents ACS Appl. Mater. Interfaces 2016, 8, 16002-16008 10.1021/acsami.6b03193
48. 2-Based Electrolyte Systems: Understanding Electrolyte-Electrode Interactions for the Development of Mg-Ion Batteries J. Am. Chem. Soc. 2016, 138, 8682-8685 10.1021/jacs.6b04319
49. Giffin, G. A. Ionic liquid-based electrolytes for “beyond lithium” battery technologies J. Mater. Chem. A 2016, 4, 13378-13389 10.1039/C6TA05260F
50. 2 Solutions J. Phys. Chem. C 2016, 120, 19586-19594 10.1021/acs.jpcc.6b07733
51. Tutusaus, O.; Mohtadi, R.; Singh, N.; Arthur, T. S.; Mizuno, F. Study of Electrochemical Phenomena Observed at the Mg Metal/Electrolyte Interface ACS Energy Lett. 2017, 2, 224-229 10.1021/acsenergylett.6b00549
52. Lu, Z.; Schechter, A.; Moshkovich, M.; Aurbach, D. On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions J. Electroanal. Chem. 1999, 466, 203-217 10.1016/S0022-0728(99)00146-1
53. Gregory, T. D.; Hoffman, R. J.; Winter, M. Nonaqueous Electrochemistry of Magnesium J. Electrochem. Soc. 1990, 137, 775-780 10.1149/1.2086553
54. Aurbach, D.; Gizbar, H.; Schechter, A.; Chusid, O.; Gottlieb, H. E.; Gofer, Y.; Goldberg, I. Electrolyte Solutions for Rechargeable Magnesium Batteries Based on Organomagnesium Chloroaluminate Complexes J. Electrochem. Soc. 2002, 149, A115-A121 10.1149/1.1429925
55. Doe, R. E.; Han, R.; Gofer, Y.; Aurbach, D.; Pour, N.; Sterenberg, E. Non-Aqueous Electrolyte for Rechargeable Magnesium Ion Cell. Patent WO2013096827 A1, 2013.
56. Shao, Y.; Liu, T.; Li, G.; Gu, M.; Nie, Z.; Engelhard, M.; Xiao, J.; Lv, D.; Wang, C.; Zhang, J.-G.; Liu, J. Coordination Chemistry in magnesium battery electrolytes: how ligands affect their performance Sci. Rep. 2013, 3, 3130 10.1038/srep03130
57. Peled, E. The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems-The Solid Electrolyte Interphase Model J. Electrochem. Soc. 1979, 126, 2047-2051 10.1149/1.2128859
58. Aurbach, D. The Electrochemical Behavior of Calcium Electrodes in a Few Organic Electrolytes J. Electrochem. Soc. 1991, 138, 3536-3545 10.1149/1.2085455
59. 8 Chevrel Phase Surface Chem. Mater. 2015, 27, 5932-5940 10.1021/acs.chemmater.5b01907
60. Wu, F.; Zhou, H.; Bai, Y.; Wang, H.; Wu, C. Toward 5 V Li-Ion Batteries: Quantum Chemical Calculation and Electrochemical Characterization of Sulfone-Based High-Voltage Electrolytes ACS Appl. Mater. Interfaces 2015, 7, 15098-15107 10.1021/acsami.5b04477
61. Terada, S.; Mandai, T.; Suzuki, S.; Tsuzuki, S.; Watanabe, K.; Kamei, Y.; Ueno, K.; Dokko, K.; Watanabe, M. Thermal and Electrochemical Stability of Tetraglyme-Magnesium Bis(trifluoromethanesulfonyl)amide Complex: Electric Field Effect of Divalent Cation on Solvate Stability J. Phys. Chem. C 2016, 120, 1353-1365 10.1021/acs.jpcc.5b09779
62. 3 Langmuir 2013, 29, 10964-10972 10.1021/la402391f
63. 2 in Diglyme: Implications for Multivalent Electrolytes J. Phys. Chem. C 2016, 120, 3583-3594 10.1021/acs.jpcc.5b08999
64. - in Organic Electrolytes Chem. Mater. 2016, 28, 8268-8277 10.1021/acs.chemmater.6b03227
65. Sa, N.; Rajput, N. N.; Wang, H.; Key, B.; Ferrandon, M.; Srinivasan, V.; Persson, K. A.; Burrell, A. K.; Vaughey, J. T. Concentration dependent electrochemical properties and structural analysis of a simple magnesium electrolyte: magnesium bis(trifluoromethane sulfonyl)imide in diglyme RSC Adv. 2016, 6, 113663-113670 10.1039/C6RA22816J
66. Kumar, N.; Siegel, D. J. Interface-Induced Renormalization of Electrolyte Energy Levels in Magnesium Batteries J. Phys. Chem. Lett. 2016, 7, 874-881 10.1021/acs.jpclett.6b00091
67. Watkins, T.; Kumar, A.; Buttry, D. A. Designer Ionic Liquids for Reversible Electrochemical Deposition/Dissolution of Magnesium J. Am. Chem. Soc. 2016, 138, 641-650 10.1021/jacs.5b11031
68. Saha, P.; Datta, M. K.; Velikokhatnyi, O. I.; Manivannan, A.; Alman, D.; Kumta, P. N. Rechargeable magnesium battery: Current status and key challenges for the future Prog. Mater. Sci. 2014, 66, 1-86 10.1016/j.pmatsci.2014.04.001
69. Huie, M. M.; Bock, D. C.; Takeuchi, E. S.; Marschilok, A. C.; Takeuchi, K. J. Cathode materials for magnesium and magnesium-ion based batteries Coord. Chem. Rev. 2015, 287, 15-27 10.1016/j.ccr.2014.11.005
70. Park, M.-S.; Kim, J.-G.; Kim, Y.-J.; Choi, N.-S.; Kim, J.-S. Recent Advances in Rechargeable Magnesium Battery Technology: A Review of the Field’s Current Status and Prospects Isr. J. Chem. 2015, 55, 570-585 10.1002/ijch.201400174
71. Shterenberg, I.; Salama, M.; Gofer, Y.; Levi, E.; Aurbach, D. The Challenge of Developing Rechargeable Magnesium Batteries MRS Bull. 2014, 39, 453-460 10.1557/mrs.2014.61
72. Levi, E.; Levi, M. D.; Chasid, O.; Aurbach, D. A review on the problems of the solid state ions diffusion in cathodes for rechargeable Mg batteries J. Electroceram. 2009, 22, 13-19 10.1007/s10832-007-9370-5
73. Crabtree, G. The joint center for energy storage research: A new paradigm for battery research and development AIP Conf. Proc. 2014, 1652, 112-128 10.1063/1.4916174
74. Gallagher, K. G.; Trask, S. E.; Bauer, C.; Woehrle, T.; Lux, S. F.; Tschech, M.; Lamp, P.; Polzin, B. J.; Ha, S.; Long, B.; Wu, Q.; Lu, W.; Dees, D. W.; Jansen, A. N. Optimizing Areal Capacities through Understanding the Limitations of Lithium-Ion Electrodes J. Electrochem. Soc. 2016, 163, A138-A149 10.1149/2.0321602jes
75. Gallagher, K. G.; Goebel, S.; Greszler, T.; Mathias, M.; Oelerich, W.; Eroglu, D.; Srinivasan, V. Quantifying the promise of lithium-air batteries for electric vehicles Energy Environ. Sci. 2014, 7, 1555-1563 10.1039/c3ee43870h
76. Eroglu, D.; Ha, S.; Gallagher, K. G. Fraction of the theoretical specific energy achieved on pack level for hypothetical battery chemistries J. Power Sources 2014, 267, 14-19 10.1016/j.jpowsour.2014.05.071
77. Nelson, P. A.; Gallagher, K. G.; Bloom, I.; Dees, D. Modeling the Performance and Cost of Lithium-Ion Batteries for Electric-Drive Vehicles; Technical Report ANL-11/32; Argonne National Laboratory: Argonne, IL, September 2011, http://www.ipd.anl.gov/anlpubs/2011/10/71302.pdf, 2012.
