Origin of the Regioselective Fatty-Acid Hydroxylation versus Decarboxylation by a Cytochrome P450 Peroxygenase: What Drives the Reaction to Biofuel Production?

Chemistry - A European Journal

Volumn 22, Issue 16, 2016, Pages 5478-5483

  Faponle, Abayomi S ^a   Quesne, Matthew G ^a   De Visser, Sam P ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

bioengineering; cytochromes; density functional calculations; heme proteins; iron

Indexed keywords

BIFURCATION (MATHEMATICS); CARBOXYLATION; DENSITY FUNCTIONAL THEORY; HYDROXYLATION; IRON; PORPHYRINS; PROTEINS; SYSTEMS SCIENCE;

BIODIESEL PRODUCTION; BIOFUEL PRODUCTION; DECARBOXYLATION REACTIONS; DESATURASE ACTIVITY; HEME PROTEINS; LONG CHAIN FATTY ACID; SOLVENT ACCESSIBILITY; VALENCE BOND MODELS;

FATTY ACIDS;

BIOFUEL; CYTOCHROME P-450 PEROXYGENASE; CYTOCHROME P450; FATTY ACID; PEROXIDASE;

CHEMISTRY; DECARBOXYLATION; HYDROXYLATION; KINETICS; METABOLISM; OXIDATION REDUCTION REACTION;

BIOFUELS; CYTOCHROME P-450 ENZYME SYSTEM; DECARBOXYLATION; FATTY ACIDS; HYDROXYLATION; KINETICS; OXIDATION-REDUCTION; PEROXIDASES;

EID: 84961785318     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201600739     Document Type: Article

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