메뉴 건너뛰기




Volumn , Issue , 2013, Pages 47-68

Electronic Transitions and Spin States in the Lower Mantle

Author keywords

[No Author keywords available]

Indexed keywords

IRON COMPOUNDS; MAGNETIC MOMENTS; PEROVSKITE; SILICATES; SPIN DYNAMICS;

EID: 84952937447     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1029/174GM06     Document Type: Chapter
Times cited : (6)

References (82)
  • 1
    • 0024568355 scopus 로고
    • Composition of the Earth
    • Anderson, D.L., Composition of the Earth, Science, 243, 367-370, 1989.
    • (1989) Science , vol.243 , pp. 367-370
    • Anderson, D.L.1
  • 2
    • 0035065907 scopus 로고    scopus 로고
    • Evaluation of (Mg,Fe) partitioning between silicate perovskite and magnesiowüstite up to 120 GPa and 2300 K
    • Andrault, D., Evaluation of (Mg,Fe) partitioning between silicate perovskite and magnesiowüstite up to 120 GPa and 2300 K, J. Geophys. Res., 106, 2079-2087, 2001.
    • (2001) J. Geophys. Res. , vol.106 , pp. 2079-2087
    • Andrault, D.1
  • 5
    • 3142674913 scopus 로고    scopus 로고
    • Electronic transitions in perovskite: Possible nonconvecting layers in the lower mantle
    • Badro, J., J.-P. Rueff, G. Vankó, G. Monaco, G. Fiquet, and F. Guyot, Electronic transitions in perovskite: Possible nonconvecting layers in the lower mantle, Science, 305, 383-386, 2004.
    • (2004) Science , vol.305 , pp. 383-386
    • Badro, J.1    Rueff, J.-P.2    Vankó, G.3    Monaco, G.4    Fiquet, G.5    Guyot, F.6
  • 6
    • 84951148874 scopus 로고    scopus 로고
    • Thermochemical state of the lower mantle: New insights from mineral physics
    • edited by R.D. van der Hilst, et al., American Geophysical Union, Washington DC
    • Badro, J., G. Fiquet, and F. Guyot, Thermochemical state of the lower mantle: New insights from mineral physics, in Earth's Deep Mantle: Structure, Composition, and Evolution, edited by R.D. van der Hilst, et al., pp. 241- 260 American Geophysical Union, Washington DC, 2005.
    • (2005) Earth's Deep Mantle: Structure, Composition, and Evolution , pp. 241- 260
    • Badro, J.1    Fiquet, G.2    Guyot, F.3
  • 7
    • 0141503200 scopus 로고
    • Applications of the Mössbauer effect to silicate mineralogy-I. Iron silicates of known crystal structure
    • Bancroft, G.M., A.G. Maddock, and R.G. Burns, Applications of the Mössbauer effect to silicate mineralogy-I. Iron silicates of known crystal structure, Geochim. Cosmochim. Acta, 31, 2219-2246, 1967.
    • (1967) Geochim. Cosmochim. Acta , vol.31 , pp. 2219-2246
    • Bancroft, G.M.1    Maddock, A.G.2    Burns, R.G.3
  • 8
    • 0007418090 scopus 로고
    • Halsted Press, John Wiley and Sons, Inc., New York
    • Bancroft, G.M., Mössbauer spectroscopy, 252 pp., Halsted Press, John Wiley and Sons, Inc., New York, 1973.
    • (1973) Mössbauer spectroscopy , pp. 252
    • Bancroft, G.M.1
  • 9
    • 0019663639 scopus 로고
    • Thermodynamic parameters in the Earth as determined from seismic profiles
    • Brown J.M., and T.J. Shankland, Thermodynamic parameters in the Earth as determined from seismic profiles. Geophys. J.R. Astron. Soc. 66, 579-596, 1981.
    • (1981) Geophys. J.R. Astron. Soc. , vol.66 , pp. 579-596
    • Brown, J.M.1    Shankland, T.J.2
  • 10
    • 0002890378 scopus 로고
    • 57Fe-bearing oxide, silicate, and aluminosilicate minerals
    • edited by L.M. Coyne, et al., American Chemical Society, Washington DC
    • Burns, R.G., and T.C. Solberg, 57Fe-bearing oxide, silicate, and aluminosilicate minerals, in Spectroscopic characterization of minerals and their surfaces, edited by L.M. Coyne, et al., pp. 262-283, American Chemical Society, Washington DC, 1990.
