Capacitive Energy Storage: Current and Future Challenges

Journal of Physical Chemistry Letters

Volumn 6, Issue 18, 2015, Pages 3594-3609

  Vatamanu, Jenel ^a   Bedrov, Dmitry ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRODES; ENERGY STORAGE; MOLECULES;

CAPACITIVE ENERGY STORAGE; CHARGED SURFACES; ELECTRIC DOUBLE LAYER; ENERGY APPLICATIONS; FUTURE CHALLENGES; NANOPOROUS ELECTRODE; POROUS ELECTRODES; THEORETICAL RESEARCH;

ELECTROLYTIC CAPACITORS;

EID: 84942017248     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/acs.jpclett.5b01199     Document Type: Article

References (221)

1. Fedorov, M. V.; Kornyshev, A. A. Ionic Liquids at Electrified Interfaces Chem. Rev. 2014, 114, 2978-3036 10.1021/cr400374x
2. Hayes, R.; Warr, G. G.; Atkin, R. Structure and Nanostructure in Ionic Liquids Chem. Rev. 2015, 115, 6357 10.1021/cr500411q
3. Zhang, Y.-Z.; Wang, Y.; Cheng, T.; Lai, W.-Y.; Pang, H.; Huang, W. Flexible Supercapacitors Based on Paper Substrates: A New Paradigm for Low-Cost Energy Storage Chem. Soc. Rev. 2015, 44, 5181 10.1039/C5CS00174A
4. Simon, P.; Gogotsi, Y. Materials for Electrochemical Capacitors Nat. Mater. 2008, 7, 845-854 10.1038/nmat2297
5. Simon, P.; Gogotsi, Y. Capacitive Energy Storage in Nanostructured Carbon-Electrolyte Systems Acc. Chem. Res. 2013, 46, 1094-1103 10.1021/ar200306b
6. Tasis, D.; Tagmatarchis, N.; Bianco, A.; Prato, M. Chemistry of Carbon Nanotubes Chem. Rev. 2006, 106, 1105-1136 10.1021/cr050569o
7. Georgakilas, V.; Otyepka, M.; Bourlinos, A. B.; Chandra, V.; Kim, N.; Kemp, K. C.; Hobza, P.; Zboril, R.; Kim, K. S. Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications Chem. Rev. 2012, 112, 6156-6214 10.1021/cr3000412
8. Boukhvalov, D. W.; Katsnelson, M. I. Chemical Functionalization of Graphene J. Phys.: Condens. Matter 2009, 21, 344205 10.1088/0953-8984/21/34/344205
9. Merlet, C.; Rotenberg, B.; Madden, P. A.; Salanne, M. Computer Simulations of Ionic Liquids at Electrochemical Interfaces Phys. Chem. Chem. Phys. 2013, 15, 15781-15792 10.1039/c3cp52088a
10. Hughes, Z. E.; Walsh, T. R. Computational Chemistry for Graphene-Based Energy Applications: Progress and Challenges Nanoscale 2015, 7, 6883-6908 10.1039/C5NR00690B
11. Jiang, D.-e.; Meng, D.; Wu, J. Density Functional Theory for Differential Capacitance of Planar Electric Double Layers in Ionic Liquids Chem. Phys. Lett. 2011, 504, 153-158 10.1016/j.cplett.2011.01.072
12. Li, Z.; Wu, J. Density Functional Theory for Planar Electric Double Layers: Closing the Gap between Simple and Polyelectrolytes J. Phys. Chem. B 2006, 110, 7473-7484 10.1021/jp060127w
13. Henderson, D.; Lamperski, S.; Jin, Z.; Wu, J. Density Functional Study of the Electric Double Layer Formed by a High Density Electrolyte J. Phys. Chem. B 2011, 115, 12911-12914 10.1021/jp2078105
14. Ma, K.; Forsman, J.; Woodward, C. E. Influence of Ion Pairing in Ionic Liquids on Electrical Double Layer Structures and Surface Force Using Classical Density Functional Approach J. Chem. Phys. 2015, 142, 174704 10.1063/1.4919314
15. Forsman, J.; Woodward, C. E.; Trulsson, M. A Classical Density Functional Theory of Ionic Liquids J. Phys. Chem. B 2011, 115, 4606-4612 10.1021/jp111747w
16. Siepmann, J. I.; Sprik, M. Influence of Surface Topology and Electrostatic Potential on Water/Electrode Systems J. Chem. Phys. 1995, 102, 511-524 10.1063/1.469429
17. Reed, S. K.; Lanning, O. J.; Madden, P. A. Electrochemical Interface between an Ionic Liquid and a Model Metallic Electrode J. Chem. Phys. 2007, 126, 084704 10.1063/1.2464084
18. Pastewka, L.; Järvi, T. T.; Mayrhofer, L.; Moseler, M. Charge-Transfer Model for Carbonaceous Electrodes in Polar Environments Phys. Rev. B: Condens. Matter Mater. Phys. 2011, 83, 165418 10.1103/PhysRevB.83.165418
19. Wang, Z.; Yang, Y.; Olmsted, D. L.; Asta, M.; Laird, B. B. Evaluation of the Constant Potential Method in Simulating Electric Double-Layer Capacitors J. Chem. Phys. 2014, 141, 184102 10.1063/1.4899176
20. Merlet, C.; Péan, C.; Rotenberg, B.; Madden, P. A.; Simon, P.; Salanne, M. Simulating Supercapacitors: Can We Model Electrodes as Constant Charge Surfaces? J. Phys. Chem. Lett. 2013, 4, 264-268 10.1021/jz3019226
21. Merlet, C.; Limmer, D. T.; Salanne, M.; van Roij, R.; Madden, P. A.; Chandler, D.; Rotenberg, B. The Electric Double Layer Has a Life of Its Own J. Phys. Chem. C 2014, 118, 18291-18298 10.1021/jp503224w
22. Kondrat, S.; Kornyshev, A. Superionic State in Double-Layer Capacitors with Nanoporous Electrodes J. Phys.: Condens. Matter 2011, 23, 022201 10.1088/0953-8984/23/2/022201
23. Vatamanu, J.; Borodin, O.; Smith, G. D. Molecular Dynamics Simulations of Atomically Flat and Nanoporous Electrodes with a Molten Salt Electrolyte Phys. Chem. Chem. Phys. 2010, 12, 170-182 10.1039/B917592J
24. Kiss, P. T.; Sega, M.; Baranyai, A. Efficient Handling of Gaussian Charge Distributions: An Application to Polarizable Molecular Models J. Chem. Theory Comput. 2014, 10, 5513-5519 10.1021/ct5009069
25. Reed, S. K.; Madden, P. A.; Papadopoulos, A. Electrochemical Charge Transfer at a Metallic Electrode: A Simulation Study J. Chem. Phys. 2008, 128, 124701 10.1063/1.2844801
26. Golze, D.; Iannuzzi, M.; Nguyen, M.-T.; Passerone, D.; Hutter, J. Simulation of Adsorption Processes at Metallic Interfaces: An Image Charge Augmented Qm/Mm Approach J. Chem. Theory Comput. 2013, 9, 5086-5097 10.1021/ct400698y
27. Yeh, I.-C.; Berkowitz, M. L. Ewald Summation for Systems with Slab Geometry J. Chem. Phys. 1999, 111, 3155-3162 10.1063/1.479595
28. Heyes, D. M. Pressure Tensor of Partial-Charge and Point-Dipole Lattices with Bulk and Surface Geometries Phys. Rev. B: Condens. Matter Mater. Phys. 1994, 49, 755-764 10.1103/PhysRevB.49.755
29. Heyes, D. M. Molecular Dynamics of Ionic Solid and Liquid Surfaces Phys. Rev. B: Condens. Matter Mater. Phys. 1984, 30, 2182-2201 10.1103/PhysRevB.30.2182
30. Kawata, M.; Mikami, M. Rapid Calculation of Two-Dimensional Ewald Summation Chem. Phys. Lett. 2001, 340, 157-164 10.1016/S0009-2614(01)00378-5
