Role of Chloride for a Simple, Non-Grignard Mg Electrolyte in Ether-Based Solvents

ACS Applied Materials and Interfaces

Volumn 8, Issue 25, 2016, Pages 16002-16008

  Sa, Niya ^a,b   Pan, Baofei ^a,b   Saha Shah, Anumita ^c   Hubaud, Aude A ^a,b   Vaughey, John T ^a,b   Baker, Lane A ^c   Liao, Chen ^a,b   Burrell, Anthony K ^a,b  

^a Joint Center for Energy Storage Research (JCESR)   (United States)

^b ARGONNE NATIONAL LABORATORY   (United States)

^c INDIANA UNIVERSITY   (United States)

Author keywords

Chevrel phase cathode; Mg battery; nonaqueous Mg electrolyte; plating and stripping of magnesium; rechargeable magnesium battery

Indexed keywords

CATHODES; CHLORINE COMPOUNDS; DEPOSITION; ELECTRIC BATTERIES; ELECTRODES; MAGNESIUM; MAGNESIUM PRINTING PLATES; MOLYBDENUM; MOLYBDENUM OXIDE; ORGANIC SOLVENTS; PROTECTIVE COATINGS; SECONDARY BATTERIES;

BIS(TRIFLUOROMETHANE SULFONYL)IMIDE; CHEVREL PHASE; COLUMBIC EFFICIENCY; MAGNESIUM CHLORIDES; MG BATTERIES; NON-AQUEOUS; RECHARGEABLE MAGNESIUM BATTERY; SYNTHETIC STRATEGIES;

ELECTROLYTES;

EID: 84976567610     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/acsami.6b03193     Document Type: Article

References (32)