78. Gallagher, K. G.; Nelson, P. A.; Dees, D. W. Simplified calculation of the area specific impedance for battery design J. Power Sources 2011, 196, 2289-2297 10.1016/j.jpowsour.2010.10.020
79. Berg, E. J.; Villevieille, C.; Streich, D.; Trabesinger, S.; Novák, P. Rechargeable Batteries: Grasping for the Limits of Chemistry J. Electrochem. Soc. 2015, 162, A2468-A2475 10.1149/2.0081514jes
80. 4 Solid State Ionics 1998, 112, 165-168 10.1016/S0167-2738(98)00167-2
81. Neubauer, J.; Pesaran, A.; Bae, C.; Elder, R.; Cunningham, B. Updating United States Advanced Battery Consortium and Department of Energy battery technology targets for battery electric vehicles J. Power Sources 2014, 271, 614-621 10.1016/j.jpowsour.2014.06.043
82. Christensen, J.; Albertus, P.; Sanchez-Carrera, R. S.; Lohmann, T.; Kozinsky, B.; Liedtke, R.; Ahmed, J.; Kojic, A. A Critical Review of Li/Air Batteries J. Electrochem. Soc. 2012, 159, R1-R30 10.1149/2.086202jes
83. 8 System Probed by ex Situ Synchrotron X-ray Diffraction Chem. Mater. 2007, 19, 5131-5142 10.1021/cm0715489
84. 2+ Powder Diffr. 1999, 14, 25-30 10.1017/S0885715600010265
85. 8 Phys. Rev. B: Condens. Matter Mater. Phys. 1985, 31, 3084-3087 10.1103/PhysRevB.31.3084
86. 8 Chevrel Phases in Aqueous Electrolytes Inorg. Chem. 2016, 55, 3294-3301 10.1021/acs.inorgchem.5b02362
87. 8 Nanocubes and Applications for Advanced Zinc-Ion Batteries ACS Appl. Mater. Interfaces 2016, 8, 13673-13677 10.1021/acsami.6b03197
88. 8 Chem. Mater. 2015, 27, 4926-4929 10.1021/acs.chemmater.5b01918
89. Levi, E.; Gershinsky, G.; Aurbach, D.; Isnard, O.; Ceder, G. New Insight on the Unusually High Ionic Mobility in Chevrel Phases Chem. Mater. 2009, 21, 1390-1399 10.1021/cm900033v
90. Seghir, S.; Stein, N.; Boulanger, C.; Lecuire, J.-M. Electrochemical determination of the diffusion coefficient of cations into Chevrel phase-based electrochemical transfer junction by potential step chronoamperometry and impedance spectroscopy Electrochim. Acta 2011, 56, 2740-2747 10.1016/j.electacta.2010.12.056
91. 8 Chevrel Phase J. Electrochem. Soc. 2004, 151, A1044-A1051 10.1149/1.1758811
92. Rao, C.; Biswas, K. In Essentials of Inorganic Materials Synthesis; 1st ed.; Rao, C.; Biswas, K., Eds.; John Wiley & Sons, Inc.: Hoboken, NJ, 2015.
93. 8 Solid State Ionics 2014, 261, 17-20 10.1016/j.ssi.2014.03.023
94. 8 (M = Ti, Cr, Fe, Ni) Phys. Rev. B: Condens. Matter Mater. Phys. 1999, 60, 16442-16447 10.1103/PhysRevB.60.16442
95. 8 Phys. Rev. B: Condens. Matter Mater. Phys. 2003, 67, 104103-1-104103-10 10.1103/PhysRevB.67.104103
96. 8 (T = S, Se). 1. Crystal Structure of the Sulfides Chem. Mater. 2006, 18, 5492-5503 10.1021/cm061656f
97. 8 (M = Cd, Na, Mn, and Zn, T = S, Se) and Their Cation Mobility Inorg. Chem. 2009, 48, 8751-8758 10.1021/ic900805g
98. 8 Chevrel Phase Cathode for Rechargeable Magnesium Battery J. Electrochem. Soc. 2014, 161, A593-A598 10.1149/2.061404jes
99. 8 Cathodes in Rechargeable Mg Batteries Chem. Mater. 2004, 16, 2832-2838 10.1021/cm034944+
100. 4 Mater. Res. Bull. 1977, 12, 781-788 10.1016/0025-5408(77)90005-8
101. Cheng, Y.; Parent, L. R.; Shao, Y.; Wang, C.; Sprenkle, V. L.; Li, G.; Liu, J. Facile Synthesis of Chevrel Phase Nanocubes and Their Applications for Multivalent Energy Storage Chem. Mater. 2014, 26, 4904-4907 10.1021/cm502306c
102. Ritter, C.; Gocke, E.; Fischer, C.; Schöllhorn, R. Neutron diffraction study on the crystal structure of lithium intercalated chevrel phases Mater. Res. Bull. 1992, 27, 1217-1225 10.1016/0025-5408(92)90229-S
103. 8 compounds Chem. Commun. 2007, 4212-4214 10.1039/b710743a
104. 8 and Cu Mixture Cathodes for Magnesium Ion Batteries ACS Appl. Mater. Interfaces 2015, 7, 7016-7024 10.1021/am508702j
105. 8 (x ≥ 1) Chevrel-phase cathode materials synthesized by chemical intercalation process for rechargeable magnesium batteries RSC Adv. 2014, 4, 59048-59055 10.1039/C4RA09250C
106. Liu, M.; Jain, A.; Rong, Z.; Qu, X.; Canepa, P.; Malik, R.; Ceder, G.; Persson, K. Evaluation of sulfur spinel compounds for multivalent battery cathode applications Energy Environ. Sci. 2016, 9, 3201-3209 10.1039/C6EE01731B
107. 8 (M = Metals, T = S, Se, Te) as a Structural Chameleon: Changes in the Rhombohedral Framework and Triclinic Distortion Chem. Mater. 2010, 22, 3678-3692 10.1021/cm100422z
108. Nikolowski, K.; Bramnik, N.; Baehtz, C.; Ehrenberg, H. In situ XRD Analysis of Magnesium Batteries. http://hasyweb.desy.de/science/annual_reports/2004_report/part1/contrib/41/12712.pdf (addessed December 20, 2016).