31. Kawata, M.; Mikami, M.; Nagashima, U. Computationally Efficient Method to Calculate the Coulomb Interactions in Three-Dimensional Systems with Two-Dimensional Periodicity J. Chem. Phys. 2002, 116, 3430-3448 10.1063/1.1445103
32. Kawata, M.; Mikami, M.; Nagashima, U. Rapid Calculation of the Coulomb Component of the Stress Tensor for Three-Dimensional Systems with Two-Dimensional Periodicity J. Chem. Phys. 2001, 115, 4457-4462 10.1063/1.1395564
33. Kawata, M.; Nagashima, U. Particle Mesh Ewald Method for Three-Dimensional Systems with Two-Dimensional Periodicity Chem. Phys. Lett. 2001, 340, 165-172 10.1016/S0009-2614(01)00393-1
34. Pensado, A. S.; Malberg, F.; Gomes, M. F. C.; Padua, A. A. H.; Fernandez, J.; Kirchner, B. Interactions and Structure of Ionic Liquids on Graphene and Carbon Nanotubes Surfaces RSC Adv. 2014, 4, 18017-18024 10.1039/c4ra02059f
35. Kirchner, B.; Hollóczki, O.; Canongia Lopes, J. N.; Pádua, A. A. H. Multiresolution Calculation of Ionic Liquids Wiley Interdiscip. Rev.: Comput. Mol. Sci. 2015, 5, 202-214 10.1002/wcms.1212
36. Pak, A. J.; Paek, E.; Hwang, G. S. Tailoring the Performance of Graphene-Based Supercapacitors Using Topological Defects: A Theoretical Assessment Carbon 2014, 68, 734-741 10.1016/j.carbon.2013.11.057
37. García, G.; Atilhan, M.; Aparicio, S. Flavonols on Graphene: A Dft Insight Theor. Chem. Acc. 2015, 134, 1-13 10.1007/s00214-015-1660-4
38. Borodin, O. Polarizable Force Field Development and Molecular Dynamics Simulations of Ionic Liquids J. Phys. Chem. B 2009, 113, 11463-11478 10.1021/jp905220k
39. Borodin, O.; Smith, G. D.; Henderson, W. Li+ Cation Environment, Transport, and Mechanical Properties of the Litfsi Doped N-Methyl-N-Alkylpyrrolidinium+TFSI- Ionic Liquids J. Phys. Chem. B 2006, 110, 16879-16886 10.1021/jp061930t
40. Borodin, O.; Smith, G. D. Development of Many-Body Polarizable Force Fields for Li-Battery Components: 1. Ether, Alkane, and Carbonate-Based Solvents J. Phys. Chem. B 2006, 110, 6279-6292 10.1021/jp055079e
41. Borodin, O.; Smith, G. D. Development of Many-Body Polarizable Force Fields for Li-Battery Applications: 2. Litfsi-Doped Oligoether, Polyether, and Carbonate-Based Electrolytes J. Phys. Chem. B 2006, 110, 6293-6299 10.1021/jp055080d
42. Xing, L.; Vatamanu, J.; Borodin, O.; Smith, G. D.; Bedrov, D. Electrode/Electrolyte Interface in Sulfolane-Based Electrolytes for Li Ion Batteries: A Molecular Dynamics Simulation Study J. Phys. Chem. C 2012, 116, 23871-23881 10.1021/jp3054179
43. Vatamanu, J.; Borodin, O.; Smith, G. D. Molecular Dynamics Simulation Studies of the Structure of a Mixed Carbonate/LiPF6 Electrolyte near Graphite Surface as a Function of Electrode Potential J. Phys. Chem. C 2011, 116, 1114-1121 10.1021/jp2101539
44. Wu, F.; Lee, J. T.; Nitta, N.; Kim, H.; Borodin, O.; Yushin, G. Lithium Iodide as a Promising Electrolyte Additive for Lithium-Sulfur Batteries: Mechanisms of Performance Enhancement Adv. Mater. 2015, 27, 101-108 10.1002/adma.201404194
45. Vatamanu, J.; Borodin, O.; Smith, G. D. Molecular Simulations of the Electric Double Layer Structure, Differential Capacitance, and Charging Kinetics for N-Methyl-N-Propylpyrrolidinium Bis(Fluorosulfonyl)Imide at Graphite Electrodes J. Phys. Chem. B 2011, 115, 3073-3084 10.1021/jp2001207
46. Vatamanu, J.; Borodin, O.; Smith, G. D. Molecular Insights into the Potential and Temperature Dependences of the Differential Capacitance of a Room-Temperature Ionic Liquid at Graphite Electrodes J. Am. Chem. Soc. 2010, 132, 14825-33 10.1021/ja104273r
47. Hu, Z.; Vatamanu, J.; Borodin, O.; Bedrov, D. A Molecular Dynamics Simulation Study of the Electric Double Layer and Capacitance of [Bmim][PF6] and [Bmim][BF4] Room Temperature Ionic Liquids near Charged Surfaces Phys. Chem. Chem. Phys. 2013, 15, 14234-47 10.1039/c3cp51218e
48. Vatamanu, J.; Borodin, O.; Bedrov, D.; Smith, G. D. Molecular Dynamics Simulation Study of the Interfacial Structure and Differential Capacitance of Alkylimidazolium Bis(Trifluoromethanesulfonyl)Imide [Cnmim][TFSI] Ionic Liquids at Graphite Electrodes J. Phys. Chem. C 2012, 116, 7940-7951 10.1021/jp301399b
49. Hu, Z.; Vatamanu, J.; Borodin, O.; Bedrov, D. A Comparative Study of Alkylimidazolium Room Temperature Ionic Liquids with FSI and TFSI Anions near Charged Electrodes Electrochim. Acta 2014, 145, 40-52 10.1016/j.electacta.2014.08.072
50. Canongia Lopes, J. N.; Pádua, A. A. H. Molecular Force Field for Ionic Liquids Iii: Imidazolium, Pyridinium, and Phosphonium Cations; Chloride, Bromide, and Dicyanamide Anions J. Phys. Chem. B 2006, 110, 19586-19592 10.1021/jp063901o
51. Chaban, V. V.; Voroshylova, I. V. Systematic Refinement of Canongia Lopes-Pádua Force Field for Pyrrolidinium-Based Ionic Liquids J. Phys. Chem. B 2015, 119, 6242-6249 10.1021/jp5122678
52. Mondal, A.; Balasubramanian, S. A Refined All-Atom Potential for Imidazolium-Based Room Temperature Ionic Liquids: Acetate, Dicyanamide, and Thiocyanate Anions J. Phys. Chem. B 2015, 119, 11041 10.1021/acs.jpcb.5b02272
53. Shimizu, K.; Almantariotis, D.; Gomes, M. F. C.; Pádua, A. A. H.; Canongia Lopes, J. N. Molecular Force Field for Ionic Liquids V: Hydroxyethylimidazolium, Dimethoxy-2- Methylimidazolium, and Fluoroalkylimidazolium Cations and Bis(Fluorosulfonyl)Amide, Perfluoroalkanesulfonylamide, and Fluoroalkylfluorophosphate Anions J. Phys. Chem. B 2010, 114, 3592-3600 10.1021/jp9120468
54. Schröder, C.; Steinhauser, O. Simulating Polarizable Molecular Ionic Liquids with Drude Oscillators J. Chem. Phys. 2010, 133, 154511 10.1063/1.3493689
55. Tazi, S.; Molina, J. J.; Rotenberg, B.; Turq, P.; Vuilleumier, R.; Salanne, M. A Transferable Ab Initio Based Force Field for Aqueous Ions J. Chem. Phys. 2012, 136, 114507 10.1063/1.3692965
56. Molina, J. J.; Lectez, S.; Tazi, S.; Salanne, M.; Dufreîche, J.-F.; Roques, J.; Simoni, E.; Madden, P. A.; Turq, P. Ions in Solutions: Determining Their Polarizabilities from First-Principles J. Chem. Phys. 2011, 134, 014511 10.1063/1.3518101
