X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)

Applied Surface Science

Volumn 362, Issue , 2016, Pages 406-417

  Halim, Joseph ^a,b,c   Cook, Kevin M ^d   Naguib, Michael ^e   Eklund, Per ^c   Gogotsi, Yury ^a,b   Rosen, Johanna ^c   Barsoum, Michel W ^a,c  

^a Drexel University   (United States)

^b DREXEL UNIVERSITY   (United States)

^c LINKÖPING UNIVERSITY   (Sweden)

^d NAVAL AIR SYSTEMS COMMAND   (United States)

^e OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

Metal carbides; MXene; XPS

Indexed keywords

CARBIDES; PHOTOELECTRONS; PHOTONS; SURFACE CHEMISTRY; TRANSITION METALS;

METAL CARBIDES; MXENE; NEGATIVE CHARGE; NOMINAL COMPOSITION; SPUTTER CLEANING; SURFACE TERMINATION; TRANSITION METAL CARBIDE; TWO DIMENSIONAL (2 D);

X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 84955447114     PISSN: 01694332     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apsusc.2015.11.089     Document Type: Article

References (71)

1. K.S. Novoselov, V.I. Fal'ko, L. Colombo, P.R. Gellert, M.G. Schwab, and K. Kim A roadmap for graphene Nature 490 2012 192 200
2. K.I. Bolotin, K.J. Sikes, Z. Jiang, M. Klima, G. Fudenberg, J. Hone, P. Kim, and H.L. Stormer Ultrahigh electron mobility in suspended graphene Solid State Commun. 146 2008 351 355
3. R.R. Nair, P. Blake, A.N. Grigorenko, K.S. Novoselov, T.J. Booth, T. Stauber, N.M. Peres, and A.K. Geim Fine structure constant defines visual transparency of graphene Science 320 2008 1308
4. L. Ci, L. Song, C. Jin, D. Jariwala, D. Wu, Y. Li, A. Srivastava, Z.F. Wang, K. Storr, L. Balicas, F. Liu, and P.M. Ajayan Atomic layers of hybridized boron nitride and graphene domains Nat. Mater. 9 2010 430 435
5. J.N. Coleman, M. Lotya, A. O'Neill, S.D. Bergin, P.J. King, U. Khan, K. Young, A. Gaucher, S. De, R.J. Smith, I.V. Shvets, S.K. Arora, G. Stanton, H.Y. Kim, K. Lee, G.T. Kim, G.S. Duesberg, T. Hallam, J.J. Boland, J.J. Wang, J.F. Donegan, J.C. Grunlan, G. Moriarty, A. Shmeliov, R.J. Nicholls, J.M. Perkins, E.M. Grieveson, K. Theuwissen, D.W. McComb, P.D. Nellist, and V. Nicolosi Two-dimensional nanosheets produced by liquid exfoliation of layered materials Science 331 2011 568 571
6. A.M. van der Zande, P.Y. Huang, D.A. Chenet, T.C. Berkelbach, Y. You, G.H. Lee, T.F. Heinz, D.R. Reichman, D.A. Muller, and J.C. Hone Grains and grain boundaries in highly crystalline monolayer molybdenum disulphide Nat. Mater. 12 2013 554 561
7. S. Najmaei, Z. Liu, W. Zhou, X. Zou, G. Shi, S. Lei, B.I. Yakobson, J.C. Idrobo, P.M. Ajayan, and J. Lou Vapour phase growth and grain boundary structure of molybdenum disulphide atomic layers Nat. Mater. 12 2013 754 759
8. R. Ma, and T. Sasaki Nanosheets of oxides and hydroxides: ultimate 2D charge-bearing functional crystallites Adv. Mater. 22 2010 5082 5104
9. V. Nicolosi, M. Chhowalla, M.G. Kanatzidis, M.S. Strano, and J.N. Coleman Liquid exfoliation of layered materials Science 340 2013 1226419-1-1226419-18
10. S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, and R.S. Ruoff Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide Carbon 45 2007 1558 1565