109. Levi, E.; Mitelman, A.; Aurbach, D.; Isnard, O. On the Mechanism of Triclinic Distortion in Chevrel Phase as Probed by In-Situ Neutron Diffraction Inorg. Chem. 2007, 46, 7528-7535 10.1021/ic7008573
110. 8 cathode for Mg intercalation from an electronic structure perspective Phys. Chem. Chem. Phys. 2015, 17, 22548-22551 10.1039/C5CP03046C
111. Wan, L. F.; Wright, J.; Perdue, B. R.; Fister, T. T.; Kim, S.; Apblett, C. A.; Prendergast, D. Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy Phys. Chem. Chem. Phys. 2016, 18, 17326-17329 10.1039/C6CP02412B
112. 2+ ions J. Power Sources 2016, 306, 431-436 10.1016/j.jpowsour.2015.12.009
113. Wang, Y.; Richards, W. D.; Ong, S. P.; Miara, L. J.; Kim, J. C.; Mo, Y.; Ceder, G. Design principles for solid-state lithium superionic conductors Nat. Mater. 2015, 14, 1026-1031 10.1038/nmat4369
114. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 1976, 32, 751-767 10.1107/S0567739476001551
115. Whittingham, M. S. Chemistry of intercalation compounds: Metal guests in chalcogenide hosts Prog. Solid State Chem. 1978, 12, 41-99 10.1016/0079-6786(78)90003-1
116. Aydinol, M. K.; Kohan, A. F.; Ceder, G.; Cho, K.; Joannopoulos, J. Ab initio study of lithium intercalation in metal oxides and metal dichalcogenides Phys. Rev. B: Condens. Matter Mater. Phys. 1997, 56, 1354-1365 10.1103/PhysRevB.56.1354
117. Whittingham, M. S. Lithium Batteries and Cathode Materials Chem. Rev. 2004, 104, 4271-4302 10.1021/cr020731c
118. Bruce, P. G.; Krok, F.; Nowinski, J.; Gibson, V. C.; Tavakkoli, K. Chemical intercalation of magnesium into solid hosts J. Mater. Chem. 1991, 1, 705-706 10.1039/jm9910100705
119. Bruce, P.; Krok, F.; Lighfoot, P.; Nowinski, J. L. Multivalent cation intercalation Solid State Ionics 1992, 53-56, 351-355 10.1016/0167-2738(92)90399-A
120. Amir, N.; Vestfrid, Y.; Chusid, O.; Gofer, Y.; Aurbach, D. Progress in nonaqueous magnesium electrochemistry J. Power Sources 2007, 174, 1234-1240 10.1016/j.jpowsour.2007.06.206
121. Sun, X.; Duffort, V.; Bonnick, P.; Rong, Z.; Liu, M.; Persson, K.; Ceder, G.; Nazar, L. F. A High Capacity Thiospinel Cathode for Mg Batteries Energy Environ. Sci. 2016, 9, 2273-2277 10.1039/C6EE00724D
122. 2 nanotubes as the cathode materials of Mg-ion batteries Chem. Commun. 2004, 2080-2081 10.1039/b403855j
123. 2Positive Electrode for Mg Batteries ACS Energy Lett. 2016, 1, 297-301 10.1021/acsenergylett.6b00145
124. Emly, A.; Van der Ven, A. Mg Intercalation in Layered and Spinel Host Crystal Structures for Mg Batteries Inorg. Chem. 2015, 54, 4394-4402 10.1021/acs.inorgchem.5b00188
125. 2 J. Mater. Chem. 1992, 2, 139-140 10.1039/jm9920200139
126. 2 by neutron diffraction Can. J. Phys. 1980, 58, 207-213 10.1139/p80-033
127. Doe, R. E.; Downie, C. M.; Fischer, C.; Lane, G. H.; Morgan, D.; Nevin, J.; Ceder, G.; Persson, K. A.; Eaglesham, D. Layered materials with improved magnesium intercalation for rechargeable magnesium ion cells. U.S. Patent App. 13/794,551, 2013.
128. 2+ Intercalation J. Phys. Chem. B 2004, 108, 13893-13900 10.1021/jp0367575
129. Liang, Y.; Yoo, H. D.; Li, Y.; Shuai, J.; Calderon, H. A.; Robles Hernandez, F. C.; Grabow, L. C.; Yao, Y. Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage Nano Lett. 2015, 15, 2194-2202 10.1021/acs.nanolett.5b00388
130. 2 Cathode and Ultrasmall Mg Nanoparticle Anode Adv. Mater. 2011, 23, 640-643 10.1002/adma.201003560
131. 2 Nanoribbon As a Promising Cathode Material for Rechargeable Mg Batteries J. Phys. Chem. C 2012, 116, 1307-1312 10.1021/jp2097026
132. 2with controlled interlayer spacing Mater. Res. Express 2016, 3, 064001-1-064001-8 10.1088/2053-1591/3/6/064001
133. 2-cathode with d-p orbital hybridized electronic structure Sci. Rep. 2015, 5, 12486 10.1038/srep12486
134. 2 Nanowire Cathodes ACS Nano 2013, 7, 8051-8058 10.1021/nn4032454
135. Schutte, W. J.; De Boer, J. L.; Jellinek, F. Crystal structures of tungsten disulfide and diselenide J. Solid State Chem. 1987, 70, 207-209 10.1016/0022-4596(87)90057-0
136. + Mediation J. Am. Chem. Soc. 2015, 137, 12388-12393 10.1021/jacs.5b07820
137. Zhao-Karger, Z.; Zhao, X.; Wang, D.; Diemant, T.; Behm, R. J.; Fichtner, M. Performance Improvement of Magnesium Sulfur Batteries with Modified Non-Nucleophilic Electrolytes Adv. Energy Mater. 2015, 5, 1401155 10.1002/aenm.201401155
138. Yu, X.; Manthiram, A. Performance Enhancement and Mechanistic Studies of Magnesium-Sulfur Cells with an Advanced Cathode Structure ACS Energy Lett. 2016, 1, 431-437 10.1021/acsenergylett.6b00213
139. Kubaschewski, O.; Evans, E. L.; Alcock, C. B. Metallurgical Thermochemistry; Pergamon Press: Oxford, 1967.
140. 2 (0
141. Levi, E.; Gofer, Y.; Aurbach, D. On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials Chem. Mater. 2010, 22, 860-868 10.1021/cm9016497
142. Rong, Z.; Malik, R.; Canepa, P.; Sai Gautam, G.; Liu, M.; Jain, A.; Persson, K.; Ceder, G. Materials Design Rules for Multivalent Ion Mobility in Intercalation Structures Chem. Mater. 2015, 27, 6016-6021 10.1021/acs.chemmater.5b02342
143. 2 nanosheets as a high-capacitance pseudocapacitor electrode J. Mater. Chem. 2012, 22, 14691-14695 10.1039/c2jm31080e
144. x nanotubes Chem. Commun. 2008, 5236-5238 10.1039/b809253b
145. Kim, S.; Nam, K. W.; Lee, S.; Cho, W.; Kim, J.-S.; Kim, B. G.; Oshima, Y.; Kim, J.-S.; Doo, S.-G.; Chang, H.; Aurbach, D.; Choi, J. W. Direct Observation of an Anomalous Spinel-to-Layered Phase Transition Mediated by Crystal Water Intercalation Angew. Chem., Int. Ed. 2015, 54, 15094-15099 10.1002/anie.201505487
146. Novák, P.; Desilvestro, J. Electrochemical Insertion of Magnesium in Metal Oxides and Sulfides from Aprotic Electrolytes J. Electrochem. Soc. 1993, 140, 140-144 10.1149/1.2056075
