Coordination Chemistry in magnesium battery electrolytes: How ligands affect their performance

Scientific Reports

Volumn 3, Issue , 2013, Pages

  Shao, Yuyan ^a   Liu, Tianbiao ^a   Li, Guosheng ^a   Gu, Meng ^a   Nie, Zimin ^a   Engelhard, Mark ^a   Xiao, Jie ^a   Lv, Dongping ^a   Wang, Chongmin ^a   Zhang, Ji Guang ^a   Liu, Jun ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84889241811     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep03130     Document Type: Article

References (54)

1. Liu, J. et al. Materials science and materials chemistry for large scale electrochemical energy storage: from transportation to electrical grid. Adv. Funct. Mater. 23, 929-946 (2013).
2. Yang, Z. G. et al. Electrochemical energy storage for green grid. Chem. Rev. 111, 3577-3613 (2011).
3. Bruce, P. G., Scrosati, B. & Tarascon, J.M.Nanomaterials for rechargeable lithium batteries. Angew. Chem.-Int. Edit. 47, 2930-2946 (2008).
4. Dunn, B., Kamath, H. & Tarascon, J. M. Electrical energy storage for the grid: a battery of choices. Science 334, 928-935 (2011).
5. Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J. M. Li-O2 and Li-S batteries with high energy storage. Nat. Mater. 11, 19-29 (2012).
6. Matsui, M. Study on electrochemically deposited Mg metal. J. Power Sources 196, 7048-7055 (2011).
7. Ling, C., Banerjee, D. &Matsui, M. Study of the electrochemical deposition of Mg in the atomic level: why it prefers the non-dendritic morphology. Electrochim. Acta 76, 270-274 (2012).
8. Yoo, H. D. et al.Mg rechargeable batteries: an on-going challenge. Energy Environ. Sci. 6, 2265-2279 (2013).
9. Aurbach, D. et al. Progress in rechargeable magnesium battery technology. Adv. Mater. 19, 4260-4267 (2007). (Pubitemid 350254808)
10. Muldoon, J. et al. Electrolyte roadblocks to a magnesium rechargeable battery. Energy Environ. Sci. 5, 5941-5950 (2012).
11. Lv, D. P. et al. A scientific study of current collectors for Mg batteries in Mg(AlCl2EtBu)2/THF electrolyte. J. Electrochem. Soc. 160, A351-A355 (2013).
12. Aurbach, D. et al. Prototype systems for rechargeable magnesium batteries. Nature 407, 724-727 (2000).
13. Pour, N., Gofer, Y., Major, D. T. & Aurbach, D. Structural analysis of electrolyte solutions for rechargeable Mg batteries by stereoscopic means and DFT calculations. J. Am. Chem. Soc. 133, 6270-6278 (2011).
14. Mizrahi, O. et al. Electrolyte solutions with a wide electrochemical window for recharge magnesium batteries. J. Electrochem. Soc. 155, A103-A109 (2008).
15. Guo, Y. S. et al. Boron-based electrolyte solutions with wide electrochemical windows for rechargeable magnesium batteries. Energy Environ. Sci. 5, 9100-9106 (2012).
16. Kim, H. S. et al. Structure and compatibility of a magnesium electrolyte with a sulphur cathode. Nat. Commun. 2, 427 (2011).
17. Mohtadi, R., Matsui, M., Arthur, T. S. & Hwang, S. J. Magnesium borohydride: from hydrogen storage to magnesium battery. Angew. Chem.-Int. Edit. 51, 9780-9783 (2012).
18. Levi, E., Gofer, Y. & Aurbach, D. On the way to rechargeable mg batteries: the challenge of new cathode materials. Chem. Mat. 22, 860-868 (2010).
19. Levi, E., Gershinsky, G., Aurbach, D., Isnard, O. & Ceder, G. New insight on the unusually high ionic mobility in chevrel phases. Chem. Mat. 21, 1390-1399 (2009).