    • (1990) Spectroscopic characterization of minerals and their surfaces , pp. 262-283
    • Burns, R.G.1    Solberg, T.C.2
  • 11
    • 0005481864 scopus 로고
    • Mixed valency minerals: Influences of crystal structures on optical and Mössbauer spectra
    • edited by K. Prassides, Plenum, New York
    • Burns, R.G., Mixed valency minerals: Influences of crystal structures on optical and Mössbauer spectra, in Mixed Valence Systems: Applications in chemistry, physics, and biology, edited by K. Prassides, pp. 175-200, Plenum, New York, 1991.
    • (1991) Mixed Valence Systems: Applications in chemistry, physics, and biology , pp. 175-200
    • Burns, R.G.1
  • 13
    • 0037167838 scopus 로고    scopus 로고
    • 3 perovskite at high pressure and temperature
    • 3 perovskite at high pressure and temperature, Nature, 419, 824-826, 2002.
    • (2002) Nature , vol.419 , pp. 824-826
    • Chen, J.1    Weidner, D.J.2    Vaughan, M.T.3
  • 14
    • 0038110231 scopus 로고
    • Radiative transfer in the Earth's mantle
    • Clark, S.J., Radiative transfer in the Earth's mantle, Trans. AGU, 38, 931-938, 1957.
    • (1957) Trans. AGU , vol.38 , pp. 931-938
    • Clark, S.J.1
  • 15
    • 0030621135 scopus 로고    scopus 로고
    • Magnetic Collapse in transition metal oxides at high pressure: implication for the Earth
    • Cohen, R.E., I.I. Mazin, and D.G. Isaak, Magnetic Collapse in transition metal oxides at high pressure: implication for the Earth, Science, 275, 654-657, 1997.
    • (1997) Science , vol.275 , pp. 654-657
    • Cohen, R.E.1    Mazin, I.I.2    Isaak, D.G.3
  • 16
    • 0026082414 scopus 로고
    • Experimental determination of element partitioning and calculation of phase relations in the MgO-FeO-SiO2 system at high pressure and high temperature
    • Fei, Y., H.K. Mao, and B.O. Mysen, Experimental determination of element partitioning and calculation of phase relations in the MgO-FeO-SiO2 system at high pressure and high temperature, J. Geophys. Res., 96, 2157-2169, 1991.
    • (1991) J. Geophys. Res. , vol.96 , pp. 2157-2169
    • Fei, Y.1    Mao, H.K.2    Mysen, B.O.3
  • 19
    • 0036079149 scopus 로고    scopus 로고
    • 3 on Fe-Mg partitioning between magnesiowüstite and magnesium silicate perovskite
    • 3 on Fe-Mg partitioning between magnesiowüstite and magnesium silicate perovskite, Earth Planet. Sci. Lett., 199, 227-241, 2002.
    • (2002) Earth Planet. Sci. Lett. , vol.199 , pp. 227-241
    • Frost, D.J.1    Langenhorst, F.2
  • 20
    • 2442509703 scopus 로고    scopus 로고
    • Approach to the mineralogy of the lower mantle by a combined method of a laser-heated diamond anvil cell experiment and analytical electron microscopy
    • 215-221
    • Fujino, K., Y. Sasaki, T. Komori, H. Ogawa, N. Miyajima, N. Sata, and T. Yagi, Approach to the mineralogy of the lower mantle by a combined method of a laser-heated diamond anvil cell experiment and analytical electron microscopy, Phys. Earth Planet. Int., 143-144, 215-221, 2004.
    • (2004) Phys. Earth Planet. Int. , pp. 143-144
    • Fujino, K.1    Sasaki, Y.2    Komori, T.3    Ogawa, H.4    Miyajima, N.5    Sata, N.6    Yagi, T.7
  • 21
    • 0033794111 scopus 로고    scopus 로고
    • Heterogeneity of the lowermost mantle
    • Garnero, E.J., Heterogeneity of the lowermost mantle, Annu. Rev. Earth Planet. Sci., 28, 509-537, 2000.