147. Nam, K. W. et al. The High Performance of Crystal Water Containing Manganese Birnessite Cathodes for Magnesium Batteries Nano Lett. 2015, 15, 4071-4079 10.1021/acs.nanolett.5b01109
148. Zhou, F.; Cococcioni, M.; Marianetti, C. A.; Morgan, D.; Ceder, G. First-principles prediction of redox potentials in transition-metal compounds with LDA+U Phys. Rev. B: Condens. Matter Mater. Phys. 2004, 70, 235121-1-235121-8 10.1103/PhysRevB.70.235121
149. Jain, A.; Ong, S. P.; Hautier, G.; Chen, W.; Richards, W. D.; Dacek, S.; Cholia, S.; Gunter, D.; Skinner, D.; Ceder, G.; Persson, K. A. The Materials Project: A materials genome approach to accelerating materials innovation APL Mater. 2013, 1, 011002 10.1063/1.4812323
150. Sempolinski, D. R.; Kingery, W. D. Ionic conductivity and Magnesium Vacancy mobility in Magnesium Oxide J. Am. Ceram. Soc. 1980, 63, 664-669 10.1111/j.1151-2916.1980.tb09857.x
151. Spahr, M.; Novák, P.; Haas, O.; Nesper, R. Electrochemical insertion of lithium, sodium, and magnesium in molybdenum(VI) oxide J. Power Sources 1995, 54, 346-351 10.1016/0378-7753(94)02099-O
152. 3 Thin Films Jpn. J. Appl. Phys. 2004, 43, 6248-6251 10.1143/JJAP.43.6248
153. 3 Thin Films Electrochem. Solid-State Lett. 2006, 9, A120-A122 10.1149/1.2163427
154. 3: A New Electrode Material for Nonaqueous Secondary Battery Applications J. Electrochem. Soc. 1971, 118, 1905-1908 10.1149/1.2407864
155. Incorvati, J. T.; Wan, L. F.; Key, B.; Zhou, D.; Liao, C.; Fuoco, L.; Holland, M.; Wang, H.; Prendergast, D.; Poeppelmeier, K. R.; Vaughey, J. T. Reversible Magnesium Intercalation into a Layered Oxyfluoride Cathode Chem. Mater. 2016, 28, 17-20 10.1021/acs.chemmater.5b02746
156. Gofer, Y.; Turgeman, R.; Cohen, H.; Aurbach, D. XPS Investigation of Surface Chemistry of Magnesium Electrodes in Contact with Organic Solutions of Organochloroaluminate Complex Salts Langmuir 2003, 19, 2344-2348 10.1021/la026642c
157. 2 (Anatase) Nanoparticles J. Phys. Chem. C 2007, 111, 14925-14931 10.1021/jp074464w
158. 2 for Magnesium Battery Cathodes ACS Appl. Mater. Interfaces 2014, 6, 7004-7008 10.1021/am5015327
159. Kaveevivitchai, W.; Jacobson, A. J. High Capacity Rechargeable Magnesium-Ion Batteries Based on a Microporous Molybdenum-Vanadium Oxide Cathode Chem. Mater. 2016, 28, 4593-4601 10.1021/acs.chemmater.6b01245
160. 8 J. Mater. Chem. A 2016, 4, 17643-17648 10.1039/C6TA07804D
161. 3 perovskites (M = Mo, Cr, Mn, Fe, Co, Ni) Phys. Chem. Chem. Phys. 2016, 18, 19966-19972 10.1039/C6CP03381D
162. Amatucci, G. G.; Badway, F.; Singhal, A.; Beaudoin, B.; Skandan, G.; Bowmer, T.; Plitz, I.; Pereira, N.; Chapman, T.; Jaworski, R. Investigation of Yttrium and Polyvalent Ion Intercalation into Nanocrystalline Vanadium Oxide J. Electrochem. Soc. 2001, 148, A940-A950 10.1149/1.1383777
163. 4 positive electrode material Electrochem. Commun. 2016, 67, 59-64 10.1016/j.elecom.2016.03.016
164. Hayashi, M.; Arai, H.; Ohtsuka, H.; Sakurai, Y. Electrochemical insertion/extraction of calcium ions using crystalline vanadium oxide Electrochem. Solid-State Lett. 2004, 7, A119-A121 10.1149/1.1675951
165. Whittingham, M. S. The Role of Ternary Phases in Cathode Reactions J. Electrochem. Soc. 1976, 123, 315-320 10.1149/1.2132817
166. Wiesener, K.; Schneider, W.; Ilić, D.; Steger, E.; Hallmeier, K.; Brackmann, E. Vanadium oxides in electrodes for rechargeable lithium cells J. Power Sources 1987, 20, 157-164 10.1016/0378-7753(87)80106-4
167. 5 system: An overview of the structure modifications induced by the lithium intercalation Solid State Ionics 1994, 69, 257-264 10.1016/0167-2738(94)90414-6
168. 5 J. Solid State Chem. 1986, 65, 63-71 10.1016/0022-4596(86)90089-7
169. 5 from First-Principles Chem. Mater. 2015, 27, 3733-3742 10.1021/acs.chemmater.5b00957
170. 5 Chem. Commun. 2015, 51, 13619-13622 10.1039/C5CC04947D
171. Novák, P.; Imhof, R.; Haas, O. Magnesium insertion electrodes for rechargeable nonaqueous batteries - a competitive alternative to lithium? Electrochim. Acta 1999, 45, 351-367 10.1016/S0013-4686(99)00216-9
172. 5 in sulfone-based electrolytes at 150°C J. Electroanal. Chem. Interfacial Electrochem. 1987, 218, 241-249 10.1016/0022-0728(87)87019-5
173. Novák, P.; Shklover, V.; Nesper, R. Magnesium Insertion in Vanadium Oxides: A Structural Study Z. Phys. Chem. 1994, 185, 51-68 10.1524/zpch.1994.185.Part_1.051
174. 5 from aprotic electrolytes with varied water content J. Colloid Interface Sci. 2004, 278, 160-165 10.1016/j.jcis.2004.05.028
175. Legendre, J.-J.; Livage, J. Vanadium pentoxide gels: I. Structural study by electron diffraction J. Colloid Interface Sci. 1983, 94, 75-83 10.1016/0021-9797(83)90236-9
176. 5 Electrode J. Electrochem. Soc. 1970, 117, 152-156 10.1149/1.2407456
177. 5 cathode Phys. Chem. Chem. Phys. 2014, 16, 18578-18585 10.1039/C4CP02230K
178. 5 a promising cathode material for rechargeable Li and Mg ion batteries: an ab initio study Phys. Chem. Chem. Phys. 2013, 15, 8705-8709 10.1039/c3cp51167g
179. 5 J. Phys. Chem. C 2014, 118, 19599-19607 10.1021/jp505821w
180. 5: A Comparative Structural Investigation J. Solid State Chem. 1998, 136, 56-62 10.1006/jssc.1997.7654
181. Matts, I. L.; Dacek, S.; Pietrzak, T. K.; Malik, R.; Ceder, G. Explaining Performance-Limiting Mechanisms in Fluorophosphate Na-Ion Battery Cathodes through Inactive Transition-Metal Mixing and First-Principles Mobility Calculations Chem. Mater. 2015, 27, 6008-6015 10.1021/acs.chemmater.5b02299
182. Rossouw, M.; Liles, D.; Thackeray, M.; David, W.; Hull, S. Alpha manganese dioxide for lithium batteries: A structural and electrochemical study Mater. Res. Bull. 1992, 27, 221-230 10.1016/0025-5408(92)90216-M
183. 4F Cathode Materials Angew. Chem. 2010, 122, 8920-8924 10.1002/ange.201003743
184. 4F electrodes for Li-ion batteries J. Mater. Chem. A 2015, 3, 16988-16997 10.1039/C5TA05107J
185. 6 Cathode upon Na Intercalation Chem. Mater. 2015, 27, 3763-3768 10.1021/acs.chemmater.5b01132
