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2 laser (90% TEM00) was used for heating. The small sample thickness and the effective thermal insulation of the sample from the diamond by the argon pressure medium allowed defocusing of the laser beam to reach high temperatures with small axial and radial gradients. Large portions of the samples were thus converted to high-pressure minerals from the glass starting material without scanning the laser beam. Thermal radiation spectra were recorded from areas 2 to 3 μm in diameter with a charge-coupled device detector in the wavelength range 500 to 815 nm, and Planck's radiation function was fitted to the spectra. The emissivity of the sample was taken to be independent of wavelength. The temperature uncertainty based on this assumption is about ±150 K (2). The temperatures reported in this work are maximum temperatures in the center of the laser-heated spot.
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Backscattering electron (topographic) images were made with the SEM unit of JEOL JXA 8900 RL. For quantitative measurements of the sample topography, we used an AFM (Explorer, Topo Metrix) operated in the contact mode [R. Wiesendanger and H.-J. Güntherodt, Eds., Scanning Tunneling Spectroscopy II and III; Springer Series in Surface Sciences (Springer-Verlag, Berlin, ed. 2, 1995 and 1996)], vols. 28 and 29.
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2642660741
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We thank V. Hillgren, B. Schulz-Dobrick, and G. Serghiou for helpful discussions and V. Hillgren, G. Serghiou, and the reviewers for constructive comments on the manuscript.
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