Flexible and conductive MXene films and nanocomposites with high capacitance

Proceedings of the National Academy of Sciences of the United States of America

Volumn 111, Issue 47, 2014, Pages 16676-16681

  Ling, Zheng ^a,b,c   Ren, Chang E ^a,b   Zhao, Meng Qiang ^a,b   Yang, Jian ^a,b,d   Giammarco, James M ^a,b   Qiu, Jieshan ^c   Barsoum, Michel W ^a,b   Gogotsi, Yury ^a,b  

^a Drexel University   (United States)

^b DREXEL UNIVERSITY   (United States)

^c State Key Laboratory of Fine Chemicals   (China)

^d NANJING TECH UNIVERSITY   (China)

Author keywords

2D material; Composite; Film; MXene; Supercapacitor

Indexed keywords

CARBIDE DERIVATIVE; NANOCOMPOSITE; NANOFILM; POLY(DIALLYLDIMETHYLAMMONIUM CHLORIDE); POLYVINYL ALCOHOL; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; COMPRESSIVE STRENGTH; ELECTRIC CAPACITANCE; ELECTRIC CONDUCTIVITY; INTERCALATION COMPLEX; NANOFABRICATION; TENSILE STRENGTH;

EID: 84912535342     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1414215111     Document Type: Article

References (44)