11. M.K. Kinyanjui, C. Kramberger, T. Pichler, J.C. Meyer, P. Wachsmuth, G. Benner, and U. Kaiser Direct probe of linearly dispersing 2D interband plasmons in a free-standing graphene monolayer EPL 97 2012 57005
12. Y. Liu, R. Willis, K. Emtsev, and T. Seyller Plasmon dispersion and damping in electrically isolated two-dimensional charge sheets Phys. Rev. B: Condens. Matter Mater. Phys. 78 2008 201403
13. A. Politano, A.R. Marino, V. Formoso, D. Farias, R. Miranda, and G. Chiarello Evidence for acoustic-like plasmons on epitaxial graphene on Pt(1 1 1) Phys. Rev. B: Condens. Matter Mater. Phys. 84 2011 033401
14. E. Bekyarova, M.E. Itkis, P. Ramesh, C. Berger, M. Sprinkle, W.A. de Heer, and R.C. Haddon Chemical modification of epitaxial graphene: spontaneous grafting of aryl groups J. Am. Chem. Soc. 131 2009 1336 1337
15. D.R. Dreyer, S. Park, C.W. Bielawski, and R.S. Ruoff The chemistry of graphene oxide Chem. Soc. Rev. 39 2010 228 240
16. K.N. Kudin, B. Ozbas, H.C. Schniepp, R.K. Prud'homme, I.A. Aksay, and R. Car Raman spectra of graphite oxide and functionalized graphene sheets Nano Lett. 8 2008 36 41
17. 2 Adv. Mater. 23 2011 4248 4253
18. M.W. Barsoum MAX Phases: Properties of Machinable Ternary Carbides and Nitrides 2013 John Wiley & Sons Weinheim, Germany
19. M. Ghidiu, M.R. Lukatskaya, M.Q. Zhao, Y. Gogotsi, and M.W. Barsoum Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance Nature 516 2014 78 81
20. M. Naguib, O. Mashtalir, J. Carle, V. Presser, J. Lu, L. Hultman, Y. Gogotsi, and M.W. Barsoum Two-dimensional transition metal carbides ACS Nano 6 2012 1322 1331
21. M. Naguib, J. Halim, J. Lu, K.M. Cook, L. Hultman, Y. Gogotsi, and M.W. Barsoum New two-dimensional niobium and vanadium carbides as promising materials for Li-ion batteries J. Am. Chem. Soc. 135 2013 15966 15969
22. J. Halim, M.R. Lukatskaya, K.M. Cook, J. Lu, C.R. Smith, L.A. Naslund, S.J. May, L. Hultman, Y. Gogotsi, P. Eklund, and M.W. Barsoum Transparent conductive two-dimensional titanium carbide epitaxial thin films Chem. Mater. 26 2014 2374 2381
23. M. Naguib, V.N. Mochalin, M.W. Barsoum, and Y. Gogotsi 25th anniversary article: MXenes: a new family of two-dimensional materials Adv. Mater. 26 2014 992 1005
24. 3 (MXene) Chem. Commun. (Camb.) 50 2014 9517 9520
25. B. Anasori, Y. Xie, M. Beidaghi, J. Lu, B.C. Hosler, L. Hultman, P.R. Kent, Y. Gogotsi, and M.W. Barsoum Two-dimensional, ordered, double transition metals carbides (MXenes) ACS Nano 2015 10.1021/acsnano.5b03591
26. M. Naguib, J. Come, B. Dyatkin, V. Presser, P.L. Taberna, P. Simon, M.W. Barsoum, and Y. Gogotsi MXene: a promising transition metal carbide anode for lithium-ion batteries Electrochem. Commun. 16 2012 61 64
27. O. Mashtalir, M. Naguib, V.N. Mochalin, Y. Dall'Agnese, M. Heon, M.W. Barsoum, and Y. Gogotsi Intercalation and delamination of layered carbides and carbonitrides Nat. Commun. 4 2013 1716
28. 2 (X = F, OH) monolayer J. Am. Chem. Soc. 134 2012 16909 16916
29. 2 C-based two-dimensional negative electrode J. Electrochem. Soc. 159 2012 A1368 A1373
