Enantioselective Construction of Quaternary Carbon Stereocenter via Palladium-Catalyzed Asymmetric Allylic Alkylation of Lactones

Synthesis (Germany)

Volumn 48, Issue 10, 2016, Pages 1568-1572

  Li, Xiao Hui ^a   Wan, Shi Li ^a   Chen, Di ^a   Liu, Qing Rong ^a   Ding, Chang Hua ^a   Fang, Ping ^a   Hou, Xue Long ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

allylic alkylation; asymmetric catalysis; lactones; palladium; quaternary carbon

Indexed keywords

ALKYLATION; ALLYLATION; BIOCHEMISTRY; CATALYSIS; ENANTIOSELECTIVITY; PALLADIUM;

ALLYLIC ALKYLATION; ASYMMETRIC ALLYLIC ALKYLATIONS; ASYMMETRIC CATALYSIS; ENANTIOSELECTIVE CONSTRUCTION; LACTONES; PALLADIUM-CATALYZED; PRACTICAL METHOD; QUATERNARY CARBON;

ESTERS;

3 ALLYL 3 BENZYLTETRAHYDRO 2H PYRAN 2 ONE; 3 ALLYL 3 ETHYLTETRAHYDRO 2H PYRAN 2 ONE; 3 ALLYL 3 ISOBUTYLTETRAHYDRO 2H PYRAN 2 ONE; 3 ALLYL 3 METHYLCHROMAN 2 ONE; 3 ALLYL 3 METHYLTETRAHYDRO 2H PYRAN 2 ONE; 3 ALLYL 3 PHENYLTETRAHYDRO 2H PYRAN 2 ONE; 3 BENZYL 3 CINNAMYLTETRAHYDRO 2H PYRAN 2 ONE; 3 CINNAMYL 3 PHENYLTETRAHYDRO 2H PYRAN 2 ONE; 3 [3 (FURAN 2 YL)ALLYL] 3 PHENYLTETRAHYDRO 2H PYRAN 2 ONE; CARBON; LACTONE; PALLADIUM; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CATALYSIS; CHIRALITY; ENANTIOSELECTIVITY; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 84960447769     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0035-1561574     Document Type: Article

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