The crystal chemistry of ferric iron in Fe0.05Mg0.95SiO3 perovskite as determined by Mössbauer spectroscopy in the temperature range 80-293 K

Physics and Chemistry of Minerals

Volumn 25, Issue 4, 1998, Pages 292-300

  McCammon, C A ^a  

^a UNIVERSITÄT BAYREUTH   (Germany)

Author keywords

Electron delocalisation; Ferric iron; M ssbauer spectroscopy; Perovskite structure

Indexed keywords

CRYSTAL CHEMISTRY; IRON; MOSSBAUER SPECTROSCOPY; PEROVSKITE;

EID: 0031929134     PISSN: 03421791     EISSN: None     Source Type: Journal    
DOI: 10.1007/s002690050117     Document Type: Article

References (34)

1. 57Fe in silicate garnets. Z Kristallogr 143:14-55
2. Bancroft GM, Burns RG, Stone AJ (1968) Applications of the Mössbauer effect to silicate mineralogy - II. Iron silicates of unknown and complex crystal structures. Geochim Cosmochim Acta 32:547-559
3. Bevington PR (1969) Data reduction and error analysis for the physical sciences. McGraw-Hill, New York
4. Birch WD, Pring A, Reller A, Schmalle H (1992) Bernalite: a new ferric hydroxide with perovskite structure. Naturwiss 79:509-511
5. 3, a new mineral from Broken Hill, New South Wales: Description and structure. Am Mineral 78:827-834
6. Burns RG (1993) Mineralogical applications of crystal field theory, 2nd edn. Cambridge University Press, Cambridge, UK
7. 57Fe-bearing oxide, silicate, and aluminosilicate minerals. In: Coyne LM. McKeever SWS, Blake DF (eds) Spectroscopic characterization of minerals and their surfaces, Vol 415. American Chemical Society, Washinaton DC, pp 262-283
8. De Grave E, Van Alboom A (1991) Evaluation of ferrous and ferric Mössbauer fractions. Phys Chem Minerals 18:337-342
9. 3 perovskite. Am Mineral 79:826-837
10. Gibb TC (1968) Estimation of ligand-field parameters from Mössbauer spectra. J Chem Soc A: 1439-1444
11. Heberle J (1971) The Debye integrals. the thermal shift and the Mössbauer fraction. In: Gruverman IJ (ed) Mössbauer effect methodology, Vol 7. Plenum, New York, pp 299-308
12. Herber RH (1984) Structure, bonding, and the Mössbauer lattice temperature. In: Herber RH (ed) Chemical Mössbauer spectroscopy. Plenum, New York. pp 199-216
13. 3: single-crystal X-ray diffraction study. Am Mineral 72:357-360
14. Ingalls R (1964) Electric-field gradient tensor in ferrous compounds. Phys Rev 133:A787-A795
15. 3 perovskite. Am Mineral 79:1215-1218
16. Kesson SE. Fitz Gerald JD, Shelley JMG. Withers RL (1995) Phase relations, structure and crystal chemistry of some aluminous silicate perovskites. Earth Planet Sci Lett 134:187-201
17. Kolk B (1984) Studies of dynamical properties of solids with the Mössbauer effect. In: Horton GK, Maradudin AA (eds) Dynamical properties of solids, Vol 5. North Holland, Amsterdam, pp 3-328
18. 3 perovskite. Geophys Res Lett 17:1481-1484
19. 3+ ions on octahedral sites in spinels studied by means of paramagnetic Mössbauer spectra and susceptibility measurements. J Phys Chem Solids 38:565-572
20. 3 perovskite at 80 and 298 K. Am Mineral 77:894-897
21. 3, using Mössbauer spectroscopy, optical spectroscopy and transmission electron microscopy. Phys Chem Minerals 22:11-20
22. 187. Z Phys 159:33-48
23. O'Neill HSC, Rubie DC, Canil D, Geiger CA, Ross II CR, Seifert F, Woodland AB (1993a) Ferric iron in the upper mantle and in transition zone assemblages: implications for relative oxygen fugacities in the mantle. In: Takahashi T, Jeanloz R, Rubie DC (ed) Evolution of the earth and planets. American Geophysical Union, Washington D C., pp 73-88
24. O'Neill HSC. McCammon CA, Canil DC, Rubie DC, Ross II CR, Seifert F (1993b) Mössbauer spectroscopy of transition zone phases and determination of minimum Fe content. Am Mineral 78:456-460
25. Poirier JP, Peyronneau J (1992) Experimental determination of the electrical conductivity of the material of the Earth's lower mantle. In: Syono Y. Manghnani MH (eds) High-pressure research: application to earth and planetary sciences. Terra Scientific Publishing Company/American Geophysical Union, Tokyo/Washington DC, pp 77-87
26. Pound RV, Rebka GA Jr (1960) Variation with temperature of the energy of recoil-free gamma rays from solids. Phys Rev Lett 4:274-277
27. 2 oxygen buffer from EMF and NiO + Ni-Pd redox sensor measurements. Contrib Mineral Petrol 118:130-137
28. Rancourt DG (1989) Accurate site populations from Mössbauer spectroscopy. Nucl Instr Meth Phys Res B44:199-210
29. Rancourt DG, Ping JY (1991) Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mössbauer spectroscopy. Nucl Instr Meth Phys Res B58:85-97
30. Rancourt DG, McDonald AM, Lalonde AE, Ping JY (1993) Mössbauer absorber thicknesses for accurate site populations in Febearing minerals. Am Mineral 78:1-7
31. 2+ site populations in synthetic annite by Mössbauer spectroscopy. Am Mineral 79:51-62
32. Skogby H, Annersten H, Domeneghetti MC, Molin GM, Tazzoli V (1992) Iron distribution in orthopyroxene: A comparison of Mössbauer spectroscopy and x-ray refinement results. Eur J Mineral 4:441-452
33. 57Fe Mössbauer Spectroscopy. Phys Chem Minerals 20:263-275
34. 12 (andradite-"skiagite") garnet solid solutions. Phys Chem Minerals 21:117-132