30. M.R. Lukatskaya, O. Mashtalir, C.E. Ren, Y. Dall'Agnese, P. Rozier, P.L. Taberna, M. Naguib, P. Simon, M.W. Barsoum, and Y. Gogotsi Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide Science 341 2013 1502 1505
31. O. Mashtalir, K.M. Cook, V.N. Mochalin, M. Crowe, M.W. Barsoum, and Y. Gogotsi Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media J. Mater. Chem. A 2 2014 14334 14338
32. Q. Peng, J. Guo, Q. Zhang, J. Xiang, B. Liu, A. Zhou, R. Liu, and Y. Tian Unique lead adsorption behavior of activated hydroxyl group in two-dimensional titanium carbide J. Am. Chem. Soc. 136 2014 4113 4116
33. X. Li, G. Fan, and C. Zeng Synthesis of ruthenium nanoparticles deposited on graphene-like transition metal carbide as an effective catalyst for the hydrolysis of sodium borohydride Int. J. Hydrogen Energy 39 2014 14927 14934
34. Z. Ling, C.E. Ren, M.-Q. Zhao, J. Yang, J.M. Giammarco, J. Qiu, M.W. Barsoum, and Y. Gogotsi Flexible and conductive MXene films and nanocomposites with high capacitance Proc. Nat. Acad. Sci. 111 2014 16676 16681
35. M. Naguib, R.R. Unocic, B.L. Armstrong, and J. Nanda Large-scale delamination of multi-layers transition metal carbides and carbonitrides "MXenes" Dalton Trans. 44 2015 9353 9358
36. 2 C MXene for Li-ion energy storage devices Adv. Mater. 27 2015 3501 3506
37. S. Balendhran, S. Walia, H. Nili, S. Sriram, and M. Bhaskaran Elemental analogues of graphene: silicene, germanene, stanene, and phosphorene Small 11 2015 640 652
38. H.S. Liu, N.N. Han, and J.J. Zhao Atomistic insight into the oxidation of monolayer transition metal dichalcogenides: from structures to electronic properties RSC Adv. 5 2015 17572 17581
39. M. Naguib, O. Mashtalir, M.R. Lukatskaya, B. Dyatkin, C. Zhang, V. Presser, Y. Gogotsi, and M.W. Barsoum One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes Chem. Commun. (Camb.) 50 2014 7420 7423
40. 2 J. Mater. Chem. A 2 2014 14339 14343
41. 2 Mater. Sci. Eng., B 191 2015 33 40
42. 2 C nanosheets Ceram. Int. 41 2015 2631 2635
43. S. Yamamoto, H. Bluhm, K. Andersson, G. Ketteler, H. Ogasawara, M. Salmeron, and A. Nilsson In situ X-ray photoelectron spectroscopy studies of water on metals and oxides at ambient conditions J. Phys. - Condens. Matter 20 2008 184025
44. C. Mousty-Desbuquoit, J. Riga, and J.J. Verbist Electronic structure of titanium(III) and titanium(IV) halides studied by solid-phase X-ray photoelectron spectroscopy Inorg. Chem. 26 1987 1212 1217
45. 5 J. Alloys Compd. 453 2008 138 142
46. 3 Sn-surfaces IEEE Trans. Magn. 23 1987 1381 1384
47. M.T. Marques, A.M. Ferraria, J.B. Correia, A.M.B.d. Rego, and R. Vilar XRD, XPS and SEM characterisation of Cu-NbC nanocomposite produced by mechanical alloying Mater. Chem. Phys. 109 2008 174 180
48. 0.5 C layers Fresenius J. Anal. Chem. 346 1993 227 232
49. E. Lewin, M. Gorgoi, F. Schäfers, S. Svensson, and U. Jansson Influence of sputter damage on the XPS analysis of metastable nanocomposite coatings Surf. Coat. Technol. 204 2009 455 462
50. 3 layered carbide/nitride phases - characterization by XPS J. Phys. Chem. Solids 62 2001 811 817