57. Salanne, M.; Rotenberg, B.; Jahn, S.; Vuilleumier, R.; Simon, C.; Madden, P. Including Many-Body Effects in Models for Ionic Liquids Theor. Chem. Acc. 2012, 131, 1-16 10.1007/s00214-012-1143-9
58. Paek, E.; Pak, A. J.; Hwang, G. S. Curvature Effects on the Interfacial Capacitance of Carbon Nanotubes in an Ionic Liquid J. Phys. Chem. C 2013, 117, 23539-23546 10.1021/jp408085w
59. Paek, E.; Pak, A. J.; Hwang, G. S. A Computational Study of the Interfacial Structure and Capacitance of Graphene in [Bmim][PF6] Ionic Liquid J. Electrochem. Soc. 2013, 160, A1-A10 10.1149/2.019301jes
60. Pak, A. J.; Paek, E.; Hwang, G. S. Impact of Graphene Edges on Enhancing the Performance of Electrochemical Double Layer Capacitors J. Phys. Chem. C 2014, 118, 21770-21777 10.1021/jp504458z
61. Paek, E.; Pak, A. J.; Hwang, G. S. On the Influence of Polarization Effects in Predicting the Interfacial Structure and Capacitance of Graphene-Like Electrodes in Ionic Liquids J. Chem. Phys. 2015, 142, 024701 10.1063/1.4905328
62. Paek, E.; Pak, A. J.; Kweon, K. E.; Hwang, G. S. On the Origin of the Enhanced Supercapacitor Performance of Nitrogen-Doped Graphene J. Phys. Chem. C 2013, 117, 5610-5616 10.1021/jp312490q
63. Pak, A. J.; Paek, E.; Hwang, G. S. Relative Contributions of Quantum and Double Layer Capacitance to the Supercapacitor Performance of Carbon Nanotubes in an Ionic Liquid Phys. Chem. Chem. Phys. 2013, 15, 19741-19747 10.1039/C3CP52590B
64. Chapman, D. L. Li. A Contribution to the Theory of Electrocapillarity Philos. Mag. 1913, 25, 475-481 10.1080/14786440408634187
65. Gouy, G. Constitution of the Electric Charge at the Surface of an Electrolyte Compt. Rend. 1910, 149, 654
66. Stern, O. The Theory of the Electrolytic Double Layer Z. Elektrochem. Angew. Phys. Chem. 1924, 30, 508-516
67. Kornyshev, A. A. Double-Layer in Ionic Liquids: Paradigm Change? J. Phys. Chem. B 2007, 111, 5545-5557 10.1021/jp067857o
68. Oldham, K. B. A Gouy-Chapman-Stern Model of the Double Layer at a (Metal)/(Ionic Liquid) Interface J. Electroanal. Chem. 2008, 613, 131-138 10.1016/j.jelechem.2007.10.017
69. Yining, H.; Shanghui, H.; Tianying, Y. A Mean-Field Theory on the Differential Capacitance of Asymmetric Ionic Liquid Electrolytes J. Phys.: Condens. Matter 2014, 26, 284103 10.1088/0953-8984/26/28/284103
70. Kim, E.-Y.; Kim, S.-C. Electric Double Layer for a Size-Asymmetric Electrolyte around a Spherical Colloid J. Chem. Phys. 2014, 140, 154703 10.1063/1.4871499
71. Vibhu, I.; Modak, B.; Patra, C. N.; Ghosh, S. K. Zeta Potential of Colloidal Particle in Solvent Primitive Model Electrolyte Solution: A Density Functional Theory Study Mol. Phys. 2013, 111, 489-496 10.1080/00268976.2012.728637
72. Patra, C. N. Structure of Fluid Mixtures near a Solute: A Density Functional Approach J. Chem. Phys. 2014, 141, 104503 10.1063/1.4894810
73. Kim, E.-Y.; Kim, S.-C.; Han, Y.-S.; Seong, B.-S. Structure of a Planar Electric Double Layer Containing Size-Asymmetric Ions: Density Functional Approach Mol. Phys. 2015, 113, 871-879 10.1080/00268976.2014.985753
74. Henderson, D.; Jiang, D.-e.; Jin, Z.; Wu, J. Application of Density Functional Theory to Study the Double Layer of an Electrolyte with an Explicit Dimer Model for the Solvent J. Phys. Chem. B 2012, 116, 11356-11361 10.1021/jp305400z
75. Nagy, T.; Henderson, D.; Boda, D. Simulation of an Electrical Double Layer Model with a Low Dielectric Layer between the Electrode and the Electrolyte J. Phys. Chem. B 2011, 115, 11409-11419 10.1021/jp2063244
76. Jiménez-ángeles, F.; Lozada-Cassou, M. A Model Macroion Solution Next to a Charged Wall: Overcharging, Charge Reversal, and Charge Inversion by Macroions J. Phys. Chem. B 2004, 108, 7286-7296 10.1021/jp036464b
77. Modak, B.; Patra, C. N.; Ghosh, S. K.; Das, P. Structure of Colloidal Solution in Presence of Mixed Electrolytes: A Solvent Restricted Primitive Model Study J. Phys. Chem. B 2011, 115, 12126-12134 10.1021/jp204913d
78. Howard, J. J.; Perkyns, J. S.; Pettitt, B. M. The Behavior of Ions near a Charged Wall-Dependence on Ion Size, Concentration, and Surface Charge J. Phys. Chem. B 2010, 114, 6074-6083 10.1021/jp9108865
79. Guerrero-García, G. I.; González-Tovar, E.; Chávez-Páez, M.; Lozada-Cassou, M. Overcharging and Charge Reversal in the Electrical Double Layer around the Point of Zero Charge J. Chem. Phys. 2010, 132, 054903 10.1063/1.3294555
80. Iida, K.; Sato, H. A Two-Dimensional-Reference Interaction Site Model Theory for Solvation Structure near Solid-Liquid Interface J. Chem. Phys. 2011, 135, 244702 10.1063/1.3668468
81. Woelki, S.; Kohler, H.-H.; Krienke, H. A Singlet-RISM Theory for Solid/Liquid Interfaces Part I: Uncharged Walls J. Phys. Chem. B 2007, 111, 13386-13397 10.1021/jp068998t
82. Woelki, S.; Kohler, H.-H.; Krienke, H. A Singlet Reference Interation Site Model Theory for Solid/Liquid Interfaces Part Ii: Electrical Double Layers J. Phys. Chem. B 2008, 112, 3365-3374 10.1021/jp077485z
83. Outhwaite, C. W. Modified Poisson-Boltzmann Equation in Electric Double Layer Theory Based on the Bogoliubov-Born-Green-Yvon Integral Equations J. Chem. Soc., Faraday Trans. 2 1978, 74, 1214-1221 10.1039/f29787401214
84. Bazant, M. Z.; Storey, B. D.; Kornyshev, A. A. Double Layer in Ionic Liquids: Overscreening Versus Crowding Phys. Rev. Lett. 2011, 106, 046102 10.1103/PhysRevLett.106.046102
85. Booth, M. J.; Eaton, A. C.; Haymet, A. D. J. Electrolytes at Charged Interfaces: Integral Equation Theory for 2-2 and 1-1 Model Electrolytes J. Chem. Phys. 1995, 103, 417-431 10.1063/1.469608
86. Vatamanu, J.; Cao, L.; Borodin, O.; Bedrov, D.; Smith, G. D. On the Influence of Surface Topography on the Electric Double Layer Structure and Differential Capacitance of Graphite/Ionic Liquid Interfaces J. Phys. Chem. Lett. 2011, 2, 2267-2272 10.1021/jz200879a