20. Zheng, Y. P. et al. Magnesium cobalt silicate materials for reversible magnesium ion storage. Electrochim. Acta 66, 75-81 (2012).
21. Nuli, Y. N., Yang, J., Li, Y. S. & Wang, J. L. Mesoporous magnesium manganese silicate as cathode materials for rechargeable magnesium batteries. Chem. Commun. 46, 3794-3796 (2010).
22. Inamoto, M., Kurihara, H. & Yajima, T. Electrode performance of vanadium pentoxide xerogel prepared by microwave irradiation as an active cathode material for rechargeable magnesium batteries. Electrochemistry 80, 421-422 (2012).
23. Lancry, E., Levi, E., Mitelman, A., Malovany, S. & Aurbach, D. Molten salt synthesis (MSS) of Cu2Mo6S8-new way for large-scale production of chevrel phases. J. Solid State Chem. 179, 1879-1882 (2006). (Pubitemid 43782581)
24. NuLi, Y. N., Zheng, Y. P., Wang, Y., Yang, J. & Wang, J. L. Electrochemical intercalation of Mg21 in 3d hierarchically porous magnesium cobalt silicate and its application as an advanced cathode material in rechargeable magnesium batteries. J. Mater. Chem. 21, 12437-12443 (2011).
25. Liang, Y. L. et al. Rechargeable Mg batteries with graphene-like MoS2 cathode and ultrasmall Mg nanoparticle anode. Adv. Mater. 23, 640-643 (2011).
26. Yang, S. Q., Li, D. X., Zhang, T. R., Tao, Z. L. & Chen, J. First-principles study of zigzag MoS2 nanoribbon as a promising cathode material for rechargeable Mg batteries. J. Phys. Chem. C 116, 1307-1312 (2012).
27. Singh, N., Arthur, T. S., Ling, C., Matsui, M. & Mizuno, F. A high energy-density tin anode for rechargeable magnesium-ion batteries. Chem. Commun. 49, 149-151 (2013).
28. Lu, Z., Schechter, A., Moshkovich, M. & Aurbach, D. On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions. J. Electroanal. Chem. 466, 203-217 (1999).
29. Gregory, T. D.,Hoffman, R. J.&Winterton, R. C. Nonaqueous electrochemistry of magnesium-applications to energy storage. J. Electrochem. Soc. 137, 775-780 (1990).
30. Aurbach, D. et al. A comparison between the electrochemical behavior of reversible magnesium and lithium electrodes. J. Power Sources 97-8, 269-273 (2001). (Pubitemid 32631265)
31. Aurbach, D. et al. A short review on the comparison between Li battery systems and rechargeable magnesium battery technology. J. Power Sources 97-98, 28-32 (2001). (Pubitemid 32631212)
32. Aurbach, D. et al. Electrolyte solutions for rechargeable magnesium batteries based on organomagnesium chloroaluminate complexes. J. Electrochem. Soc. 149, A115-A121 (2002).
33. Aurbach, D., Moshkovich, M., Schechter, A. & Turgeman, R. Magnesium deposition and dissolution processes in ethereal grignard salt solutions using simultaneous EQCM-EIS and in situ FTIR spectroscopy. Electrochem. Solid State Lett. 3, 31-34 (2000). (Pubitemid 32211582)
34. Aurbach, D., Schechter, A., Moshkovich, M. & Cohen, Y. On the mechanisms of reversible magnesium deposition processes. J. Electrochem. Soc. 148, A1004-A1014 (2001).
35. Connor, J. H., Reid, W. E. & Wood, G. B. Electrodeposition of metals from organic solutions. 5. electrodeposition of magnesium and magnesium alloys. J. Electrochem. Soc. 104, 38-41 (1957).
36. Poonia, N. S. & Bajaj, A. V. Coordination chemistry of alkali and alkaline-earth cations. Chem. Rev. 79, 389-445 (1979).