    • (2000) Annu. Rev. Earth Planet. Sci. , vol.28 , pp. 509-537
    • Garnero, E.J.1
  • 22
    • 33744502089 scopus 로고    scopus 로고
    • Reduced radiative conductivity of low-spin (Mg, Fe)O in the lower mantle
    • Goncharov A.F., V.V., Struzhkin, and S.D., Jacobsen, Reduced radiative conductivity of low-spin (Mg, Fe)O in the lower mantle. Science 312, 1205-1208, 2006.
    • (2006) Science , vol.312 , pp. 1205-1208
    • Goncharov, A.F.1    Struzhkin, V.V.2    Jacobsen, S.D.3
  • 23
    • 0019214352 scopus 로고
    • Absorption spectrum of shock-compressed Fe2 -bearing MgO and the radiative conductivity of the lower mantle
    • Goto, T., T.J. Ahrens, G.R. Rossman, and Y. Syono, Absorption spectrum of shock-compressed Fe2 -bearing MgO and the radiative conductivity of the lower mantle, Phys. Earth Planet. Int., 22, 277-288, 1980.
    • (1980) Phys. Earth Planet. Int. , vol.22 , pp. 277-288
    • Goto, T.1    Ahrens, T.J.2    Rossman, G.R.3    Syono, Y.4
  • 25
    • 33344478426 scopus 로고    scopus 로고
    • Is low-spin Fe2 present in Earth's mantle?
    • Hofmeister, A.M., Is low-spin Fe2 present in Earth's mantle?, Earth Planet. Sci. Lett., 243, 44-52, 2006.
    • (2006) Earth Planet. Sci. Lett. , vol.243 , pp. 44-52
    • Hofmeister, A.M.1
  • 28
    • 36149012645 scopus 로고
    • Electric-field gradient tensor in ferrous compounds
    • Ingalls, R., Electric-field gradient tensor in ferrous compounds, Phys. Rev., 133, A787-A795, 1964.
    • (1964) Phys. Rev. , vol.133 , pp. A787-A795
    • Ingalls, R.1
  • 30
    • 0036117063 scopus 로고    scopus 로고
    • Structure and elasticity of single-crystal (Mg,Fe)O and a new method of generating shear waves for gigahertz ultrasonic interferometry
    • Jacobsen, S.D., H.-J. Reichmann, H.A. Spetzler, S.J. Mackwell, J.R. Smyth, R.J. Angel, and C.A. McCammon, Structure and elasticity of single-crystal (Mg,Fe)O and a new method of generating shear waves for gigahertz ultrasonic interferometry, J. Geophys. Res., 107, 2037-2051, doi: 2010.1029/2001JB000490, 2002.
    • (2002) J. Geophys. Res. , vol.107 , pp. 2037-2051
    • Jacobsen, S.D.1    Reichmann, H.-J.2    Spetzler, H.A.3    Mackwell, S.J.4    Smyth, J.R.5    Angel, R.J.6    McCammon, C.A.7
  • 32
    • 33645462710 scopus 로고    scopus 로고
    • Spin crossover in (Mg,Fe)O: A Mössbauer effect study with an alternative interpretation of x-ray emission spectroscopy data
    • R
    • Kantor, I.Y., L.S. Dubrovinsky. and C.A. McCammon, Spin crossover in (Mg,Fe)O: A Mössbauer effect study with an alternative interpretation of x-ray emission spectroscopy data. Phys. Rev. B 73, 100101(R), 2006.
    • (2006) Phys. Rev. B , vol.73 , pp. 100101
    • Kantor, I.Y.1    Dubrovinsky, L.S.2    McCammon, C.A.3
  • 33
    • 0035171184 scopus 로고    scopus 로고
    • Origin of lateral variation of seismic wave velocities and density in the deep mantle
    • Karato, S.-i., and B.B. Karki, Origin of lateral variation of seismic wave velocities and density in the deep mantle, J. Geophys. Res., 106, 21,771-721,783, 2001.
    • (2001) J. Geophys. Res. , vol.106
    • Karato, S.-I.1    Karki, B.B.2
  • 34
    • 0033583061 scopus 로고    scopus 로고
    • Compositional stratification in the deep mantle
    • Kellogg, L.H., B.H. Hager, and R.D. v. d. Hilst, Compositional stratification in the deep mantle, Science, 283, 1881-1884, 1999.