87. Yamamoto, R.; Morisaki, H.; Sakata, O.; Shimotani, H.; Yuan, H.; Iwasa, Y.; Kimura, T.; Wakabayashi, Y. External Electric Field Dependence of the Structure of the Electric Double Layer at an Ionic Liquid/Au Interface Appl. Phys. Lett. 2012, 101, 053122 10.1063/1.4742920
88. Zhang, X.; Zhong, Y.-X.; Yan, J.-W.; Su, Y.-Z.; Zhang, M.; Mao, B.-W. Probing Double Layer Structures of Au (111)-Bmipf6 Ionic Liquid Interfaces from Potential-Dependent AFM Force Curves Chem. Commun. 2012, 48, 582-584 10.1039/C1CC15463J
89. Mezger, M.; Ocko, B. M.; Reichert, H.; Deutsch, M. Surface Layering and Melting in an Ionic Liquid Studied by Resonant Soft X-Ray Reflectivity Proc. Natl. Acad. Sci. U. S. A. 2013, 110, 3733-3737 10.1073/pnas.1211749110
90. Nishi, N.; Uruga, T.; Tanida, H.; Kakiuchi, T. Temperature Dependence of Multilayering at the Free Surface of Ionic Liquids Probed by X-Ray Reflectivity Measurements Langmuir 2011, 27, 7531-7536 10.1021/la200252z
91. Hayes, R.; Borisenko, N.; Tam, M. K.; Howlett, P. C.; Endres, F.; Atkin, R. Double Layer Structure of Ionic Liquids at the Au(111) Electrode Interface: An Atomic Force Microscopy Investigation J. Phys. Chem. C 2011, 115, 6855-6863 10.1021/jp200544b
92. Hayes, R.; El Abedin, S. Z.; Atkin, R. Pronounced Structure in Confined Aprotic Room-Temperature Ionic Liquids J. Phys. Chem. B 2009, 113, 7049-7052 10.1021/jp902837s
93. Atkin, R.; Warr, G. G. Structure in Confined Room-Temperature Ionic Liquids J. Phys. Chem. C 2007, 111, 5162-5168 10.1021/jp067420g
94. Smith, A. M.; Parkes, M. A.; Perkin, S. Molecular Friction Mechanisms across Nanofilms of a Bilayer-Forming Ionic Liquid J. Phys. Chem. Lett. 2014, 5, 4032-4037 10.1021/jz502188g
95. Smith, A. M.; Lovelock, K. R. J.; Gosvami, N. N.; Licence, P.; Dolan, A.; Welton, T.; Perkin, S. Monolayer to Bilayer Structural Transition in Confined Pyrrolidinium-Based Ionic Liquids J. Phys. Chem. Lett. 2013, 4, 378-382 10.1021/jz301965d
96. Zhong, Y.-X.; Yan, J.-W.; Li, M.-G.; Zhang, X.; He, D.-W.; Mao, B.-W. Resolving Fine Structures of the Electric Double Layer of Electrochemical Interfaces in Ionic Liquids with an AFM Tip Modification Strategy J. Am. Chem. Soc. 2014, 136, 14682-14685 10.1021/ja508222m
97. Baldelli, S. Surface Structure at the Ionic Liquid-Electrified Metal Interface Acc. Chem. Res. 2008, 41, 421-431 10.1021/ar700185h
98. Peñalber, C. Y.; Baldelli, S. Observation of Charge Inversion of an Ionic Liquid at the Solid Salt-Liquid Interface by Sum Frequency Generation Spectroscopy J. Phys. Chem. Lett. 2012, 3, 844-847 10.1021/jz3000917
99. Baldelli, S. Interfacial Structure of Room-Temperature Ionic Liquids at the Solid-Liquid Interface as Probed by Sum Frequency Generation Spectroscopy J. Phys. Chem. Lett. 2013, 4, 244-252 10.1021/jz301835j
100. Nishi, N.; Uchiyashiki, J.; Oogami, R.; Sakka, T. Ionic Liquid Structure at the Electrified Ionic Liquid|Hg Interface Studied Using in Situ Spectroscopic Ellipsometry Thin Solid Films 2014, 571, 735-738 10.1016/j.tsf.2013.10.117
101. Yokota, Y.; Harada, T.; Fukui, K.-i. Direct Observation of Layered Structures at Ionic Liquid/Solid Interfaces by Using Frequency-Modulation Atomic Force Microscopy Chem. Commun. 2010, 46, 8627-8629 10.1039/c0cc02643c
102. Pan, G.-B.; Freyland, W. 2d Phase Transition of PF6 Adlayers at the Electrified Ionic Liquid/Au(111) Interface Chem. Phys. Lett. 2006, 427, 96-100 10.1016/j.cplett.2006.05.114
103. Castillo, M. R.; Fraile, J. M.; Mayoral, J. A. Structure and Dynamics of 1-Butyl-3-Methylimidazolium Hexafluorophosphate Phases on Silica and Laponite Clay: From Liquid to Solid Behavior Langmuir 2012, 28, 11364-11375 10.1021/la300976p
104. Lamperski, S.; Outhwaite, C. W.; Bhuiyan, L. B. The Electric Double-Layer Differential Capacitance at and near Zero Surface Charge for a Restricted Primitive Model Electrolyte J. Phys. Chem. B 2009, 113, 8925-8929 10.1021/jp900037h
105. Lazar, P.; Zboril, R.; Pumera, M.; Otyepka, M. Chemical Nature of Boron and Nitrogen Dopant Atoms in Graphene Strongly Influences Its Electronic Properties Phys. Chem. Chem. Phys. 2014, 16, 14231-14235 10.1039/c4cp01638f
106. Lu, Y.-F.; Lo, S.-T.; Lin, J.-C.; Zhang, W.; Lu, J.-Y.; Liu, F.-H.; Tseng, C.-M.; Lee, Y.-H.; Liang, C.-T.; Li, L.-J. Nitrogen-Doped Graphene Sheets Grown by Chemical Vapor Deposition: Synthesis and Influence of Nitrogen Impurities on Carrier Transport ACS Nano 2013, 7, 6522-6532 10.1021/nn402102y
107. Geng, D.; Yang, S.; Zhang, Y.; Yang, J.; Liu, J.; Li, R.; Sham, T.-K.; Sun, X.; Ye, S.; Knights, S. Nitrogen Doping Effects on the Structure of Graphene Appl. Surf. Sci. 2011, 257, 9193-9198 10.1016/j.apsusc.2011.05.131
108. Gebhardt, J.; Koch, R. J.; Zhao, W.; Höfert, O.; Gotterbarm, K.; Mammadov, S.; Papp, C.; Görling, A.; Steinrück, H. P.; Seyller, T. Growth and Electronic Structure of Boron-Doped Graphene Phys. Rev. B: Condens. Matter Mater. Phys. 2013, 87, 155437 10.1103/PhysRevB.87.155437
109. Ju, L.; Velasco, J., Jr; Huang, E.; Kahn, S.; Nosiglia, C.; Tsai, H.-Z.; Yang, W.; Taniguchi, T.; Watanabe, K.; Zhang, Y. et al. Photoinduced Doping in Heterostructures of Graphene and Boron Nitride Nat. Nanotechnol. 2014, 9, 348-352 10.1038/nnano.2014.60
110. Merlet, C.; Salanne, M.; Rotenberg, B.; Madden, P. A. Imidazolium Ionic Liquid Interfaces with Vapor and Graphite: Interfacial Tension and Capacitance from Coarse-Grained Molecular Simulations J. Phys. Chem. C 2011, 115, 16613-16618 10.1021/jp205461g
111. Sha, M.; Dou, Q.; Luo, F.; Zhu, G.; Wu, G. Molecular Insights into the Electric Double Layers of Ionic Liquids on Au(100) Electrodes ACS Appl. Mater. Interfaces 2014, 6, 12556-12565 10.1021/am502413m
112. Kislenko, S. A.; Samoylov, I. S.; Amirov, R. H. Molecular Dynamics Simulation of the Electrochemical Interface between a Graphite Surface and the Ionic Liquid [Bmim][PF6] Phys. Chem. Chem. Phys. 2009, 11, 5584-5590 10.1039/b823189c
