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Volumn 110, Issue 7, 2010, Pages 4079-4124

Ammonia-Borane and related compounds as dihydrogen sources

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA GAS; CROSSLINKED STRUCTURES; DIHYDROGEN; DIHYDROGEN BONDS; INELASTIC INCOHERENT NEUTRON SCATTERING; LITHIUM IMIDE; LITHIUM NITRIDE; LOW FREQUENCY; NON-VOLATILE; POLYAMINOBORANE; POWDER X RAY DIFFRACTION; RELATED COMPOUNDS; TORSIONAL MOTION;

EID: 77955216404     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/cr100088b     Document Type: Article
Times cited : (1084)

References (324)
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    • For computational studies of this reaction, see
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    • 2 with V = potential energy, x = distance form equilibrium distance, and k = force constant. However, such a model is unrealistic, as it will not allow dissociation of the molecule, gives equidistant energy levels, and does not adequately allow for internuclear repulsion. A more realistic approach is the use of a Morse potential, where not only the latter is accounted for, but the energy levels move closer and closer together, the higher the energy, and asymptotically approach the dissociation energy. The shape of this potential is not symmetrical with respect to the equilibrium distance but allows for much larger elongations, the closer in energy the system is to the dissociation energy than the harmonic oscillator. Therefore, the larger the anharmonicity of a system, i.e. the higher the anharmonicity constant, the smaller the dissociation energy. See, for example: (a) Wedler, G. Lehrbuch der Physikalischen Chemie, 4 th ed.; Wiley VCH: 1997; or
    • (1997) Lehrbuch der Physikalischen Chemie
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    • For some recent reviews of materials other than ammonia-borane, see
    • For some recent reviews of materials other than ammonia-borane, see
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    • -1
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    • note
    • The thermal dehydrogenation of borazine to form boron nitride has elicited considerable interest due to the material properties of boron nitride. While this expands the chemical knowledge of formally the third dehydrogenation step of ammonia-borane, this is of no interest for hydrogen storage purposes, as, firstly, borazine is a fuel cell poison and, secondly, formation of boron nitride as a thermodynamically extremely stable product makes recycling impossible. Readers who are interested in this aspect of ammonia-borane chemistry are referred to, for example
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    • note
    • 2 to AB was observed to lower the dehydrogenation temperature and increase the hydrogen yield by Sneddon and co-workers, which was published as a preliminary result in: New Methods for Promoting Amineborane Dehydrogenation/Regeneration Reactions; Sneddon, L. G., Ed.; DoE Hydrogen Program, FY, Annual Progress Report, Section IV.B.4g; 2006; p 418.
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    • Sneddon, L.G.1
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    • For a variety of values for these amine-boranes at different temperatures/pressures, see
    • For a variety of values for these amine-boranes at different temperatures/pressures, see: Schlesinger, H. I., Ritter, D. M., and Burg, A. B. J. Am. Chem. Soc. 1938, 60, 1296
    • (1938) J. Am. Chem. Soc. , vol.60 , pp. 1296
    • Schlesinger, H.I.1    Ritter, D.M.2    Burg, A.B.3
  • 282
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    • Amineborane-Based Chemical Hydrogen Storage, DoE Hydrogen Program Review, 2007
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.