186. Kim, H.; Hong, J.; Yoon, G.; Kim, H.; Park, K.-Y.; Park, M.-S.; Yoon, W.-S.; Kang, K. Sodium intercalation chemistry in graphite Energy Environ. Sci. 2015, 8, 2963-2969 10.1039/C5EE02051D
187. 5 Nano Lett. 2016, 16, 2426-2431 10.1021/acs.nanolett.5b05273
188. 2O Xerogel Solved by the Atomic Pair Distribution Function Technique J. Am. Chem. Soc. 2002, 124, 10157-10162 10.1021/ja026143y
189. 5 Layer J. Solid State Chem. 1996, 126, 65-73 10.1006/jssc.1996.0311
190. 2O, M = Ca, Ni J. Solid State Chem. 1997, 132, 323-329 10.1006/jssc.1997.7467
191. Bervas, M.; Klein, L.; Amatucci, G. Vanadium oxide-propylene carbonate composite as a host for the intercalation of polyvalent cations Solid State Ionics 2005, 176, 2735-2747 10.1016/j.ssi.2005.09.009
192. 2 Solutions Acta Phys. Pol., A 2010, 117, 837-840 10.12693/APhysPolA.117.837
193. Lee, S. H.; DiLeo, R. A.; Marschilok, A. C.; Takeuchi, K. J.; Takeuchi, E. S. Sol Gel Based Synthesis and Electrochemistry of Magnesium Vanadium Oxide: A Promising Cathode Material for Secondary Magnesium Ion Batteries ECS Electrochem. Lett. 2014, 3, A87-A90 10.1149/2.0021408eel
194. Tepavcevic, S.; Xiong, H.; Stamenkovic, V. R.; Zuo, X.; Balasubramanian, M.; Prakapenka, V. B.; Johnson, C. S.; Rajh, T. Nanostructured Bilayered Vanadium Oxide Electrodes for Rechargeable Sodium-Ion Batteries ACS Nano 2012, 6, 530-538 10.1021/nn203869a
195. Tepavcevic, S.; Liu, Y.; Zhou, D.; Lai, B.; Maser, J.; Zuo, X.; Chan, H.; Král, P.; Johnson, C. S.; Stamenkovic, V. et al. Nanostructured Layered Cathode for Rechargeable Mg-Ion Batteries ACS Nano 2015, 9, 8194-8205 10.1021/acsnano.5b02450
196. 5/graphite composite in aqueous electrolytic solutions: experimental and theoretical approach Electrochim. Acta 2015, 176, 130-140 10.1016/j.electacta.2015.07.004
197. 5 aerogels Chem. Mater. 1998, 10, 682-684 10.1021/cm9705101
198. 2O Xerogel Material Chem. Mater. 2016, 28, 2962-2969 10.1021/acs.chemmater.6b00026
199. 5 Battery Adv. Energy Mater. 2016, 6, 1600826 10.1002/aenm.201600826
200. 5/carbon composites Solid State Ionics 2003, 161, 173-180 10.1016/S0167-2738(03)00267-4
201. 5 gel/Carbon Composites under High-Rate Condition J. Electrochem. Soc. 2003, 150, A753-A758 10.1149/1.1571531
202. 2+ on Battery Performance J. Electrochem. Soc. 2016, 163, A1941-A1943 10.1149/2.0781609jes
203. 4 in Aqueous Electrolytes Electrochem. Solid-State Lett. 2008, 11, F23-F26 10.1149/1.2972990
204. 2 for rechargeable aqueous battery Electrochim. Acta 2014, 116, 404-412 10.1016/j.electacta.2013.11.090
205. Kundu, D.; Adams, B. D.; Duffort, V.; Vajargah, S. H.; Nazar, L. F. A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode Nat. Energy 2016, 1, 16119-1-16119-8 10.1038/nenergy.2016.119
206. 2 in Lithium Cells J. Electrochem. Soc. 1974, 121, 656-660 10.1149/1.2401880
207. 2 for Li Batteries J. Electrochem. Soc. 1982, 129, 1861-1865 10.1149/1.2124315
208. 2 tunnel related phase as host lattice for Li intercalation Solid State Ionics 1995, 80, 151-158 10.1016/0167-2738(95)00133-Q
209. 4 Mater. Res. Bull. 1984, 19, 179-187 10.1016/0025-5408(84)90088-6
210. Renuka, R.; Ramamurthy, S. An investigation on layered birnessite type manganese oxides for battery applications J. Power Sources 2000, 87, 144-152 10.1016/S0378-7753(99)00474-7
211. Kumagai, N.; Komaba, S.; Sakai, H.; Kumagai, N. Preparation of todorokite-type manganese-based oxide and its application as lithium and magnesium rechargeable battery cathode J. Power Sources 2001, 97-98, 515-517 10.1016/S0378-7753(01)00726-1
212. 2 and its cathode characteristics for rechargeable lithium batteries J. Power Sources 2005, 146, 310-314 10.1016/j.jpowsour.2005.03.145
213. 2 batteries Nano Res. 2009, 2, 713-721 10.1007/s12274-009-9075-y
214. 2 cathode in an aqueous secondary battery J. Alloys Compd. 2011, 509, 5974-5980 10.1016/j.jallcom.2011.03.044
215. Rasul, S.; Suzuki, S.; Yamaguchi, S.; Miyayama, M. High capacity positive electrodes for secondary Mg-ion batteries Electrochim. Acta 2012, 82, 243-249 10.1016/j.electacta.2012.03.095
216. 2/acetylene black composite cathode for secondary Mg-ion batteries Solid State Ionics 2012, 225, 542-546 10.1016/j.ssi.2012.01.019
217. Rasul, S.; Suzuki, S.; Yamaguchi, S.; Miyayama, M. Manganese oxide octahedral molecular sieves as insertion electrodes for rechargeable Mg batteries Electrochim. Acta 2013, 110, 247-252 10.1016/j.electacta.2013.06.094
218. 2 as a cathode material for rechargeable Mg batteries Electrochem. Commun. 2012, 23, 110-113 10.1016/j.elecom.2012.07.021
219. Kim, J.-S.; Chang, W.-S.; Kim, R.-H.; Kim, D.-Y.; Han, D.-W.; Lee, K.-H.; Lee, S.-S.; Doo, S.-G. High-capacity nanostructured manganese dioxide cathode for rechargeable magnesium ion batteries J. Power Sources 2015, 273, 210-215 10.1016/j.jpowsour.2014.07.162
220. 2+ insertion for a magnesium ion battery Phys. Chem. Chem. Phys. 2015, 17, 5256-5264 10.1039/C4CP05591H
221. Zhang, R.; Arthur, T. S.; Ling, C.; Mizuno, F. Manganese dioxides as rechargeable magnesium battery cathode; synthetic approach to understand magnesiation process J. Power Sources 2015, 282, 630-638 10.1016/j.jpowsour.2015.02.067
222. 2 battery performance J. Power Sources 1990, 32, 271-276 10.1016/0378-7753(90)87020-R
223. Knight, J. C.; Therese, S.; Manthiram, A. On the Utility of Spinel Oxide Hosts for Magnesium-Ion Batteries ACS Appl. Mater. Interfaces 2015, 7, 22953-22961 10.1021/acsami.5b06179
224. 2 for both aqueous and non-aqueous magnesium-ion batteries CrystEngComm 2015, 17, 8728-8735 10.1039/C5CE01436K
225. 2 Chem. Mater. 2015, 27, 5799-5807 10.1021/acs.chemmater.5b02488
226. Feng, Z. et al. Phase-Controlled Electrochemical Activity of Epitaxial Mg-Spinel Thin Films ACS Appl. Mater. Interfaces 2015, 7, 28438-28443 10.1021/acsami.5b09346
