Concise stereoselective synthesis of oxaspirocycles with 1-tosyl-1,2,3-triazoles: Application to the total syntheses of (±)-tuberostemospiroline and (±)-stemona-lactamr

Chemistry - A European Journal

Volumn 20, Issue 40, 2014, Pages 12881-12888

  Fu, Junkai ^a   Shen, Hongjuan ^a   Chang, Yuanyuan ^a   Li, Chuangchuang ^a   Gong, Jianxian ^a   Yang, Zhen ^a,b  

^a PEKING UNIVERSITY   (China)

^b Peking University   (China)

Author keywords

carbenes; oxaspirocycles; sigmatropic rearrangement; spiro compounds; total synthesis

Indexed keywords

NITROGEN; STEREOCHEMISTRY; STEREOSELECTIVITY;

CARBENES; OXASPIROCYCLES; SIGMATROPIC REARRANGEMENTS; SPIRO COMPOUNDS; TOTAL SYNTHESIS;

SYNTHESIS (CHEMICAL);

BIOLOGICAL PRODUCT; LACTAM; SPIRO COMPOUND; TRIAZOLE DERIVATIVE; TUBEROSTEMOSPIROLINE;

CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; STEMONACEAE; STEREOISOMERISM; SYNTHESIS;

BIOLOGICAL PRODUCTS; CYCLIZATION; LACTAMS; MODELS, MOLECULAR; SPIRO COMPOUNDS; STEMONACEAE; STEREOISOMERISM; TRIAZOLES;

EID: 84910008814     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201403756     Document Type: Article

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