1. Yoo, H. D.; Shterenberg, I.; Gofer, Y.; Gershinsky, G.; Pour, N.; Aurbach, D. Mg Rechargeable Batteries: An On-going Challenge Energy Environ. Sci. 2013, 6, 2265-2279 10.1039/c3ee40871j
2. Shterenberg, I.; Salama, M.; Gofer, Y.; Levi, E.; Aurbach, D. The Challenge of Developing Rechargeable Magnesium Batteries MRS Bull. 2014, 39, 453-460 10.1557/mrs.2014.61
3. Mohtadi, R.; Mizuno, F. Magnesium Batteries: Current State of the Art, Issues and Future Perspectives Beilstein J. Nanotechnol. 2014, 5, 1291-1311 10.3762/bjnano.5.143
4. Amatucci, G. G.; Badway, F.; Singhal, A.; Beaudoin, B.; Skandan, G.; Bowmer, T.; Plitz, I.; Pereira, N.; Chapman, T.; Jaworski, R. Investigation of Yttrium and Polyvalent Ion Intercalation into Nanocrystalline Vanadium Oxide J. Electrochem. Soc. 2001, 148, A940-A950 10.1149/1.1383777
5. Aurbach, D.; Lu, Z.; Schechter, A.; Gofer, Y.; Gizbar, H.; Turgeman, R.; Cohen, Y.; Moshkovich, M.; Levi, E. Prototype Systems for Rechargeable Magnesium Batteries Nature 2000, 407, 724-727 10.1038/35037553
6. Kimura, T.; Fujii, K.; Sato, Y.; Morita, M.; Yoshimoto, N. Solvation of Magnesium Ion in Triglyme-Based Electrolyte Solutions J. Phys. Chem. C 2015, 119, 18911-18917 10.1021/acs.jpcc.5b04626
7. Gregory, T. D.; Hoffman, R. J.; Winterton, R. C. Nonaqueous Electrochemistry of Magnesium: Applications to Energy Storage J. Electrochem. Soc. 1990, 137, 775-780 10.1149/1.2086553
8. Aurbach, D.; Gizbar, H.; Schechter, A.; Chusid, O.; Gottlieb, H. E.; Gofer, Y.; Goldberg, I. Electrolyte Solutions for Rechargeable Magnesium Batteries Based on Organomagnesium Chloroaluminate Complexes J. Electrochem. Soc. 2002, 149, A115-A121 10.1149/1.1429925
9. Mizrahi, O.; Amir, N.; Pollak, E.; Chusid, O.; Marks, V.; Gottlieb, H.; Larush, L.; Zinigrad, E.; Aurbach, D. Electrolyte Solutions with A Wide Electrochemical Window for Recharge Magnesium Batteries J. Electrochem. Soc. 2008, 155, A103-A109 10.1149/1.2806175
10. Mohtadi, R.; Matsui, M.; Arthur, T. S.; Hwang, S.-J. Magnesium Borohydride: From Hydrogen Storage to Magnesium Battery Angew. Chem., Int. Ed. 2012, 51, 9780-9783 10.1002/anie.201204913
11. Tuerxun, F.; Abulizi, Y.; NuLi, Y.; Shuojian, S.; Jun, Y.; JiuLin, W. High Concentration Magnesium Borohydride/tetraglyme Electrolyte for Rechargeable Magnesium Batteries J. Power Sources 2015, 276, 255-261 10.1016/j.jpowsour.2014.11.113
12. Liebenow, C.; Yang, Z.; Lobitz, P. The Electrodeposition of Magnesium Using Solutions of Organomagnesium Halides, Amidomagnesium Halides and Magnesium Organoborates Electrochem. Commun. 2000, 2, 641-645 10.1016/S1388-2481(00)00094-1
13. Wang, F.-f.; Guo, Y.-s.; Yang, J.; Nuli, Y.; Hirano, S.-i. A Novel Electrolyte System without a Grignard Reagent for Rechargeable Magnesium Batteries Chem. Commun. 2012, 48, 10763-10765 10.1039/c2cc35857c
14. Liao, C.; Guo, B.; Jiang, D.-e.; Custelcean, R.; Mahurin, S. M.; Sun, X.-G.; Dai, S. Highly Soluble Alkoxide Magnesium Salts for Rechargeable Magnesium Batteries J. Mater. Chem. A 2014, 2, 581-584 10.1039/C3TA13691D
15. Yagi, S.; Tanaka, A.; Ichikawa, Y.; Ichitsubo, T.; Matsubara, E. Electrochemical Stability of Magnesium Battery Current Collectors in a Grignard Reagent-Based Electrolyte J. Electrochem. Soc. 2013, 160, C83-C88 10.1149/2.033303jes
16. Barile, C. J.; Spatney, R.; Zavadil, K. R.; Gewirth, A. A. Investigating the Reversibility of in Situ Generated Magnesium Organohaloalurninates for Magnesium Deposition and Dissolution J. Phys. Chem. C 2014, 118, 10694-10699 10.1021/jp503506c
17. Liu, T.; Shao, Y.; Li, G.; Gu, M.; Hu, J.; Xu, S.; Nie, Z.; Chen, X.; Wang, C.; Liu, J. A Facile Approach Using MgCl2 to Formulate High Performance Mg2+ Electrolytes for Rechargeable Mg Batteries J. Mater. Chem. A 2014, 2, 3430-3438 10.1039/c3ta14825d