    • (1999) Science , vol.283 , pp. 1881-1884
    • Kellogg, L.H.1    Hager, B.H.2    Hilst, R.D.V.D.3
  • 36
    • 7144223397 scopus 로고    scopus 로고
    • Mineralogy and dynamics of a pyrolite lower mantle
    • Kesson, S.E., J.D. Fitz Gerald, and J.M. Shelley, Mineralogy and dynamics of a pyrolite lower mantle. Nature 393, 252-255, 1998.
    • (1998) Nature , vol.393 , pp. 252-255
    • Kesson, S.E.1    Fitz Gerald, J.D.2    Shelley, J.M.3
  • 37
    • 0037200278 scopus 로고    scopus 로고
    • Partitioning of iron between magnesian silicate perovskite and magnesiowüstite at about 1 Mbar
    • Kesson, S.E., J.D.F. Gerald, H.S.C. O'Neill, and J.M.G. Shelley, Partitioning of iron between magnesian silicate perovskite and magnesiowüstite at about 1 Mbar, Phys. Earth Planet. Int., 131, 295-310, 2002.
    • (2002) Phys. Earth Planet. Int. , vol.131 , pp. 295-310
    • Kesson, S.E.1    Gerald, J.D.F.2    O'Neill, H.S.C.3    Shelley, J.M.G.4
  • 38
    • 0000839233 scopus 로고
    • High-pressure phase transitions in FeS, using 57Fe Mössbauer spectroscopy
    • King, H., D. Virgo, and H.K. Mao, High-pressure phase transitions in FeS, using 57Fe Mössbauer spectroscopy, Carnegie Inst. Yb., 77, 830-834, 1978.
    • (1978) Carnegie Inst. Yb. , vol.77 , pp. 830-834
    • King, H.1    Virgo, D.2    Mao, H.K.3
  • 40
    • 0032473957 scopus 로고    scopus 로고
    • The core-mantle boundary layer and deep Earth dynamics
    • Lay, T., Q. Williams, and E.J. Garnero, The core-mantle boundary layer and deep Earth dynamics, Nature, 392, 461-468, 1998.
    • (1998) Nature , vol.392 , pp. 461-468
    • Lay, T.1    Williams, Q.2    Garnero, E.J.3
  • 46
    • 84987566200 scopus 로고
    • Silicate perovskite from phase transformations of pyrope-garnet at high-pressure and high-temperature
    • Liu, L.-G., Silicate perovskite from phase transformations of pyrope-garnet at high-pressure and high-temperature, Geophys. Res. Lett., 1, 277-280, 1974.
    • (1974) Geophys. Res. Lett. , vol.1 , pp. 277-280
    • Liu, L.-G.1
  • 47
    • 0031472011 scopus 로고    scopus 로고
    • Multivariable dependence of Fe-Mg partitioning in the lower mantle
    • Mao, H.K., G. Shen, and R.J. Hemley, Multivariable dependence of Fe-Mg partitioning in the lower mantle, Science, 278, 2098-2100, 1997.
    • (1997) Science , vol.278 , pp. 2098-2100
    • Mao, H.K.1    Shen, G.2    Hemley, R.J.3
  • 50
    • 85012960969 scopus 로고    scopus 로고
    • The relative behavior of shear velocity, bulk sound speed, and compressional velocity in the mantle: Implications for chemical and thermal structure
    • edited, American Geophysical Union, Washington DC
    • Masters, G., G. Laske, H. Bolton, and A. Dziewonski, The relative behavior of shear velocity, bulk sound speed, and compressional velocity in the mantle: Implications for chemical and thermal structure, in Earth's Deep Interior: Mineral Physics and Tomography from the Atomic to the Global Scale, edited, pp. 63-87, American Geophysical Union, Washington DC, 2000.
    • (2000) Earth's Deep Interior: Mineral Physics and Tomography from the Atomic to the Global Scale , pp. 63-87
    • Masters, G.1    Laske, G.2    Bolton, H.3    Dziewonski, A.4
  • 52
    • 0030617679 scopus 로고    scopus 로고
    • Perovskite as a possible sink for ferric iron in the lower mantle
    • McCammon, C., Perovskite as a possible sink for ferric iron in the lower mantle, Nature, 387, 694-696, 1997.