227. Sun, X.; Duffort, V.; Mehdi, B. L.; Browning, N. D.; Nazar, L. F. Investigation of the Mechanism of Mg Insertion in Birnessite in Nonaqueous and Aqueous Rechargeable Mg-Ion Batteries Chem. Mater. 2016, 28, 534-542 10.1021/acs.chemmater.5b03983
228. Xu, C.; Li, B.; Du, H.; Kang, F. Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery Angew. Chem., Int. Ed. 2012, 51, 933-935 10.1002/anie.201106307
229. 2 Cathode: Enhanced Performance in an Aqueous Rechargeable Battery Ind. Eng. Chem. Res. 2011, 50, 8792-8795 10.1021/ie2001742
230. Xu, C.; Chiang, S. W.; Ma, J.; Kang, F. Investigation on Zinc Ion Storage in Alpha Manganese Dioxide for Zinc Ion Battery by Electrochemical Impedance Spectrum J. Electrochem. Soc. 2013, 160, A93-A97 10.1149/2.008302jes
231. 2 as a zinc-ion intercalating material Electrochim. Acta 2013, 112, 138-143 10.1016/j.electacta.2013.08.136
232. Lee, B.; Yoon, C. S.; Lee, H. R.; Chung, K. Y.; Cho, B. W.; Oh, S. H. Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide Sci. Rep. 2014, 4, 6066 10.1038/srep06066
233. 2 Cathode of a High Capacity Zinc-Ion Battery System Chem. Mater. 2015, 27, 3609-3620 10.1021/cm504717p
234. 4-based spinels J. Mater. Chem. A 2015, 3, 21077-21082 10.1039/C5TA06482A
235. Pan, H.; Shao, Y.; Yan, P.; Cheng, Y.; Han, K. S.; Nie, Z.; Wang, C.; Yang, J.; Li, X.; Bhattacharya, P.; Mueller, K. T.; Liu, J. Reversible aqueous zinc/manganese oxide energy storage from conversion reactions Nat. Energy 2016, 1, 16039 10.1038/nenergy.2016.39
236. Kim, C.; Phillips, P. J.; Key, B.; Yi, T.; Nordlund, D.; Yu, Y.-S.; Bayliss, R. D.; Han, S.-D.; He, M.; Zhang, Z.; Burrell, A. K.; Klie, R. F.; Cabana, J. Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host Adv. Mater. 2015, 27, 3377-3384 10.1002/adma.201500083
237. Messaoudi, B.; Joiret, S.; Keddam, M.; Takenouti, H. Anodic behaviour of manganese in alkaline medium Electrochim. Acta 2001, 46, 2487-2498 10.1016/S0013-4686(01)00449-2
238. Brock, S. L.; Duan, N.; Tian, Z. R.; Giraldo, O.; Zhou, H.; Suib, S. L. A Review of Porous Manganese Oxide Materials Chem. Mater. 1998, 10, 2619-2628 10.1021/cm980227h
239. Stobbe, E.; De Boer, B.; Geus, J. The reduction and oxidation behaviour of manganese oxides Catal. Today 1999, 47, 161-167 10.1016/S0920-5861(98)00296-X
240. Liu, M.; Rong, Z.; Malik, R.; Canepa, P.; Jain, A.; Ceder, G.; Persson, K. A. Spinel compounds as multivalent battery cathodes: a systematic evaluation based on ab initio calculations Energy Environ. Sci. 2015, 8, 964-974 10.1039/C4EE03389B
241. 2 for rechargeable zinc batteries Chem. Commun. 2015, 51, 9265-9268 10.1039/C5CC02585K
242. 2 Electrochem. Solid-State Lett. 2001, 4, A78-A81 10.1149/1.1368896
243. Kim, S.; Lee, S.; Nam, K. W.; Shin, J.; Lim, S. Y.; Cho, W.; Suzuki, K.; Oshima, Y.; Hirayama, M.; Kanno, R.; Choi, J. W. On the Mechanism of Crystal Water Insertion during Anomalous Spinel-to-Birnessite Phase Transition Chem. Mater. 2016, 28, 5488-5494 10.1021/acs.chemmater.6b02083
244. 2 nanoflake cathode with high zinc-storage capacities for eco-friendly battery applications Electrochem. Commun. 2015, 60, 121-125 10.1016/j.elecom.2015.08.019
245. Irani, K.; Sinha, A.; Biswas, A. Effect of temperature on the structure of manganites J. Phys. Chem. Solids 1962, 23, 711-727 10.1016/0022-3697(62)90530-9
246. 4) J. Phys. Chem. Solids 1967, 28, 2335-2341 10.1016/0022-3697(67)90259-4
247. 4±δ Spinels J. Solid State Chem. 2002, 166, 171-176 10.1006/jssc.2002.9577
248. Sánchez, L.; Pereira-Ramos, J.-P. Electrochemical insertion of magnesium in a mixed manganese cobalt oxide J. Mater. Chem. 1997, 7, 471-473 10.1039/a605210j
249. 2 J. Solid State Chem. 1996, 121, 483-491 10.1006/jssc.1996.0067
250. 2 cathodes Electrochem. Commun. 2004, 6, 832-837 10.1016/j.elecom.2004.06.004
251. xO4 (M = Cr, Fe, Co, and Ni) Cathodes J. Electrochem. Soc. 2015, 162, A426-A431 10.1149/2.0661503jes
252. 2 J. Electrochem. Soc. 1997, 144, 2587-2592 10.1149/1.1837869
253. Mishra, S. K.; Ceder, G. Structural stability of lithium manganese oxides Phys. Rev. B: Condens. Matter Mater. Phys. 1999, 59, 6120-6130 10.1103/PhysRevB.59.6120
254. 2 polymorphs in density functional theory Phys. Rev. B: Condens. Matter Mater. Phys. 2016, 93, 045132 10.1103/PhysRevB.93.045132
255. Lipson, A. L.; Proffit, D. L.; Pan, B.; Fister, T. T.; Liao, C.; Burrell, A. K.; Vaughey, J. T.; Ingram, B. J. Current Collector Corrosion in Ca-Ion Batteries J. Electrochem. Soc. 2015, 162, A1574-A1578 10.1149/2.0811508jes
256. 4: A first-principles study by GGA and GGA+U methods J. Power Sources 2010, 195, 4971-4976 10.1016/j.jpowsour.2010.02.060
257. Okamoto, S.; Ichitsubo, T.; Kawaguchi, T.; Kumagai, Y.; Oba, F.; Yagi, S.; Shimokawa, K.; Goto, N.; Doi, T.; Matsubara, E. Intercalation and Push-Out Process with Spinel-to-Rocksalt Transition on Mg Insertion into Spinel Oxides in Magnesium Batteries Adv. Sci. 2015, 2, 1500072 10.1002/advs.201500072
258. 4 (A = Li, Na, or Mg) and Its Application as a Rechargeable Battery Cathode Chem. Mater. 2013, 25, 3062-3071 10.1021/cm401250c
259. 4: Role of inversion Phys. Rev. B: Condens. Matter Mater. Phys. 2005, 71, 174102 10.1103/PhysRevB.71.174102
260. 4 under High Pressure J. Am. Chem. Soc. 2006, 128, 9448-9456 10.1021/ja0612302
261. Zhang, R.; Ling, C. Status and challenge of Mg battery cathode MRS Energy & Sustainability 2016, 3, E1-1-E1-19 10.1557/mre.2016.2
262. 4Polymorphs as Cathode Materials for Ca Ion Batteries Chem. Mater. 2016, 28, 6886-6893 10.1021/acs.chemmater.6b02146
263. 4 (M = Mn, Fe, Co, Ni) Olivine Materials Electrochem. Solid-State Lett. 2004, 7, A30-A32 10.1149/1.1633511
264. 4 Olivine-Type Battery Material Chem. Mater. 2005, 17, 5085-5092 10.1021/cm050999v
265. Kang, B.; Ceder, G. Battery materials for ultrafast charging and discharging Nature 2009, 458, 190-193 10.1038/nature07853