18. Zhao-Karger, Z.; Mueller, J. E.; Zhao, X.; Fuhr, O.; Jacob, T.; Fichtner, M. Novel Transmetalation Reaction for Electrolyte Synthesis for Rechargeable Magnesium Batteries RSC Adv. 2014, 4, 26924-26927 10.1039/c4ra03867c
19. Doe, R. E.; Han, R.; Hwang, J.; Gmitter, A. J.; Shterenberg, I.; Yoo, H. D.; Pour, N.; Aurbach, D. Novel Electrolyte Solutions Comprising Fully Inorganic Salts with High Anodic Stability for Rechargeable Magnesium Batteries Chem. Commun. 2014, 50, 243-245 10.1039/C3CC47896C
20. Kim, H. S.; Arthur, T. S.; Allred, G. D.; Zajicek, J.; Newman, J. G.; Rodnyansky, A. E.; Oliver, A. G.; Boggess, W. C.; Muldoon, J. Structure and Compatibility of a Magnesium Electrolyte with a Sulphur Cathode Nat. Commun. 2011, 2, 427 10.1038/ncomms1435
21. Ha, S. Y.; Lee, Y. W.; Woo, S. W.; Koo, B.; Kim, J. S.; Cho, J.; Lee, K. T.; Choi, N. S. Magnesium(II) Bis(trifluoromethane sulfonyl) Imide-Based Electrolytes with Wide Electrochemical Windows for Rechargeable Magnesium Batteries ACS Appl. Mater. Interfaces 2014, 6, 4063-4073 10.1021/am405619v
22. Shterenberg, I.; Salama, M.; Yoo, H. D.; Gofer, Y.; Park, J.-B.; Sun, Y.-K.; Aurbach, D. Evaluation of (CF3SO2)2N- (TFSI) Based Electrolyte Solutions for Mg Batteries J. Electrochem. Soc. 2015, 162, A7118-A7128 10.1149/2.0161513jes
23. Doe, R. E.; Lane, G. H.; Jilek, R. E.; Hwang, J., High Voltage Rechargeable Magnesium Cells Having a Non-aqueous Electrolyte. U. S. Patent 9293790, March 22, 2016.
24. Sa, N.; Wang, H.; Proffit, L. D.; Lipson, L. A.; Key, B.; Liu, M.; Feng, Z.; Fister, T. T.; Ren, Y.; Sun, C.; Vaughey, T. J.; Fenter, A. P.; Persson, A. K.; Burrell, K. A. Is Alpha-V2O5 a Cathode Material for Mg Insertion Batteries? J. Power Sources 2016, 323, 44-50 10.1016/j.jpowsour.2016.05.028
25. Cheng, Y.; Stolley, R. M.; Han, K. S.; Shao, Y.; Arey, B. W.; Washton, N. M.; Mueller, K. T.; Helm, M. L.; Sprenkle, V. L.; Liu, J.; Li, G. Highly Active Electrolytes for Rechargeable Mg Batteries Based on A [Mg2([small mu ]-Cl)2]2+ Cation Complex in Dimethoxyethane Phys. Chem. Chem. Phys. 2015, 17, 13307-13314 10.1039/C5CP00859J
26. Levi, E.; Gofer, Y.; Vestfreed, Y.; Lancry, E.; Aurbach, D. Cu2Mo6S8 Chevrel Phase, A Promising Cathode Material for New Rechargeable Mg Batteries: A Mechanically Induced Chemical Reaction Chem. Mater. 2002, 14, 2767-2773 10.1021/cm021122o
27. Levi, M. D.; Gizbar, H.; Lancry, E.; Gofer, Y.; Levi, E.; Aurbach, D. A Comparative Study of Mg2+ and Li+ Ion Insertions Into the (MoS8)-S-6 Chevrel Phase Using Electrochemical Impedance Spectroscopy J. Electroanal. Chem. 2004, 569, 211-223 10.1016/j.jelechem.2004.03.004
28. Sheldrick, G. M. SADABS-2008/1 Absorption Correction Program; Bruker AXS: Madison, WI, 2008.
29. Sheldrick, G. M. SHELXTL-2008/4, Structure Determination Software Suite; Bruker AXS:n Madison, WI, 2008.
30. Liu, T. B.; Shao, Y. Y.; Li, G. S.; Gu, M.; Hu, J. Z.; Xu, S. C.; Nie, Z. M.; Chen, X. L.; Wang, C. M.; Liu, J. A Facile Approach Using MgCl2 to Formulate High Performance Mg2+ Electrolytes for Rechargeable Mg Batteries J. Mater. Chem. A 2014, 2, 3430-3438 10.1039/c3ta14825d
31. Pan, B.; Zhang, J.; Huang, J.; Vaughey, J. T.; Zhang, L.; Han, S.-D.; Burrell, A. K.; Zhang, Z.; Liao, C. A Lewis Acid-free and Phenolate-based Magnesium Electrolyte for Rechargeable Magnesium Batteries Chem. Commun. 2015, 51, 6214-6217 10.1039/C5CC01225B
32. Wan, L. F.; Perdue, B. R.; Apblett, C. A.; Prendergast, D. Mg Desolvation and Intercalation Mechanism at the Mo6S8 Chevrel Phase Surface Chem. Mater. 2015, 27, 5932-5940 10.1021/acs.chemmater.5b01907