High-internal-phase emulsions stabilized by metal-organic frameworks and derivation of ultralight metal-organic aerogels

Scientific Reports

Volumn 6, Issue , 2016, Pages

  Zhang, Bingxing ^a   Zhang, Jianling ^a   Liu, Chengcheng ^a   Peng, Li ^a   Sang, Xinxin ^a   Han, Buxing ^a   Ma, Xue ^a   Luo, Tian ^a   Tan, Xiuniang ^a   Yang, Guanying ^a  

^a INSTITUTE OF CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84959020727     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep21401     Document Type: Article

References (51)

1. Furukawa, H., Müller, U., Yaghi, O. M. "Heterogeneity within Order" in metal-organic frameworks. Angew. Chem. Int. Ed. 54, 3417-3430 (2015).
2. Furukawa, H., Cordova, K. E., O'Keeffe, M., Yaghi, O. M. The chemistry and applications of metal-organic frameworks. Science 341, 1230444 (2013).
3. Burtch, N. C., Jasuja, H., Walton, K. S. Water Stability and Adsorption in metal-organic frameworks. Chem. Rev. 114, 10575-10612 (2014).
4. Murray, L. J., Dinc?, M., Long, J. R. Hydrogen storage in metal-organic frameworks. Chem. Soc. Rev. 38, 1294-1314 (2009).
5. Makal, T. A., Li, J.-R., Lua, W., Zhou, H.-C. Methane storage in advanced porous materials. Chem. Soc. Rev. 41, 7761-7779 (2012).
6. He, Y., Zhou, W., Qian, G., Chen, B. Methane storage in metal-organic frameworks. Chem. Soc. Rev. 43, 5657-5678 (2014).
7. Yan, Y., Yang, S., Blake, A. J., Schröder, M. Studies on metal-organic frameworks of Cu(II) with isophthalate linkers for hydrogen storage. Acc. Chem. Res. 47, 296-307 (2014).
8. Li, J.-R., Kuppler, R. J., Zhou, H.-C. Selective gas adsorption and separation in metal-organic frameworks. Chem. Soc. Rev. 38, 1477-1504 (2009).
9. Voorde, B. V., Bueken, B., Denayer, J., Vos, D. D. Adsorptive separation on metal-organic frameworks in the liquid phase. Chem. Soc. Rev. 43, 5766-5788 (2014).
10. Li, J.-R., Sculley, J., Zhou, H.-C. Metal-organic frameworks for separations. Chem. Rev. 112, 869-932 (2012).
11. Douvali, A. et al. Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metalorganic framework. Angew. Chem. Int. Ed. 54, 1651-1656 (2015).
12. Gassensmith, J. J. et al. A Metal-organic framework-based material for electrochemical sensing of carbon dioxide. J. Am. Chem. Soc. 136, 8277-8282 (2014).
13. Zhang, M. et al. Two-dimensional metal-organic framework with wide channels and responsive turn-on fluorescence for the chemical sensing of volatile organic compounds. J. Am. Chem. Soc. 136, 7241-7244 (2014).
14. Campbell, M. G., Sheberla, D., Liu, S. F., Swager, T. M., Dinca, M. Cu3(hexaiminotriphenylene)2: An electrically conductive 2D metal-organic framework for chemiresistive sensing. Angew. Chem. Int. Ed. 54, 4349-4352 (2015).
15. Corma, A., GarcIá, H., Llabrés i Xamena & F. X. Engineering metal organic frameworks for heterogeneous catalysis. Chem. Rev. 110, 4606-4655 (2010).
16. Dhakshinamoorthy, A., Garcia, H. Catalysis by metal nanoparticles embedded on metal-organic frameworks. Chem. Soc. Rev. 41, 5262-5284 (2012).
17. Falkowski, J. M. et al. Privileged Phosphine-based metal-organic frameworks for broad-scope asymmetric catalysis. J. Am. Chem. Soc. 136, 5213-5216 (2014).
18. Dhakshinamoorthy, A., Asiric, A. M., Garcia, H. Metal-organic frameworks catalyzed C-C and C-heteroatom coupling reactions. Chem. Soc. Rev. 44, 1922-1947 (2015).
19. Manna, K., Zhang, T., Greene, F. X., Lin, W. Bupyridine-and phenanthroline-based metal-organic frameworks for highly efficient and tandem catalytic organic transformations via directed C-H activation. J. Am. Chem. Soc. 137, 2665-2673 (2015).
20. Lohe, M. R., Rose, M., Kaskel, S. Metal-organic framework (MOF) aerogels with high micro-and macroporosity. Chem. Commun. 40, 6056-6058 (2009).
21. Li, L. et al. A synthetic route to ultralight hierarchically micro/mesoporous Al(III)-carboxylate metal-organic aerogels. Nat. Commun. 4, 1774 (2013).
22. Xia, W. et al. Facile and economical synthesis of metal-organic framework MIL-100(Al) gels for high efficiency removal of microcystin-LR. RSC Adv. 3, 11007-11013 (2013).
23. Li, H. et al. Luminescent metal-organic gels with tetraphenylethylene moieties: Porosity and aggregation-induced emission. RSC Adv. 3, 16340-16344 (2013).
24. Piepenbrock, M. O. M., Lloyd, G. O., Clarke, N., Steed, J. W. Metal-and anion-binding supramolecular gels. Chem. Rev. 110, 1960-2004 (2010).