    • (1997) Nature , vol.387 , pp. 694-696
    • McCammon, C.1
  • 53
    • 0031929134 scopus 로고    scopus 로고
    • 3 perovskite as determined by Mössbauer spectroscopy in the temperature range 80-293 K
    • 3 perovskite as determined by Mössbauer spectroscopy in the temperature range 80-293 K, Phys. Chem. Minerals, 25, 292-300, 1998.
    • (1998) Phys. Chem. Minerals , vol.25 , pp. 292-300
    • McCammon, C.A.1
  • 56
    • 17744386140 scopus 로고    scopus 로고
    • Post-perovskite phsae transition and mineral chemistry in the pyrolitic lowermost mantle
    • Murakami, M., K. Hirose, N. Sata, and Y. Ohishi, Post-perovskite phsae transition and mineral chemistry in the pyrolitic lowermost mantle, Geophys. Res. Lett., 32, L03304, doi: 03310.01029/02004GL021956, 2005.
    • (2005) Geophys. Res. Lett. , vol.32 , pp. L03304
    • Murakami, M.1    Hirose, K.2    Sata, N.3    Ohishi, Y.4
  • 57
    • 34047117763 scopus 로고    scopus 로고
    • Effect of incorporation of iron and aluminum on the thermoelastic properties of magnesium silicate perovskite
    • Nishiyama N., T. Yagi, S. Ono, H. Gotou, T. Harada, and T. Kikegawa, Effect of incorporation of iron and aluminum on the thermoelastic properties of magnesium silicate perovskite. Phys Chem Minerals 34, 131-143, doi 10.1007/s00269-006-0134-6, 2007.
    • (2007) Phys Chem Minerals , vol.34 , pp. 131-143
    • Nishiyama, N.1    Yagi, T.2    Ono, S.3    Gotou, H.4    Harada, T.5    Kikegawa, T.6
  • 58
  • 60
    • 0000815048 scopus 로고
    • Spin selective x-ray absorption spectroscopy: Demonstration using high resolution Fe K? fluorescence
    • Peng, G., X. Wang, C.R. Randall, J.A. Moore, and S.P. Cramer, Spin selective x-ray absorption spectroscopy: Demonstration using high resolution Fe K? fluorescence, Appl. Phys. Lett, 65, 2527-2529, 1994.
    • (1994) Appl. Phys. Lett , vol.65 , pp. 2527-2529
    • Peng, G.1    Wang, X.2    Randall, C.R.3    Moore, J.A.4    Cramer, S.P.5
  • 61
    • 33845667308 scopus 로고    scopus 로고
    • Ab initio study of the composition dependence of the pressure-induced spin transition in the (Mg1-x,Fex)O system
    • Persson, K., A. Bengtson, G. Ceder, and D. Morgan, Ab initio study of the composition dependence of the pressure-induced spin transition in the (Mg1-x,Fex)O system, Geophys. Res. Lett., 33, doi:10.1029/2006GL026621, 2006.
    • (2006) Geophys. Res. Lett. , pp. 33
    • Persson, K.1    Bengtson, A.2    Ceder, G.3    Morgan, D.4
  • 62
    • 0032469643 scopus 로고    scopus 로고
    • Calculated role of aluminum in the incorporation of ferric iron into magnesium silicate perovskite
    • Richmond, N.C., and J.P. Brodholt, Calculated role of aluminum in the incorporation of ferric iron into magnesium silicate perovskite, Am. Mineral., 83, 947-951, 1998.
    • (1998) Am. Mineral. , vol.83 , pp. 947-951
    • Richmond, N.C.1    Brodholt, J.P.2
  • 63
    • 0141680875 scopus 로고    scopus 로고
    • Global mantle tomography: Progress status in the past 10 years
    • Romanowicz, B., Global mantle tomography: Progress status in the past 10 years, Annu. Rev. Earth Planet. Sci., 31, 303-328, 2003.