113. Merlet, C.; Salanne, M.; Rotenberg, B. New Coarse-Grained Models of Imidazolium Ionic Liquids for Bulk and Interfacial Molecular Simulations J. Phys. Chem. C 2012, 116, 7687-7693 10.1021/jp3008877
114. Liu, X.; Han, Y.; Yan, T. Temperature Effects on the Capacitance of an Imidazolium-Based Ionic Liquid on a Graphite Electrode: A Molecular Dynamics Simulation ChemPhysChem 2014, 15, 2503-2509 10.1002/cphc.201402220
115. Jin, W.; Liu, X.; Han, Y.; Li, S.; Yan, T. Effects of Repulsive Interaction on the Electric Double Layer of an Imidazolium-Based Ionic Liquid by Molecular Dynamics Simulation Phys. Chem. Chem. Phys. 2015, 17, 2628-2633 10.1039/C4CP04853A
116. Vatamanu, J.; Xing, L.; Li, W.; Bedrov, D. Influence of Temperature on the Capacitance of Ionic Liquid Electrolytes on Charged Surfaces Phys. Chem. Chem. Phys. 2014, 16, 5174-82 10.1039/c3cp54705a
117. Merlet, C.; Salanne, M.; Rotenberg, B.; Madden, P. A. Influence of Solvation on the Structural and Capacitive Properties of Electrical Double Layer Capacitors Electrochim. Acta 2013, 101, 262-271 10.1016/j.electacta.2012.12.107
118. Druschler, M.; Borisenko, N.; Wallauer, J.; Winter, C.; Huber, B.; Endres, F.; Roling, B. New Insights into the Interface between a Single-Crystalline Metal Electrode and an Extremely Pure Ionic Liquid: Slow Interfacial Processes and the Influence of Temperature on Interfacial Dynamics Phys. Chem. Chem. Phys. 2012, 14, 5090-5099 10.1039/c2cp40288b
119. Alam, M. T.; Islam, M. M.; Okajima, T.; Ohsaka, T. Measurements of Differential Capacitance at Mercury/Room-Temperature Ionic Liquids Interfaces J. Phys. Chem. C 2007, 111, 18326-18333 10.1021/jp075808l
120. Cannes, C.; Cachet, H.; Debiemme-Chouvy, C.; Deslouis, C.; de Sanoit, J.; Le Naour, C.; Zinovyeva, V. A. Double Layer at [Bumeim][Tf2N] Ionic Liquid-Pt or-C Material Interfaces J. Phys. Chem. C 2013, 117, 22915-22925 10.1021/jp407665q
121. Costa, R.; Pereira, C. M.; Silva, A. F. Charge Storage on Ionic Liquid Electric Double Layer: The Role of the Electrode Material Electrochim. Acta 2015, 167, 421-428 10.1016/j.electacta.2015.02.180
122. Gomes, C.; Costa, R.; Pereira, C. M.; Silva, A. F. The Electrical Double Layer at the Ionic Liquid/Au and Pt Electrode Interface RSC Adv. 2014, 4, 28914-28921 10.1039/C4RA03977G
123. Su, Y.-Z.; Fu, Y.-C.; Yan, J.-W.; Chen, Z.-B.; Mao, B.-W. Double Layer of Au(100)/Ionic Liquid Interface and Its Stability in Imidazolium-Based Ionic Liquids Angew. Chem. 2009, 121, 5250-5253 10.1002/ange.200900300
124. Costa, R.; Pereira, C. M.; Fernando Silva, A. Structural Ordering Transitions in Ionic Liquids Mixtures Electrochem. Commun. 2015, 57, 10-13 10.1016/j.elecom.2015.04.012
125. Nishi, N.; Hashimoto, A.; Minami, E.; Sakka, T. Electrocapillarity and Zero-Frequency Differential Capacitance at the Interface between Mercury and Ionic Liquids Measured Using the Pendant Drop Method Phys. Chem. Chem. Phys. 2015, 17, 5219-5226 10.1039/C4CP05818F
126. Tazi, S.; Salanne, M.; Simon, C.; Turq, P.; Pounds, M.; Madden, P. A. Potential-Induced Ordering Transition of the Adsorbed Layer at the Ionic Liquid/Electrified Metal Interface J. Phys. Chem. B 2010, 114, 8453-8459 10.1021/jp1030448
127. Outhwaite, C. W.; Lamperski, S.; Bhuiyan, L. B. Influence of Electrode Polarization on the Capacitance of an Electric Double Layer at and around Zero Surface Charge Mol. Phys. 2010, 109, 21-26 10.1080/00268976.2010.519731
128. Randin, J. P.; Yeager, E. Differential Capacitance Study of Stress-Annealed Pyrolytic Graphite Electrodes J. Electrochem. Soc. 1971, 118, 711-714 10.1149/1.2408151
129. Tang, M.; Miyazaki, K.; Abe, T.; Newman, J. Effect of Graphite Orientation and Lithium Salt on Electronic Passivation of Highly Oriented Pyrolytic Graphite J. Electrochem. Soc. 2012, 159, A634-A641 10.1149/2.073205jes
130. Gore, T. R.; Bond, T.; Zhang, W.; Scott, R. W. J.; Burgess, I. J. Hysteresis in the Measurement of Double-Layer Capacitance at the Gold-Ionic Liquid Interface Electrochem. Commun. 2010, 12, 1340-1343 10.1016/j.elecom.2010.07.015
131. Drüschler, M.; Huber, B.; Passerini, S.; Roling, B. Hysteresis Effects in the Potential-Dependent Double Layer Capacitance of Room Temperature Ionic Liquids at a Polycrystalline Platinum Interface J. Phys. Chem. C 2010, 114, 3614-3617 10.1021/jp911513k
132. Ho, T. A.; Striolo, A. Capacitance Enhancement via Electrode Patterning J. Chem. Phys. 2013, 139, 204708 10.1063/1.4833316
133. Xing, L.; Vatamanu, J.; Smith, G. D.; Bedrov, D. Nanopatterning of Electrode Surfaces as a Potential Route to Improve the Energy Density of Electric Double-Layer Capacitors: Insight from Molecular Simulations J. Phys. Chem. Lett. 2012, 3, 1124-1129 10.1021/jz300253p
134. Feng, G.; Jiang, D.-e.; Cummings, P. T. Curvature Effect on the Capacitance of Electric Double Layers at Ionic Liquid/Onion-Like Carbon Interfaces J. Chem. Theory Comput. 2012, 8, 1058-1063 10.1021/ct200914j
135. Feng, G.; Qiao, R.; Huang, J.; Dai, S.; Sumpter, B. G.; Meunier, V. The Importance of Ion Size and Electrode Curvature on Electrical Double Layers in Ionic Liquids Phys. Chem. Chem. Phys. 2011, 13, 1152-1161 10.1039/C0CP02077J
136. Vatamanu, J.; Hu, Z.; Bedrov, D.; Perez, C.; Gogotsi, Y. Increasing Energy Storage in Electrochemical Capacitors with Ionic Liquid Electrolytes and Nanostructured Carbon Electrodes J. Phys. Chem. Lett. 2013, 4, 2829-2837 10.1021/jz401472c
137. Farha, O. K.; Eryazici, I.; Jeong, N. C.; Hauser, B. G.; Wilmer, C. E.; Sarjeant, A. A.; Snurr, R. Q.; Nguyen, S. T.; Yazaydin, A. Ö.; Hupp, J. T. Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? J. Am. Chem. Soc. 2012, 134, 15016-15021 10.1021/ja3055639
138. Wang, T. C.; Bury, W.; Gómez-Gualdrón, D. A.; Vermeulen, N. A.; Mondloch, J. E.; Deria, P.; Zhang, K.; Moghadam, P. Z.; Sarjeant, A. A.; Snurr, R. Q. et al. Ultrahigh Surface Area Zirconium Mofs and Insights into the Applicability of the Bet Theory J. Am. Chem. Soc. 2015, 137, 3585-3591 10.1021/ja512973b
