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Even with very low amounts of Zr(NMe, (4 mol), the obtained product was insoluble.
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[27b]
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Furthermore, we carried out a model reaction using, 7, Zr(NMe, (0.5 equiv)THF under conditions comparable to those used for the cross-linking of, 13′, During, B{, H} NMR reaction monitoring, a resonance at, =37 ppm was detected (Figure S22), which is downfield-shifted by Δ, =5–6 ppm compared to the resonance of, 7, A downfield shift of the same magnitude (Δ, =4.7 ppm) was observed by Manke and Nocera upon the formation of the related complex (t, BuN−B(Ph)−N, t, Bu), Zr(THF)
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