266. Ellis, B. L.; Lee, K. T.; Nazar, L. F. Positive Electrode Materials for Li-Ion and Li-Batteries Chem. Mater. 2010, 22, 691-714 10.1021/cm902696j
267. Mueller, T.; Hautier, G.; Jain, A.; Ceder, G. Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing Chem. Mater. 2011, 23, 3854-3862 10.1021/cm200753g
268. Barpanda, P.; Ati, M.; Melot, B. C.; Rousse, G.; Chotard, J.-N.; Doublet, M.-L.; Sougrati, M. T.; Corr, S. A.; Jumas, J.-C.; Tarascon, J.-M. A 3.90 V iron-based fluorosulphate material for lithium-ion batteries crystallizing in the triplite structure Nat. Mater. 2011, 10, 772-77 10.1038/nmat3093
269. 4F Tavorite-Type Cathode Materials Chem. Mater. 2011, 23, 2278-2284 10.1021/cm200683n
270. 3 as a cathode in Li-ion batteries Chem. Mater. 2000, 12, 3240-3242 10.1021/cm000345g
271. Wang, R. Y.; Wessells, C. D.; Huggins, R. A.; Cui, Y. Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries Nano Lett. 2013, 13, 5748-5752 10.1021/nl403669a
272. Wang, R. Y.; Shyam, B.; Stone, K. H.; Weker, J. N.; Pasta, M.; Lee, H.-W.; Toney, M. F.; Cui, Y. Reversible Multivalent (Monovalent, Divalent, Trivalent) Ion Insertion in Open Framework Materials Adv. Energy Mater. 2015, 5, 1401869 10.1002/aenm.201401869
273. Orikasa, Y.; Masese, T.; Koyama, Y.; Mori, T.; Hattori, M.; Yamamoto, K.; Okado, T.; Huang, Z.-D.; Minato, T.; Tassel, C.; Kim, J.; Kobayashi, Y.; Abe, T.; Kageyama, H.; Uchimoto, Y. High energy density rechargeable magnesium battery using earth-abundant and non-toxic elements Sci. Rep. 2014, 4, 5622 10.1038/srep05622
274. 4 prepared via a molten salt method as a new cathode material for rechargeable magnesium batteries Chin. Sci. Bull. 2011, 56, 386-390 10.1007/s11434-010-4247-4
275. 4 Electrochem. Commun. 2008, 10, 1291-1294 10.1016/j.elecom.2008.06.021
276. 4 and its electrochemical intercalation behavior J. Power Sources 2008, 184, 604-609 10.1016/j.jpowsour.2008.05.021
277. 2+ in Magnesium Manganese Silicate and Its Application as High-Energy Rechargeable Magnesium Battery Cathode J. Phys. Chem. C 2009, 113, 12594-12597 10.1021/jp903188b
278. NuLi, Y.; Yang, J.; Li, Y.; Wang, J. Mesoporous magnesium manganese silicate as cathode materials for rechargeable magnesium batteries Chem. Commun. 2010, 46, 3794-3796 10.1039/c002456b
279. NuLi, Y.-N.; Yang, J.; Zheng, Y.-P.; Wang, J.-L. Mesoporous Magnesium Manganese Silicate as a Cathode Material for Rechargeable Magnesium Batteries Wuji Cailiao Xuebao 2011, 26, 129-133 10.3724/SP.J.1077.2011.00129
280. 4 hierarchical nanostructure for superior reversible magnesium ion storage Electrochem. Commun. 2011, 13, 1143-1146 10.1016/j.elecom.2011.07.020
281. Ling, C.; Banerjee, D.; Song, W.; Zhang, M.; Matsui, M. First-principles study of the magnesiation of olivines: redox reaction mechanism, electrochemical and thermodynamic properties J. Mater. Chem. 2012, 22, 13517-13523 10.1039/c2jm31122d
282. 2+ in 3D hierarchically porous magnesium cobalt silicate and its application as an advanced cathode material in rechargeable magnesium batteries J. Mater. Chem. 2011, 21, 12437-12443 10.1039/c1jm10485c
283. 4 cathodes for rechargeable magnesium batteries Phys. Chem. Chem. Phys. 2016, 18, 13524-13529 10.1039/C6CP00448B
284. Malik, R.; Burch, D.; Bazant, M.; Ceder, G. Particle Size Dependence of the Ionic Diffusivity Nano Lett. 2010, 10, 4123-4127 10.1021/nl1023595
285. Zheng, Y.; NuLi, Y.; Chen, Q.; Wang, Y.; Yang, J.; Wang, J. Magnesium cobalt silicate materials for reversible magnesium ion storage Electrochim. Acta 2012, 66, 75-81 10.1016/j.electacta.2012.01.037
286. 8 in the analogous rechargeable Mg-ion battery system J. Power Sources 2016, 321, 76-86 10.1016/j.jpowsour.2016.04.094
287. 4 as Magnesium Battery Cathode ACS Appl. Mater. Interfaces 2016, 8, 18018-18026 10.1021/acsami.6b03297
288. Palacios, E.; Leret, P.; Fernández, J.; De Aza, A.; Rodríguez, M. Synthesis of amorphous acid iron phosphate nanoparticles J. Nanopart. Res. 2012, 14, 1-7 10.1007/s11051-012-1131-y
289. 3 (A = Li, Na) as electrode materials Solid State Ionics 1988, 28-30, 419-423 10.1016/S0167-2738(88)80075-4
290. Ong, S. P.; Chevrier, V. L.; Hautier, G.; Jain, A.; Moore, C.; Kim, S.; Ma, X.; Ceder, G. Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials Energy Environ. Sci. 2011, 4, 3680-3688 10.1039/c1ee01782a
291. 3 (A = Li, Na, M = Ti, Sn and Zr) Int. J. Mod. Phys. B 2014, 28, 1450176-1-1450176-9 10.1142/S0217979214501768
292. 3 electrolyte J. Power Sources 2015, 293, 11-16 10.1016/j.jpowsour.2015.05.060
293. Goodenough, J.; Hong, H.-P.; Kafalas, J. Fast Na+-ion transport in skeleton structures Mater. Res. Bull. 1976, 11, 203-220 10.1016/0025-5408(76)90077-5
294. 3 J. Power Sources 2001, 99, 66-69 10.1016/S0378-7753(01)00480-3
295. 3 J. Power Sources 2001, 97-98, 512-514 10.1016/S0378-7753(01)00694-2
296. 3 (Me = Cr, Fe) J. Power Sources 2002, 112, 85-89 10.1016/S0378-7753(02)00345-2
297. 3 (TM = Fe, Mn, Co and Nb) Key Eng. Mater. 2012, 508, 291-299 10.4028/www.scientific.net/KEM.508.291
298. Huang, Z.-D.; Masese, T.; Orikasa, Y.; Mori, T.; Yamamoto, K. Vanadium phosphate as a promising high-voltage magnesium ion (de)-intercalation cathode host RSC Adv. 2015, 5, 8598-8603 10.1039/C4RA14416C
299. 3 J. Am. Chem. Soc. 2003, 125, 10402-10411 10.1021/ja034565h
300. 3 for potential use as electrolyte in solid state magnesium batteries Ceram. Int. 2014, 40, 13719-13727 10.1016/j.ceramint.2014.05.013
301. Imanaka, N.; Okazaki, Y.; Adachi, G.-y. Divalent magnesium ion conducting characteristics in phosphate based solid electrolyte composites J. Mater. Chem. 2000, 10, 1431-1435 10.1039/a909599c
302. Gautam, G. S.; Canepa, P.; Ceder, G. Mg mobility in NASICON-frameworks. Lawrence Berkeley National Laboratory: Berkeley, CA, Unpublished Work, 2017.