37. Bremer, M., Linti, G., Noth, H., Thomann-Albach, M. & Wagner, G. Metal tetrahydroborates and tetrahydroborato metalates. 30[1] solvates of alcoholato-, phenolato-, and bis(trimethylsilyl)amido-magnesium tetrahydroborates XMgBH4(Ln). Z. Anorg. Allg. Chem. 631, 683-697 (2005).
38. Schwarzenbach, G. Der chelateffekt. Helv. Chim. Acta 35, 2344-2363 (1952).
39. Breslow, R., Belvedere, S., Gershell, L. & Leung, D. The chelate effect in binding, catalysis, and chemotherapy. Pure Appl. Chem. 72, 333-342 (2000).
40. Adamson, A. W. A proposed approach to the chelate effect. J. Am. Chem. Soc. 76, 1578-1579 (1954).
41. Vantruong, N. et al. Selectivities and thermodynamic parameters of alkali-metal and alkaline-earth-metal complexes of polyethylene-glycol dimethyl ethers in methanol and acetonitrile. Inorg. Chim. Acta 184, 59-65 (1991).
42. Bond, T. M., Burns, J. C., Stevens, D. A., Dahn, H. M. & Dahn, J. R. Improving precision and accuracy in coulombic efficiency measurements of Li-ion batteries. J. Electrochem. Soc. 160, A521-A527 (2013).
43. Xu, K. Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. Chem. Rev. 104, 4303-4417 (2004).
44. Dudley, J. T. et al. Conductivity of electrolytes for rechargeable lithium batteries. J. Power Sources 35, 59-82 (1991). (Pubitemid 21694753)
45. Aurbach, D., Zinigrad, E., Cohen, Y. & Teller, H. A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions. Solid State Ion. 148, 405-416 (2002). (Pubitemid 34545666)
46. Aurbach, D., Zinigrad, E., Teller, H. & Dan, P. Factors which limit the cycle life of rechargeable lithium (metal) batteries. J. Electrochem. Soc. 147, 1274-1279 (2000).
47. Il'inchik, E. A. Standards for X-ray photoelectron spectroscopy of boron compounds. J. Appl. Spectrosc. 75, 883-891 (2008).
48. Gofer, Y., Turgeman, R., Cohen, H. & Aurbach, D. XPS investigation of surface chemistry of magnesium electrodes in contact with organic solutions of organochloroaluminate complex salts. Langmuir 19, 2344-2348 (2003).
49. Viestfrid, Y., Levi, M. D., Gofer, Y. & Aurbach, D. Microelectrode studies of reversible Mg deposition in THF solutions containing complexes of alkylaluminum chlorides and dialkylmagnesium. J. Electroanal. Chem. 576, 183-195 (2005). (Pubitemid 40219962)
50. Lobkovskii, E. B., Titov, L. V., Levicheva, M. D. & Chekhlov, A. N. Crystal and molecular-structure of magnesium borohydride diglymate. J. Struct. Chem. 31, 506-508 (1990).
51. Lobkovskii, E. B., Titov, L. V., Psikha, S. B.,Antipin,M. Y.&Struchkov, Y. T. X-ray crystallographic investigation of crystals of bis(tetrahydroborato)tris(tetrahydrofuranato) magnesium. J. Struct. Chem. 23, 644-646 (1982).
52. Levi, E. et al. Phase diagram of Mg insertion into chevrel phases, MgxMo6T8 (T 5 S, Se), 2. the crystal structure of triclinic MgMo6Se8. Chem. Mat. 18, 3705-3714 (2006). (Pubitemid 44318551)
53. Chan, L. L., Wong, K. H. & Smid, J. Complexation of lithium, sodium, and potassium carbanion pairs with polyglycol dimethy ethers (glymes), effect of chain length and temperature. J Am. Chem. Soc. 92, 1955-1963 (1970).
54. Brown, H. C., Narasimhan, S. & Choi, Y. M. Selective reductions. 30. effect of cation and solvent on the reactivity of saline borohydrides for reduction of carboxylic esters-improved procedures for the conversion of esters to alcohols by metal borohydrides. J. Org. Chem. 47, 4702-4708 (1982).