1. Norrish K (1954) The swelling of montmorillonite. Discuss Faraday Soc 18(0): 120-134.
2. Novoselov KS, et al. (2005) Two-dimensional atomic crystals. Proc Natl Acad Sci USA 102(30):10451-10453.
3. Nicolosi V, Chhowalla M, Kanatzidis MG, Strano MS, Coleman JN (2013) Liquid exfoliation of layered materials. Science 340(6139):1226419-1226437.
4. Ma R, Sasaki T (2010) Nanosheets of oxides and hydroxides: Ultimate 2D chargebearing functional crystallites. Adv Mater 22(45):5082-5104.
5. Li N, Chen Z, Ren W, Li F, Cheng H-M (2012) Flexible graphene-based lithium ion batteries with ultrafast charge and discharge rates. Proc Natl Acad Sci USA 109(43): 17360-17365.
6. Naguib M, et al. (2012) Two-dimensional transition metal carbides. ACS Nano 6(2):1322-1331.
7. Naguib M, et al. (2011) Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater 23(37):4248-4253.
8. Naguib M, et al. (2013) New two-dimensional niobium and vanadium carbides as promising materials for Li-ion batteries. J Am Chem Soc 135(43):15966-15969.
9. Barsoum MW (2013) MAX Phases: Properties of Machinable Ternary Carbides and Nitrides (Wiley, Weinheim, Germany).
10. Naguib M, Mochalin VN, Barsoum MW, Gogotsi Y (2014) 25th anniversary article: MXenes: A new family of two-dimensional materials. Adv Mater 26(7):992-1005.
11. Ghidiu M, et al. (2014) Synthesis and characterization of two-dimensional Nb4C3 (MXene). Chem Commun (Camb) 50(67):9517-9520.
12. Mashtalir O, et al. (2013) Intercalation and delamination of layered carbides and carbonitrides. Nat Commun 4:1716.
13. Naguib M, et al. (2012) MXene: A promising transition metal carbide anode for lithium-ion batteries. Electrochem Commun 16(1):61-64.
14. Lukatskaya MR, et al. (2013) Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science 341(6153):1502-1505.
15. Come J, et al. (2012) A non-aqueous asymmetric cell with a Ti2C-based twodimensional negative electrode. J Electrochem Soc 159(8):A1368-A1373.
16. Peng Q, et al. (2014) Unique lead adsorption behavior of activated hydroxyl group in two-dimensional titanium carbide. J Am Chem Soc 136(11):4113-4116.
17. Dikin DA, et al. (2007) Preparation and characterization of graphene oxide paper. Nature 448(7152):457-460.
18. Joshi RK, et al. (2014) Precise and ultrafast molecular sieving through graphene oxide membranes. Science 343(6172):752-754.
19. Li H, et al. (2013) Ultrathin, molecular-sieving graphene oxide membranes for selective hydrogen separation. Science 342(6154):95-98.
20. Nair RR, Wu HA, Jayaram PN, Grigorieva IV, Geim AK (2012) Unimpeded permeation of water through helium-leak-tight graphene-based membranes. Science 335(6067): 442-444.
21. Coleman JN, et al. (2011) Two-dimensional nanosheets produced by liquid exfoliation of layered materials. Science 331(6017):568-571.
22. Kurtoglu M, Naguib M, Gogotsi Y, Barsoum MW (2012) First principles study of twodimensional early transition metal carbides. MRS Communications 2(04):133-137.
23. Podsiadlo P, et al. (2007) Ultrastrong and stiff layered polymer nanocomposites. Science 318(5847):80-83.
24. Walther A, et al. (2010) Large-area, lightweight and thick biomimetic composites with superior material properties via fast, economic, and green pathways. Nano Lett 10(8): 2742-2748.
25. Walther A, et al. (2010) Supramolecular control of stiffness and strength in lightweight high-performance nacre-mimetic paper with fire-shielding properties. Angew Chem Int Ed Engl 49(36):6448-6453.
26. Wang J, Cheng Q, Lin L, Jiang L (2014) Synergistic toughening of bioinspired poly (vinyl alcohol)-clay-nanofibrillar cellulose artificial nacre. ACS Nano 8(3):2739-2745.
27. Yao H-B, Fang H-Y, Tan Z-H, Wu L-H, Yu S-H (2010) Biologically inspired, strong, transparent, and functional layered organic-inorganic hybrid films. Angew Chem Int Ed Engl 49(12):2140-2145.
28. Dou Y, et al. (2014) Transparent, flexible films based on layered double hydroxide/cellulose acetate with excellent oxygen barrier property. Adv Funct Mater 24(4):514-521.
29. Putz KW, Compton OC, Palmeri MJ, Nguyen ST, Brinson LC (2010) High-nanofillercontent graphene oxide-polymer nanocomposites via vacuum-assisted self-assembly. Adv Funct Mater 20(19):3322-3329.
30. Tian Y, Cao Y, Wang Y, Yang W, Feng J (2013) Realizing ultrahigh modulus and high strength of macroscopic graphene oxide papers through crosslinking of musselinspired polymers. Adv Mater 25(21):2980-2983.
31. Potts JR, Dreyer DR, Bielawski CW, Ruoff RS (2011) Graphene-based polymer nanocomposites. Polymer (Guildf) 52(1):5-25.
32. Zhang X, et al. (2013) Ultrathin nanosheets of MAX phases with enhanced thermal and mechanical properties in polymeric compositions: Ti3Si0.75Al0.25C2. Angew Chem Int Ed Engl 52(16):4361-4365.
33. Shi C, et al. (2014) Structure of nanocrystalline Ti3C2 MXene using atomic pair distribution function. Phys Rev Lett 112(12):125501.
34. Liu L, et al. (2013) High mechanical performance of layered graphene oxide/poly(vinyl alcohol) nanocomposite films. Small 9(14):2466-2472.
35. Lu X, Yu M, Wang G, Tong Y, Li Y (2014) Flexible solid-state supercapacitors: Design, fabrication and applications. Energy Environ Sci 7:2160-2181.
36. Chen H, Müller MB, Gilmore KJ, Wallace GG, Li D (2008) Mechanically strong, electrically conductive, and biocompatible graphene paper. Adv Mater 20(18):3557-3561.
37. Zhao M-Q, et al. (2014) Unstacked double-layer templated graphene for high-rate lithium-sulphur batteries. Nat Commun 5:3410.
38. Ng SH, et al. (2005) Single wall carbon nanotube paper as anode for lithium-ion battery. Electrochim Acta 51(1):23-28.
39. Halim J, et al. (2014) Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chem Mater 26(7):2374-2381.
40. Li Z, et al. (2012) Freestanding bucky paper with high strength from multi-wall carbon nanotubes. Mater Chem Phys 135(2-3):921-927.
41. Zhu Y, et al. (2011) Carbon-based supercapacitors produced by activation of graphene. Science 332(6037):1537-1541.
42. Heon M, et al. (2011) Continuous carbide-derived carbon films with high volumetric capacitance. Energy Environ Sci 4(1):135-138.
43. Yang X, Cheng C, Wang Y, Qiu L, Li D (2013) Liquid-mediated dense integration of graphene materials for compact capacitive energy storage. Science 341(6145): 534-537.
44. Lu X, et al. (2012) Stabilized TiN nanowire arrays for high-performance and flexible supercapacitors. Nano Lett 12(10):5376-5381.