303. Kamaya, N.; Homma, K.; Yamakawa, Y.; Hirayama, M.; Kanno, R.; Yonemura, M.; Kamiyama, T.; Kato, Y.; Hama, S.; Kawamoto, K.; Mitsui, A. A lithium superionic conductor Nat. Mater. 2011, 10, 682-686 10.1038/nmat3066
304. Bachman, J. C.; Muy, S.; Grimaud, A.; Chang, H.-H.; Pour, N.; Lux, S. F.; Paschos, O.; Maglia, F.; Lupart, S.; Lamp, P.; Giordano, L.; Shao-Horn, Y. Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction Chem. Rev. 2016, 116, 140-162 10.1021/acs.chemrev.5b00563
305. 4F as a feasible cathode material for magnesium batteries J. Mater. Chem. A 2014, 2, 11578-11582 10.1039/C4TA01779J
306. 4F as a potential cathode material for Mg ion batteries: a first principles calculation Phys. Chem. Chem. Phys. 2014, 16, 22974-22978 10.1039/C4CP03176H
307. 4F as a one-dimensional Mg-ion conductor for Mg ion battery positive electrode: a first principles calculation RSC Adv. 2014, 4, 15014-15017 10.1039/c4ra00199k
308. 2 Inorg. Chem. 2007, 46, 3289-3294 10.1021/ic0700250
309. Yamada, A.; Iwane, N.; Harada, Y.; Nishimura, S.-i.; Koyama, Y.; Tanaka, I. Lithium Iron Borates as High-Capacity Battery Electrodes Adv. Mater. 2010, 22, 3583-3587 10.1002/adma.201001039
310. 3 as a Li Intercalation Material J. Electrochem. Soc. 2011, 158, A309-A315 10.1149/1.3536532
311. 3 J. Mater. Chem. 2012, 22, 8799-8809 10.1039/c2jm16436a
312. 5 Chem. Mater. 2015, 27, 4630-4639 10.1021/acs.chemmater.5b01040
313. Pasta, M.; Wessells, C. D.; Liu, N.; Nelson, J.; McDowell, M. T.; Huggins, R. A.; Toney, M. F.; Cui, Y. Full open-framework batteries for stationary energy storage Nat. Commun. 2014, 5, 3007 10.1038/ncomms4007
314. Trócoli, R.; La Mantia, F. An Aqueous Zinc-Ion Battery Based on Copper Hexacyanoferrate ChemSusChem 2015, 8, 481-485 10.1002/cssc.201403143
315. Zhang, L.; Chen, L.; Zhou, X.; Liu, Z. Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System Adv. Energy Mater. 2015, 5, 1400930 10.1002/aenm.201400930
316. Yagi, S.; Fukuda, M.; Ichitsubo, T.; Nitta, K.; Mizumaki, M.; Matsubara, E. EQCM Analysis of Redox Behavior of CuFe Prussian Blue Analog in Mg Battery Electrolytes J. Electrochem. Soc. 2015, 162, A2356-A2361 10.1149/2.0751512jes
317. Reed, L. D.; Ortiz, S. N.; Xiong, M.; Menke, E. J. A rechargeable aluminum-ion battery utilizing a copper hexacyanoferrate cathode in an organic electrolyte Chem. Commun. 2015, 51, 14397-14400 10.1039/C5CC06053B
318. Lipson, A. L.; Pan, B.; Lapidus, S. H.; Liao, C.; Vaughey, J. T.; Ingram, B. J. Rechargeable Ca-Ion Batteries: A New Energy Storage System Chem. Mater. 2015, 27, 8442-8447 10.1021/acs.chemmater.5b04027
319. Sun, X.; Duffort, V.; Nazar, L. F. Prussian Blue Mg-Li Hybrid Batteries Adv. Sci. 2016, 3, 1600044 10.1002/advs.201600044
320. 6 as a High-Voltage Cathode for Magnesium Batteries ACS Appl. Mater. Interfaces 2016, 8, 8554-8560 10.1021/acsami.6b01352
321. Tojo, T.; Sugiura, Y.; Inada, R.; Sakurai, Y. Reversible Calcium Ion Batteries Using a Dehydrated Prussian Blue Analogue Cathode Electrochim. Acta 2016, 207, 22-27 10.1016/j.electacta.2016.04.159
322. Ling, C.; Chen, J.; Mizuno, F. First-Principles Study of Alkali and Alkaline Earth Ion Intercalation in Iron Hexacyanoferrate: The Important Role of Ionic Radius J. Phys. Chem. C 2013, 117, 21158-21165 10.1021/jp4078689
323. Shiga, T.; Kondo, H.; Kato, Y.; Inoue, M. Insertion of Calcium Ion into Prussian Blue Analogue in Nonaqueous Solutions and Its Application to a Rechargeable Battery with Dual Carriers J. Phys. Chem. C 2015, 119, 27946-27953 10.1021/acs.jpcc.5b10245
324. Haynes, W. M.; Bruno, T. J.; Lide, D. R., Eds. CRC Handbook of Chemistry and Physics, 96th ed.; CRC Press: Boca Raton, FL, 2016.
325. Delmas, C.; Fouassier, C.; Hagenmuller, P. Structural classification and properties of the layered oxides Physica B+C 1980, 99, 81-85 10.1016/0378-4363(80)90214-4
326. 2 and systematic deduction of possible polytypes of molybdenite. Bull. Suisse Mineral. Petrogr. 1964, 44, 105-120.
327. 2 by neutron diffraction J. Solid State Chem. 1976, 17, 389-392 10.1016/S0022-4596(76)80008-4
328. Kihlborg, L. Least squares refinement of crystal structure of molybdenum trioxide Ark. Kemi 1963, 21, 357-364
329. 8 phase (0.12 ≤ x ≤ 0.18). Solid state chemistry-X-rays-TEM-physical properties Solid State Sci. 2005, 7, 726-734 10.1016/j.solidstatesciences.2004.11.018
330. 8: eine neue Synthese und Verfeinerung ihrer Kristallstrukturen Z. Anorg. Allg. Chem. 1995, 621, 541-545 10.1002/zaac.19956210407
331. 5 Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1986, 42, 1467-1469 10.1107/S0108270186091825
332. Rossouw, M. H.; Liles, D. C.; Thackeray, M. M.; David, W. I. F.; Hull, S. Alpha manganese dioxide for lithium batteries: A structural and electrochemical study Mater. Res. Bull. 1992, 27, 221-230 10.1016/0025-5408(92)90216-M
333. 2 (x ≤ 1 J. Solid State Chem. 1971, 3, 1-11 10.1016/0022-4596(71)90001-6
334. 7−δ Pyrochlore J. Solid State Chem. 1998, 140, 182-193 10.1006/jssc.1998.7848
335. 4 as a new Li-battery cathode material Electrochem. Commun. 2005, 7, 156-160 10.1016/j.elecom.2004.11.008
336. 4 cathodes modified by phosphorous substitution and the structural consequences Solid State Ionics 2014, 259, 29-39 10.1016/j.ssi.2014.02.002
337. 4 Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1979, 35, 2680-2682 10.1107/S0567740879010165
338. 4, using X-ray diffraction data Acta Crystallogr., Sect. B: Struct. Sci. 1993, 49, 147-153 10.1107/S0108768192004701
339. 4F cathode material for Li-ion batteries Electrochim. Acta 2014, 147, 663-668 10.1016/j.electacta.2014.09.131
340. 3-a new member of the NASICON family with low thermal expansion Mater. Lett. 1993, 16, 96-101 10.1016/0167-577X(93)90031-R
341. Urban, A.; Seo, D.-H.; Ceder, G. Computational understanding of Li-ion batteries npj Comput. Mater. 2016, 2, 16002 10.1038/npjcompumats.2016.2