25. Butler, R., Hopkinson, I., Cooper, A. I. Synthesis of porous emulsion-templated polymers using high internal phase CO2-in-water emulsions. J. Am. Chem. Soc. 125, 14473-14481 (2003).
26. Schüler, F. et al. Synthesis of macroporous polystyrene by the polymerization of foamed emulsions. Angew. Chem. Int. Ed. 51, 2213-2217 (2012).
27. Oschatz, M. et al. Carbide-derived carbon monoliths with hierarchical pore architectures. Angew. Chem. Int. Ed. 51, 7577-7580 (2012).
28. Zhang, H. F., Cooper, A. I. Synthesis and applications of emulsion-templated porous materials. Soft Matter 1, 107-113 (2005).
29. Dhanuka, V. V., Dickson, J. L., Ryoo, W., Johnston, K. P. High internal phase CO2-in-water emulsions stabilized with a branched nonionic hydrocarbon surfactant. J. Colloid Interface Sci. 298, 406-418 (2006).
30. Ikem, V. O., Menner, A., Bismarck, A. High internal phase emulsions stabilized solely by functionalized silica particles. Angew. Chem. Int. Ed. 47, 8277-8279 (2008).
31. Li, Z., Ming, T., Wang, J., Ngai, T. High internal phase emulsions stabilized solely by microgel particles. Angew. Chem. Int. Ed. 45, 8490-8493 (2009).
32. Sun, G., Li, Z., Ngai, T. Inversion of particle-stabilized emulsions to form high-internal-phase emulsions. Angew. Chem. Int. Ed. 49, 2163-2166 (2010).
33. Huo, J., Marcello, M., Garai, A., Bradshaw, D. MOF-polymer composite microcapsules derived from pickering emulsions. Adv. Mater. 25, 2717-2722 (2013).
34. Xiao, B., Yuan, Q., Williams, R. A. Exceptional function of nanoporous metal organic framework particles in emulsion stabilization. Chem. Commun. 49, 8208-8210 (2013).
35. Chui, S. S. Y., Lo, S. M. F., Charmant, J. P. H., Orpen, A. G., Williams, I. D. A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n. Science 283, 1148-1150 (1999).
36. Qiu, L.-G. et al. Hierarchically micro-and mesoporous metal-organic frameworks with tunable porosity. Angew. Chem. Int. Ed. 47, 9487-9491 (2008).
37. Xiang, S., Zhou, W., Gallegos, J. M., Liu, Y., Chen, B., Exceptionally high acetylene uptake in a microporous metal-organic framework with open metal sites. J. Am. Chem. Soc. 131, 12415-12419 (2009).
38. Sun, L.-B., Li, J.-R., Park, J., Zhou, H.-C. Cooperative template-directed assembly of mesoporous metal-organic frameworks. J. Am. Chem. Soc. 134, 126-129 (2012).
39. Peng, L. et al. Surfactant-directed assembly of mesoporous metal-organic framework nanoplates in ionic liquids. Chem. Commun. 48, 8688-8690 (2012).
40. Peng, L. et al. Highly mesoporous metal-organic framework assembled in a switchable solvent. Nat. Commun. 5, 5465 (2014).
41. Zhang, B. et al. Solvent determines the formation and properties of metal-organic frameworks. RSC Adv. 5, 37691-37696 (2015).
42. Li, J., Zhang, J., Zhao, Y., Han, B., Yang, G. High-internal-ionic liquid-phase emulsions. Chem. Commun. 48, 994-996 (2012).
43. Zhang, D., Clegg, P. S. Relationship between high internal-phase Pickering emulsions and catastrophic inversion. Soft Matter 9, 7042-7048 (2013).
44. Lee, K.-Y., Blaker, J. J., Murakami, R., Heng, J. Y. Y., Bismarck, A. Phase behavior of medium and high internal phase water-in-oil emulsions stabilized solely by hydrophobized bacterial cellulose nanofibrils. Langmuir 30, 452-460 (2014).
45. Zheng, X., Zhang, Y., Wang, H., Du, Q. Interconnected macroporous polymers synthesized from silica particle stabilized high internal phase emulsions. Macromolecules 47, 6847-6855 (2014).
46. Ahmed, A., Forster, M., Clowes, R., Myers, P., Zhang, H. F. Hierarchical porous metal-organic framework monoliths. Chem. Commun. 50, 14314-14316 (2014).
47. Moitra, N. et al. Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(II) hydroxide-based monoliths. Chem. Commun. 51, 3511-3514 (2015).
48. Xiang, S. L. et al. Porous organic-inorganic hybrid aerogels based on Cr3+/Fe3+ and rigid bridging carboxylates. J. Mater. Chem. A. 22, 1862-1867 (2012).
49. Lin, S. et al. Adsorption behavior of metal-organic frameworks for methylene blue from aqueous solution. Micropor. Mesopor. Mater. 193, 27-34 (2014).
50. Tan, H. et al. Gelatin particle-stabilized high internal phase emulsions as nutraceutical containers. ACS Appl. Mater. Interfaces 6, 13977-13984 (2014).
51. Aveyard, R, Binks, B. P., Clint, J. H. Emulsions stabilised solely by colloidal particles. Adv. Colloid Interface Sci. 503, 100-102 (2003).