Regio- and enantioselective palladium-catalyzed allylic alkylation of nitromethane with monosubstituted allyl substrates: Synthesis of (R)-rolipram and (R)-baclofen

Journal of Organic Chemistry

Volumn 77, Issue 20, 2012, Pages 8980-8985

  Yang, Xiao Fei ^a   Ding, Chang Hua ^a   Li, Xiao Hui ^a   Huang, Jian Qiang ^a   Hou, Xue Long ^a   Dai, Li Xin ^a   Wang, Pin Jie ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC ALKYLATION; ASYMMETRIC ALLYLIC ALKYLATION REACTIONS; BACLOFEN; ENANTIOSELECTIVE; ENANTIOSELECTIVE SYNTHESIS; HIGH YIELD; NITROMETHANE; PALLADIUM-CATALYZED;

ALLYLATION; CATALYSIS;

ENANTIOSELECTIVITY;

ALLYL COMPOUND; BACLOFEN; NITROMETHANE; PALLADIUM; ROLIPRAM;

ALKYLATION; ARTICLE; ASYMMETRIC ALLYLIC ALKYLATION; CATALYSIS; CATALYST; CHIRALITY; DRUG SYNTHESIS; ENANTIOSELECTIVITY; QUANTUM YIELD; REACTION ANALYSIS; STEREOCHEMISTRY;

ALKYLATION; ALLYL COMPOUNDS; BACLOFEN; CATALYSIS; METHANE; MOLECULAR STRUCTURE; NITROPARAFFINS; ORGANOMETALLIC COMPOUNDS; PALLADIUM; ROLIPRAM; STEREOISOMERISM;

EID: 84867730650     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo301506p     Document Type: Article

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