139. Sarkisov, L. Accessible Surface Area of Porous Materials: Understanding Theoretical Limits Adv. Mater. 2012, 24, 3130-3133 10.1002/adma.201104708
140. Pinkert, K.; Oschatz, M.; Borchardt, L.; Klose, M.; Zier, M.; Nickel, W.; Giebeler, L.; Oswald, S.; Kaskel, S.; Eckert, J. Role of Surface Functional Groups in Ordered Mesoporous Carbide-Derived Carbon/Ionic Liquid Electrolyte Double-Layer Capacitor Interfaces ACS Appl. Mater. Interfaces 2014, 6, 2922-2928 10.1021/am4055029
141. Chakrabarti, M. H.; Brandon, N. P.; Hajimolana, S. A.; Tariq, F.; Yufit, V.; Hashim, M. A.; Hussain, M. A.; Low, C. T. J.; Aravind, P. V. Application of Carbon Materials in Redox Flow Batteries J. Power Sources 2014, 253, 150-166 10.1016/j.jpowsour.2013.12.038
142. Cui, C.; Qian, W.; Yu, Y.; Kong, C.; Yu, B.; Xiang, L.; Wei, F. Highly Electroconductive Mesoporous Graphene Nanofibers and Their Capacitance Performance at 4 V J. Am. Chem. Soc. 2014, 136, 2256-2259 10.1021/ja412219r
143. Chmiola, J.; Yushin, G.; Gogotsi, Y.; Portet, C.; Simon, P.; Taberna, P. L. Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer Science 2006, 313, 1760-1763 10.1126/science.1132195
144. Lin, R.; Taberna, P. L.; Chmiola, J.; Guay, D.; Gogotsi, Y.; Simon, P. Microelectrode Study of Pore Size, Ion Size, and Solvent Effects on the Charge/Discharge Behavior of Microporous Carbons for Electrical Double-Layer Capacitors J. Electrochem. Soc. 2009, 156, A7-A12 10.1149/1.3002376
145. Wu, C.; Deng, S.; Wang, H.; Sun, Y.; Liu, J.; Yan, H. Preparation of Novel Three-Dimensional Nio/Ultrathin Derived Graphene Hybrid for Supercapacitor Applications ACS Appl. Mater. Interfaces 2014, 6, 1106-1112 10.1021/am404691w
146. Calvo, E. G.; Lufrano, F.; Staiti, P.; Brigandì, A.; Arenillas, A.; Menéndez, J. A. Optimizing the Electrochemical Performance of Aqueous Symmetric Supercapacitors Based on an Activated Carbon Xerogel J. Power Sources 2013, 241, 776-782 10.1016/j.jpowsour.2013.03.065
147. Ji, C. C.; Xu, M. W.; Bao, S. J.; Lu, Z. J.; Cai, C. J.; Chai, H.; Wang, R. Y.; Yang, F.; Wei, H. Self-Assembled Three-Dimensional Interpenetrating Porous Graphene Aerogels with MnO2 Coating and Their Application as High-Performance Supercapacitors New J. Chem. 2013, 37, 4199-4205 10.1039/c3nj00599b
148. Peng, Q.; Li, Y.; He, X.; Gui, X.; Shang, Y.; Wang, C.; Wang, C.; Zhao, W.; Du, S.; Shi, E. et al. Graphene Nanoribbon Aerogels Unzipped from Carbon Nanotube Sponges Adv. Mater. 2014, 26, 3241-3247 10.1002/adma.201305274
149. Li, P.; Kong, C.; Shang, Y.; Shi, E.; Yu, Y.; Qian, W.; Wei, F.; Wei, J.; Wang, K.; Zhu, H. et al. Highly Deformation-Tolerant Carbon Nanotube Sponges as Supercapacitor Electrodes Nanoscale 2013, 5, 8472-8479 10.1039/c3nr01932b
150. Niu, C.; Sichel, E. K.; Hoch, R.; Moy, D.; Tennent, H. High Power Electrochemical Capacitors Based on Carbon Nanotube Electrodes Appl. Phys. Lett. 1997, 70, 1480-1482 10.1063/1.118568
151. Jiang, H.; Li, C.; Sun, T.; Ma, J. A Green and High Energy Density Asymmetric Supercapacitor Based on Ultrathin Mno 2 Nanostructures and Functional Mesoporous Carbon Nanotube Electrodes Nanoscale 2012, 4, 807-812 10.1039/C1NR11542A
152. Lin, C.; Ritter, J. A.; Popov, B. N. Characterization of Sol-Gel-Derived Cobalt Oxide Xerogels as Electrochemical Capacitors J. Electrochem. Soc. 1998, 145, 4097-4103 10.1149/1.1838920
153. Curran, S. A.; Ajayan, P. M.; Blau, W. J.; Carroll, D. L.; Coleman, J. N.; Dalton, A. B.; Davey, A. P.; Drury, A.; McCarthy, B.; Maier, S. et al. A Composite from Poly(m-phenylenevinylene-co-2,5-Dioctoxy-p-phenylenevinylene) and Carbon Nanotubes: A Novel Material for Molecular Optoelectronics Adv. Mater. 1998, 10, 1091-1093 10.1002/(SICI)1521-4095(199810)10:14<1091::AID-ADMA1091>3.3.CO;2-C
154. Markoulidis, F.; Lei, C.; Lekakou, C.; Duff, D.; Khalil, S.; Martorana, B.; Cannavaro, I. A Method to Increase the Energy Density of Supercapacitor Cells by the Addition of Multiwall Carbon Nanotubes into Activated Carbon Electrodes Carbon 2014, 68, 58-66 10.1016/j.carbon.2013.08.040
155. Hao, L.; Ning, J.; Luo, B.; Wang, B.; Zhang, Y.; Tang, Z.; Yang, J.; Thomas, A.; Zhi, L. Structural Evolution of 2d Microporous Covalent Triazine-Based Framework toward the Study of High-Performance Supercapacitors J. Am. Chem. Soc. 2015, 137, 219-225 10.1021/ja508693y
156. Chen, H.; Wang, H.; Yang, L.; Xiao, Y.; Zheng, M.; Liu, Y.; Fu, H. High Specific Surface Area Rice Hull Based Porous Carbon Prepared for EDLCs Int. J. Electrochem. Sc. 2012, 7, 4889-4897
157. Zhang, L.; Zhang, F.; Yang, X.; Long, G.; Wu, Y.; Zhang, T.; Leng, K.; Huang, Y.; Ma, Y.; Yu, A. et al. Porous 3D Graphene-Based Bulk Materials with Exceptional High Surface Area and Excellent Conductivity for Supercapacitors Sci. Rep. 2013, 3, 1408 10.1038/srep01408
158. Kondrat, S.; Wu, P.; Qiao, R.; Kornyshev, A. A. Accelerating Charging Dynamics in Subnanometre Pores Nat. Mater. 2014, 13, 387-393 10.1038/nmat3916
159. Kondrat, S.; Kornyshev, A. Charging Dynamics and Optimization of Nanoporous Supercapacitors J. Phys. Chem. C 2013, 117, 12399-12406 10.1021/jp400558y
160. He, Y.; Huang, J.; Sumpter, B. G.; Kornyshev, A. A.; Qiao, R. Dynamic Charge Storage in Ionic Liquids-Filled Nanopores: Insight from a Computational Cyclic Voltammetry Study J. Phys. Chem. Lett. 2015, 6, 22-30 10.1021/jz5024306
161. Bandopadhyay, A.; Hossain, S. S.; Chakraborty, S. Ionic Size Dependent Electroviscous Effects in Ion-Selective Nanopores Langmuir 2014, 30, 7251-7258 10.1021/la5014957
162. O'Hern, S. C.; Boutilier, M. S. H.; Idrobo, J.-C.; Song, Y.; Kong, J.; Laoui, T.; Atieh, M.; Karnik, R. Selective Ionic Transport through Tunable Subnanometer Pores in Single-Layer Graphene Membranes Nano Lett. 2014, 14, 1234-1241 10.1021/nl404118f
163. Marchetti, P.; Jimenez Solomon, M. F.; Szekely, G.; Livingston, A. G. Molecular Separation with Organic Solvent Nanofiltration: A Critical Review Chem. Rev. 2014, 114, 10735-10806 10.1021/cr500006j