    • (2003) Annu. Rev. Earth Planet. Sci. , vol.31 , pp. 303-328
    • Romanowicz, B.1
  • 64
    • 0001470103 scopus 로고    scopus 로고
    • Pressure-induced high-spin to low-spin transition in FeS evidenced by X-ray emission spectroscopy
    • Rueff, J.P., and C.C. Kao, Pressure-induced high-spin to low-spin transition in FeS evidenced by X-ray emission spectroscopy, Phys. Rev. Lett., 82, 3284-3287, 1999.
    • (1999) Phys. Rev. Lett. , vol.82 , pp. 3284-3287
    • Rueff, J.P.1    Kao, C.C.2
  • 66
    • 0000695192 scopus 로고
    • High-spin to low-spin transition of iron(II) oxides at high pressures: Possible effects on the physics and chemistry of the lower mantle
    • edited by S. Ghose, et al., Springer-Verlag, New York
    • Sherman, D.M., High-spin to low-spin transition of iron(II) oxides at high pressures: Possible effects on the physics and chemistry of the lower mantle, in Structural and Magnetic Phase Transitions in Minerals, edited by S. Ghose, et al., pp. 113-128, Springer-Verlag, New York, 1988.
    • (1988) Structural and Magnetic Phase Transitions in Minerals , pp. 113-128
    • Sherman, D.M.1
  • 67
    • 0028811766 scopus 로고
    • First-principles prediction of the highpressure phase transition and electronic structure of FeO: Implications for the chemistry of the lower mantle and core
    • Sherman, D.M., and H.J.F. Jansen, First-principles prediction of the highpressure phase transition and electronic structure of FeO: Implications for the chemistry of the lower mantle and core, Geophys. Res. Lett., 22, 1001-1004, 1995.
    • (1995) Geophys. Res. Lett. , vol.22 , pp. 1001-1004
    • Sherman, D.M.1    Jansen, H.J.F.2
  • 72
    • 0034454505 scopus 로고    scopus 로고
    • CONUSS and PHOENIX: Evaluation of nuclear resonant scattering data
    • Sturhahn, W., CONUSS and PHOENIX: Evaluation of nuclear resonant scattering data, Hyperfine Int., 125, 149-172, 2000.
    • (2000) Hyperfine Int. , vol.125 , pp. 149-172
    • Sturhahn, W.1
  • 73
    • 25844433662 scopus 로고    scopus 로고
    • The spin state of iron in minerals of Earth's lower mantle
    • Sturhahn, W., J.M. Jackson, and J.-F. Lin, The spin state of iron in minerals of Earth's lower mantle, Geophys. Res. Lett., 32, doi:10.1029/2005GL022802, 2005.
    • (2005) Geophys. Res. Lett. , pp. 32
    • Sturhahn, W.1    Jackson, J.M.2    Lin, J.-F.3
  • 75
    • 84951123166 scopus 로고    scopus 로고
    • Towards a quantitative interpretation of global seismic tomography
    • edited by R.D. van der Hilst, et al., American Geophysical Union, Washington DC
    • Trampert, J., and R.D. van der Hilst, Towards a quantitative interpretation of global seismic tomography, in Earth's Deep Mantle: Structure, Composition, and Evolution, edited by R.D. van der Hilst, et al., pp. 47-62, American Geophysical Union, Washington DC, 2005.
    • (2005) Earth's Deep Mantle: Structure, Composition, and Evolution , pp. 47-62
    • Trampert, J.1    van der Hilst, R.D.2
  • 77
    • 35949042439 scopus 로고
    • X-ray Mn Kb emission spectra of manganese oxides and manganates
    • Tsutsumi, K., H. Nakamori, and K. Ichikawa, X-ray Mn Kb emission spectra of manganese oxides and manganates, Phys. Rev., 13, 929-933, 1976.
    • (1976) Phys. Rev. , vol.13 , pp. 929-933
    • Tsutsumi, K.1    Nakamori, H.2    Ichikawa, K.3
  • 81
    • 0029783650 scopus 로고    scopus 로고
    • The effect of alumina on phase transformations at the 660-kilometer discontinuity from Fe-Mg partitioning experiments
    • Wood, B.J., and D.C. Rubie, The effect of alumina on phase transformations at the 660-kilometer discontinuity from Fe-Mg partitioning experiments, Science, 273, 1522-1524, 1996.
    • (1996) Science , vol.273 , pp. 1522-1524
    • Wood, B.J.1    Rubie, D.C.2
  • 82


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.