51. M.R. Lukatskaya, J. Halim, B. Dyatkin, M. Naguib, Y.S. Buranova, M.W. Barsoum, and Y. Gogotsi Room-temperature carbide-derived carbon synthesis by electrochemical etching of MAX phases Angew. Chem. Int. Ed. Engl. 53 2014 4877 4880
52. M. Naguib, J. Halim, J. Lu, K. Cook, L. Hultman, Y. Gogotsi, and M.W. Barsoum New two-dimensional niobium and vanadium carbides as promising materials for Li-ion batteries J. Am. Chem. Soc. 135 2013 15966 15969
53. G. Beamson, and D. Briggs High Resolution XPS of Organic Polymers: The Scienta ESCA300 Database 1992 Wiley Etobicoke, Ontario, Canada
54. T. Sultana, G.L. Georgiev, G. Auner, G. Newaz, H.J. Herfurth, and R. Patwa XPS analysis of laser transmission micro-joint between poly(vinylidene fluoride) and titanium Appl. Surf. Sci. 255 2008 2569 2573
55. F. Santerre, M.A. El Khakani, M. Chaker, and J.P. Dodelet Properties of TiC thin films grown by pulsed laser deposition Appl. Surf. Sci. 148 1999 24 33
56. 2 by XPS Surf. Sci. Spectra 4 1996 227
57. T. Tanuma, H. Okamoto, K. Ohnishi, S. Morikawa, and T. Suzuki Partially fluorinated metal oxide catalysts for a Friedel-Crafts-type reaction of dichlorofluoromethane with tetrafluoroethylene Catal. Lett. 136 2009 77 82
58. 2 (1 1 0) single-crystal surface J. Phys. Chem. C 111 2007 1764 1769
59. K.H. Ernst, D. Grman, R. Hauert, and E. Hollander Fluorine-induced corrosion of aluminum microchip bond pads - an XPS and AES analysis Surf. Interface Anal. 21 1994 691 696
60. 3 films on Al(1 1 1)-detection of an inner barrier layer Langmuir 16 2000 10309 10314
61. A. Dacca, G. Gemme, L. Mattera, and R. Parodi XPS analysis of the surface composition of niobium for superconducting RF cavities Appl. Surf. Sci. 126 1998 219 230
62. 5 thin films obtained by chemical spray pyrolysis Surf. Interface Anal. 36 2004 888 891
63. 5 thin films for nonvolatile memory application Curr. Appl. Phys. 11 2011 849 852
64. 5 microspheres with photocatalytic activities and electrochemical properties J. Mater. Chem. A 2 2014 9236 9243
65. 3 Nb and oxygen enhanced crack growth Scr. Mater. 42 2000 227 232
66. 5 electronic structure by XPS, UPS and first principles methods Surf. Interface Anal. 45 2013 1206 1210
67. n (X = C, N) monolayers Phys. Rev. B: Condens. Matter Mater. Phys. 87 2013 235441
68. M.R. Lukatskaya, S.-M. Bak, X. Yu, X.Q. Yang, M.W. Barsoum, and Y. Gogotsi Probing the mechanism of high capacitance in 2D titanium carbide using in situ X-ray absorption spectroscopy Adv. Energy Mater. 2015 10.1002/aenm.201500589
69. Y. Xie, M. Naguib, V.N. Mochalin, M.W. Barsoum, Y. Gogotsi, X. Yu, K.W. Nam, X.Q. Yang, A.I. Kolesnikov, and P.R. Kent Role of surface structure on Li-ion energy storage capacity of two-dimensional transition-metal carbides J. Am. Chem. Soc. 136 2014 6385 6394
70. Y. Dall'Agnese, M.R. Lukatskaya, K.M. Cook, P.-L. Taberna, Y. Gogotsi, and P. Simon High capacitance of surface-modified 2D titanium carbide in acidic electrolyte Electrochem. Commun. 48 2014 118 122
71. S.V. Didziulis, P. Frantz, S.S. Perry, O. El-bjeirami, S. Imaduddin, and P.B. Merrill Substrate-dependent reactivity of water on metal carbide surfaces J. Phys. Chem. B 103 1999 11129 11140