164. Aba, N. F. D.; Chong, J. Y.; Wang, B.; Mattevi, C.; Li, K. Graphene Oxide Membranes on Ceramic Hollow Fibers-Microstructural Stability and Nanofiltration Performance J. Membr. Sci. 2015, 484, 87-94 10.1016/j.memsci.2015.03.001
165. Marchetti, P.; Livingston, A. G. Predictive Membrane Transport Models for Organic Solvent Nanofiltration: How Complex Do We Need to Be? J. Membr. Sci. 2015, 476, 530-553 10.1016/j.memsci.2014.10.030
166. Guo, W.; Cao, L.; Xia, J.; Nie, F.-Q.; Ma, W.; Xue, J.; Song, Y.; Zhu, D.; Wang, Y.; Jiang, L. Energy Harvesting with Single-Ion-Selective Nanopores: A Concentration-Gradient-Driven Nanofluidic Power Source Adv. Funct. Mater. 2010, 20, 1339-1344 10.1002/adfm.200902312
167. Rao, S.; Lu, S.; Guo, Z.; Li, Y.; Chen, D.; Xiang, Y. A Light-Powered Bio-Capacitor with Nanochannel Modulation Adv. Mater. 2014, 26, 5846-5850 10.1002/adma.201401321
168. Largeot, C.; Portet, C.; Chmiola, J.; Taberna, P.-L.; Gogotsi, Y.; Simon, P. Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor J. Am. Chem. Soc. 2008, 130, 2730-2731 10.1021/ja7106178
169. Barbieri, O.; Hahn, M.; Herzog, A.; Kötz, R. Capacitance Limits of High Surface Area Activated Carbons for Double Layer Capacitors Carbon 2005, 43, 1303-1310 10.1016/j.carbon.2005.01.001
170. Doh, C.-H.; Kim, H.-S.; Moon, S.-I. A Study on the Irreversible Capacity of Initial Doping/Undoping of Lithium into Carbon J. Power Sources 2001, 101, 96-102 10.1016/S0378-7753(01)00627-9
171. Vix-Guterl, C.; Frackowiak, E.; Jurewicz, K.; Friebe, M.; Parmentier, J.; Béguin, F. Electrochemical Energy Storage in Ordered Porous Carbon Materials Carbon 2005, 43, 1293-1302 10.1016/j.carbon.2004.12.028
172. Jänes, A.; Permann, L.; Arulepp, M.; Lust, E. Electrochemical Characteristics of Nanoporous Carbide-Derived Carbon Materials in Non-Aqueous Electrolyte Solutions Electrochem. Commun. 2004, 6, 313-318 10.1016/j.elecom.2004.01.009
173. Ji, H.; Zhao, X.; Qiao, Z.; Jung, J.; Zhu, Y.; Lu, Y.; Zhang, L. L.; MacDonald, A. H.; Ruoff, R. S. Capacitance of Carbon-Based Electrical Double-Layer Capacitors Nat. Commun. 2014, 5, 3317 10.1038/ncomms4317
174. Hsia, B.; Kim, M. S.; Luna, L. E.; Mair, N. R.; Kim, Y.; Carraro, C.; Maboudian, R. Templated 3d Ultrathin Cvd Graphite Networks with Controllable Geometry: Synthesis and Application as Supercapacitor Electrodes ACS Appl. Mater. Interfaces 2014, 6, 18413-18417 10.1021/am504695t
175. Centeno, T. A.; Hahn, M.; Fernández, J. A.; Kötz, R.; Stoeckli, F. Correlation between Capacitances of Porous Carbons in Acidic and Aprotic Edlc Electrolytes Electrochem. Commun. 2007, 9, 1242-1246 10.1016/j.elecom.2007.01.031
176. Centeno, T. A.; Sereda, O.; Stoeckli, F. Capacitance in Carbon Pores of 0.7 to 15 Nm: A Regular Pattern Phys. Chem. Chem. Phys. 2011, 13, 12403-12406 10.1039/c1cp20748b
177. Fernández, J. A.; Arulepp, M.; Leis, J.; Stoeckli, F.; Centeno, T. A. Edlc Performance of Carbide-Derived Carbons in Aprotic and Acidic Electrolytes Electrochim. Acta 2008, 53, 7111-7116 10.1016/j.electacta.2008.05.028
178. Lota, G.; Centeno, T. A.; Frackowiak, E.; Stoeckli, F. Improvement of the Structural and Chemical Properties of a Commercial Activated Carbon for Its Application in Electrochemical Capacitors Electrochim. Acta 2008, 53, 2210-2216 10.1016/j.electacta.2007.09.028
179. Jiang, D.-e.; Jin, Z.; Henderson, D.; Wu, J. Solvent Effect on the Pore-Size Dependence of an Organic Electrolyte Supercapacitor J. Phys. Chem. Lett. 2012, 3, 1727-1731 10.1021/jz3004624
180. Merlet, C.; Péan, C.; Rotenberg, B.; Madden, P. A.; Daffos, B.; Taberna, P. L.; Simon, P.; Salanne, M. Highly Confined Ions Store Charge More Efficiently in Supercapacitors Nat. Commun. 2013, 4, 2701 10.1038/ncomms3701
181. Merlet, C.; Rotenberg, B.; Madden, P. A.; Taberna, P.-L.; Simon, P.; Gogotsi, Y.; Salanne, M. On the Molecular Origin of Supercapacitance in Nanoporous Carbon Electrodes Nat. Mater. 2012, 11, 306-310 10.1038/nmat3260
182. Gamby, J.; Taberna, P. L.; Simon, P.; Fauvarque, J. F.; Chesneau, M. Studies and Characterisations of Various Activated Carbons Used for Carbon/Carbon Supercapacitors J. Power Sources 2001, 101, 109-116 10.1016/S0378-7753(01)00707-8
183. Balducci, A.; Dugas, R.; Taberna, P. L.; Simon, P.; Plée, D.; Mastragostino, M.; Passerini, S. High Temperature Carbon-Carbon Supercapacitor Using Ionic Liquid as Electrolyte J. Power Sources 2007, 165, 922-927 10.1016/j.jpowsour.2006.12.048
184. Kondrat, S.; Georgi, N.; Fedorov, M. V.; Kornyshev, A. A. A Superionic State in Nano-Porous Double-Layer Capacitors: Insights from Monte Carlo Simulations Phys. Chem. Chem. Phys. 2011, 13, 11359-11366 10.1039/c1cp20798a
185. Kornyshev, A. A. The Simplest Model of Charge Storage in Single File Metallic Nanopores Faraday Discuss. 2013, 164, 117-133 10.1039/c3fd00026e
186. Lee, A. A.; Kondrat, S.; Kornyshev, A. A. Single-File Charge Storage in Conducting Nanopores Phys. Rev. Lett. 2014, 113, 048701 10.1103/PhysRevLett.113.048701
187. Wu, P.; Huang, J.; Meunier, V.; Sumpter, B. G.; Qiao, R. Voltage Dependent Charge Storage Modes and Capacity in Subnanometer Pores J. Phys. Chem. Lett. 2012, 3, 1732-1737 10.1021/jz300506j
188. Wu, P.; Huang, J.; Meunier, V.; Sumpter, B. G.; Qiao, R. Complex Capacitance Scaling in Ionic Liquids-Filled Nanopores ACS Nano 2011, 5, 9044-9051 10.1021/nn203260w
189. Xing, L.; Vatamanu, J.; Borodin, O.; Bedrov, D. On the Atomistic Nature of Capacitance Enhancement Generated by Ionic Liquid Electrolyte Confined in Subnanometer Pores J. Phys. Chem. Lett. 2013, 4, 132-140 10.1021/jz301782f
190. Vatamanu, J.; Vatamanu, M.; Bedrov, D. Non-Faradaic Energy Storage by Room Temperature Ionic Liquids in Nanoporous Electrodes ACS Nano 2015, 9, 5999-6017 10.1021/acsnano.5b00945
191. Feng, G.; Cummings, P. T. Supercapacitor Capacitance Exhibits Oscillatory Behavior as a Function of Nanopore Size J. Phys. Chem. Lett. 2011, 2, 2859-2864 10.1021/jz201312e
192. Jiang, D.-e.; Jin, Z.; Wu, J. Oscillation of Capacitance inside Nanopores Nano Lett. 2011, 11, 5373-5377 10.1021/nl202952d
