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Volumn 22, Issue 3, 2016, Pages 890-895

Rhodium-Catalyzed Intramolecular C-H Bond Activation with Triazoles: Preparation of Stereodefined Pyrrolidines and Other Related Cyclic Compounds

Author keywords

C H activation; cyclization; heterocycles; rhodium; stereoselectivity

Indexed keywords

ACTIVATION ANALYSIS; CARBON DIOXIDE; CHEMICAL ACTIVATION; CYCLIZATION; RHODIUM; STEREOSELECTIVITY;

EID: 84954078848     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201503823     Document Type: Article
Times cited : (23)

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    • While the intermolecular C-H bond insertion to hydrocarbons as solvent has been reported (reference [4a]), to the best of our knowledge, an intramolecular insertion in a stereoselective manner as shown herein had not been reported before portions of this work were preliminary and orally presented at the 95th Annual Meeting of the Chemical Society of Japan held in Chiba, Japan, March 26-29, 2015; Abstr. 3E5-18 and 3E5-29. However, after almost completion of this study, the following report has appeared
    • While the intermolecular C-H bond insertion to hydrocarbons as solvent has been reported (reference [4a]), to the best of our knowledge, an intramolecular insertion in a stereoselective manner as shown herein had not been reported before portions of this work were preliminary and orally presented at the 95th Annual Meeting of the Chemical Society of Japan held in Chiba, Japan, March 26-29, 2015; Abstr. 3E5-18 and 3E5-29. However, after almost completion of this study, the following report has appeared:
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    • As sulfonylimines produced from triazoles have been routinely converted into sulfonylamines for isolation and characterization (see references [3]-[5] and [8a]), the isolation of the former as pure samples is not trivial.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.