193. Henderson, D. Oscillations in the Capacitance of a Nanopore Containing an Electrolyte Due to Pore Width and Nonzero Size Ions J. Colloid Interface Sci. 2012, 374, 345-347 10.1016/j.jcis.2012.01.050
194. Kiyohara, K.; Shioyama, H.; Sugino, T.; Asaka, K. Phase Transition in Porous Electrodes. II. Effect of Asymmetry in the Ion Size J. Chem. Phys. 2012, 136, 094701 10.1063/1.3690084
195. Kiyohara, K.; Sugino, T.; Asaka, K. Phase Transition in Porous Electrodes J. Chem. Phys. 2011, 134, 154710 10.1063/1.3578468
196. Jiang, D.-e.; Wu, J. Unusual Effects of Solvent Polarity on Capacitance for Organic Electrolytes in a Nanoporous Electrode Nanoscale 2014, 6, 5545-5550 10.1039/c4nr00046c
197. Jung, S. M.; Mafra, D. L.; Lin, C.-T.; Jung, H. Y.; Kong, J. Controlled Porous Structures of Graphene Aerogels and Their Effect on Supercapacitor Performance Nanoscale 2015, 7, 4386-4393 10.1039/C4NR07564A
198. Péan, C.; Merlet, C.; Rotenberg, B.; Madden, P. A.; Taberna, P.-L.; Daffos, B.; Salanne, M.; Simon, P. On the Dynamics of Charging in Nanoporous Carbon-Based Supercapacitors ACS Nano 2014, 8, 1576-1583 10.1021/nn4058243
199. Tanguy, J.; Baudoin, J. L.; Chao, F.; Costa, M. Study of the Redox Mechanism of Poly-3-Methylthiophene by Impedance Spectroscopy Electrochim. Acta 1992, 37, 1417-1428 10.1016/0013-4686(92)87016-S
200. Kierzek, K.; Frackowiak, E.; Lota, G.; Gryglewicz, G.; Machnikowski, J. Electrochemical Capacitors Based on Highly Porous Carbons Prepared by Koh Activation Electrochim. Acta 2004, 49, 515-523 10.1016/j.electacta.2003.08.026
201. Sevilla, M.; Foulston, R.; Mokaya, R. Superactivated Carbide-Derived Carbons with High Hydrogen Storage Capacity Energy Environ. Sci. 2010, 3, 223-227 10.1039/B916197J
202. Peng, C.; Jin, J.; Chen, G. Z. A Comparative Study on Electrochemical Co-Deposition and Capacitance of Composite Films of Conducting Polymers and Carbon Nanotubes Electrochim. Acta 2007, 53, 525-537 10.1016/j.electacta.2007.07.004
203. Reimers, J. N.; Dahn, J. R. Electrochemical and in Situ X-Ray Diffraction Studies of Lithium Intercalation in Lix Co O2 J. Electrochem. Soc. 1992, 139, 2091-2097 10.1149/1.2221184
204. Xing, W.; Qiao, S. Z.; Ding, R. G.; Li, F.; Lu, G. Q.; Yan, Z. F.; Cheng, H. M. Superior Electric Double Layer Capacitors Using Ordered Mesoporous Carbons Carbon 2006, 44, 216-224 10.1016/j.carbon.2005.07.029
205. Gnahm, M.; Pajkossy, T.; Kolb, D. M. The Interface between Au(111) and an Ionic Liquid Electrochim. Acta 2010, 55, 6212-6217 10.1016/j.electacta.2009.08.031
206. Thounthong, P.; Raël, S.; Davat, B. Energy Management of Fuel Cell/Battery/Supercapacitor Hybrid Power Source for Vehicle Applications J. Power Sources 2009, 193, 376-385 10.1016/j.jpowsour.2008.12.120
207. Zhao, H.; Burke, A. F. Fuel Cell Powered Vehicles Using Supercapacitors-Device Characteristics, Control Strategies, and Simulation Results Fuel Cells 2010, 10, 879-896 10.1002/fuce.200900214
208. Stoppa, M.; Chiolerio, A. Wearable Electronics and Smart Textiles: A Critical Review Sensors 2014, 14, 11957-11992 10.3390/s140711957
209. Yao, B.; Yuan, L.; Xiao, X.; Zhang, J.; Qi, Y.; Zhou, J.; Zhou, J.; Hu, B.; Chen, W. Paper-Based Solid-State Supercapacitors with Pencil-Drawing Graphite/Polyaniline Networks Hybrid Electrodes Nano Energy 2013, 2, 1071-1078 10.1016/j.nanoen.2013.09.002
210. Yuan, L.; Xiao, X.; Ding, T.; Zhong, J.; Zhang, X.; Shen, Y.; Hu, B.; Huang, Y.; Zhou, J.; Wang, Z. L. Paper-Based Supercapacitors for Self-Powered Nanosystems Angew. Chem., Int. Ed. 2012, 51, 4934-4938 10.1002/anie.201109142
211. Rath, T.; Kundu, P. P. Reduced Graphene Oxide Paper Based Nanocomposite Materials for Flexible Supercapacitors RSC Adv. 2015, 5, 26666-26674 10.1039/C5RA00563A
212. Teng, S.; Siegel, G.; Wang, W.; Tiwari, A. Carbonized Wood for Supercapacitor Electrodes ECS Solid State Lett. 2014, 3, M25-M28 10.1149/2.005405ssl
213. Jiang, J.; Zhang, L.; Wang, X.; Holm, N.; Rajagopalan, K.; Chen, F.; Ma, S. Highly Ordered Macroporous Woody Biochar with Ultra-High Carbon Content as Supercapacitor Electrodes Electrochim. Acta 2013, 113, 481-489 10.1016/j.electacta.2013.09.121
214. Huang, Y.; Hu, H.; Huang, Y.; Zhu, M.; Meng, W.; Liu, C.; Pei, Z.; Hao, C.; Wang, Z.; Zhi, C. From Industrially Weavable and Knittable Highly Conductive Yarns to Large Wearable Energy Storage Textiles ACS Nano 2015, 9, 4766-4775 10.1021/acsnano.5b00860
215. Lee, J. A.; Shin, M. K.; Kim, S. H.; Cho, H. U.; Spinks, G. M.; Wallace, G. G.; Lima, M. D.; Lepró, X.; Kozlov, M. E.; Baughman, R. H. et al. Ultrafast Charge and Discharge Biscrolled Yarn Supercapacitors for Textiles and Microdevices Nat. Commun. 2013, 4, 1970 10.1038/ncomms2970
216. Huang, C.; Grant, P. S. One-Step Spray Processing of High Power All-Solid-State Supercapacitors Sci. Rep. 2013, 3, 2393 10.1038/srep02393
217. Wu, Z. S.; Parvez, K.; Feng, X.; Müllen, K. Graphene-Based in-Plane Micro-Supercapacitors with High Power and Energy Densities Nat. Commun. 2013, 4, 2487 10.1038/ncomms3487
218. El-Kady, M. F.; Kaner, R. B. Scalable Fabrication of High-Power Graphene Micro-Supercapacitors for Flexible and on-Chip Energy Storage Nat. Commun. 2013, 4, 1475 10.1038/ncomms2446
219. Zhang, Z.; Chen, X.; Chen, P.; Guan, G.; Qiu, L.; Lin, H.; Yang, Z.; Bai, W.; Luo, Y.; Peng, H. Integrated Polymer Solar Cell and Electrochemical Supercapacitor in a Flexible and Stable Fiber Format Adv. Mater. 2014, 26, 466-470 10.1002/adma.201302951
220. Hur, J.; Im, K.; Kim, S. W.; Kim, U. J.; Lee, J.; Hwang, S.; Song, J.; Kim, S.; Hwang, S.; Park, N. DNA Hydrogel Templated Carbon Nanotube and Polyaniline Assembly and Its Applications for Electrochemical Energy Storage Devices J. Mater. Chem. A 2013, 1, 14460-14466 10.1039/c3ta13382f
221. Hur, J.; Im, K.; Hwang, S.; Choi, B.; Kim, S.; Hwang, S.; Park, N.; Kim, K. DNA Hydrogel-Based Supercapacitors Operating in Physiological Fluids Sci. Rep. 2013, 3, 1282 10.1038/srep01282