Influence of electrode polarization on the capacitance of an electric double layer at and around zero surface charge

Molecular Physics

Volumn 109, Issue 1, 2011, Pages 21-26

  Outhwaite, Christopher W ^a   Lamperski, Stanislaw ^b   Bhuiyan, Lutful Bari ^c  

^a UNIVERSITY OF SHEFFIELD   (United Kingdom)

^b ADAM MICKIEWICZ UNIVERSITY   (Poland)

^c UNIVERSITY OF PUERTO RICO   (Puerto Rico)

Author keywords

capacitance; electric double layer; electrode polarization; modified Poisson Boltzmann

Indexed keywords

DIELECTRIC DISCONTINUITY; DOUBLE LAYERS; ELECTRIC DOUBLE LAYER; ELECTRODE POLARIZATION; ELECTRODE POLARIZATIONS; ELECTRODE-ELECTROLYTE INTERFACES; GRADUAL TRANSITION; IMAGE CHARGES; IMAGE INTERACTION; INTERFACIAL CAPACITANCE; LOW ELECTROLYTE CONCENTRATION; LOW TEMPERATURES; METALLIC CONDUCTOR; POISSON-BOLTZMANN; POISSON-BOLTZMANN THEORY; RELATIVE PERMITTIVITY; RESTRICTED PRIMITIVE MODEL; SURFACE POLARIZATION CHARGE; SURFACE POLARIZATIONS; ZERO SURFACE CHARGE;

CAPACITANCE; CHARGED PARTICLES; CONCENTRATION (PROCESS); ELECTROCHEMISTRY; ELECTROLYTES; PERMITTIVITY; SURFACE CHARGE;

POLARIZATION;

EID: 79551509383     PISSN: 00268976     EISSN: 13623028     Source Type: Journal    
DOI: 10.1080/00268976.2010.519731     Document Type: Article

References (30)

1. D. Henderson and D. Boda, Phys. Chem. Chem. Phys. 11, 3822 (2009).
2. A.A. Kornyshev, J. Phys. Chem. B 111, 5545 (2007).
3. W.R. Fawcett, P.J. Ryan and T.G. Smagala, J. Phys. Chem. B 113, 14310 (2009).
4. S. Lamperski, C.W. Outhwaite and L.B. Bhuiyan, J. Phys. Chem. B 113, 8925 (2009); ibid 114, 3075 (2010).
5. G. Gouy, J. Phys. (Paris) 9, 457 (1910).
6. D.L. Chapman, Philos. Mag. 25, 475 (1913).
7. O. Stern and Z. Elektrochem, 30, 508 (1924).
8. M.S. Kilic, M.Z. Bazant and A. Ajdari, Phys. Rev. E: Stat. Nonlinear Soft Matter Phys. 75, 021502 (2007).
9. M.V. Fedorov and A.A. Kornyshev, Electrochimica. Acta 53, 6835 (2008).
10. M.V. Fedorov and A.A. Kornyshev, J. Phys. Chem. B 112, 11868 (2008).
11. M.V. Fedorov, N. Georgi and A.A. Kornyshev, Electrochem. Commun. 12, 296 (2010).
12. Y. Lauw, M.D. Horne, T. Rodopoulos and FA.M. Leermakers, Phys. Rev. Lett. 103, 117801-1 (2009).
13. M. Trulsson, J. Algitsson, J. Forsman and C.E. Woodward, J. Phys. Chem. Lett. 1, 1191 (2010).
14. S. Lamperski and J. Klos, J. Chem. Phys. 129, 164503 (2008).
15. J. Klos and S. Lamperski, J. Phys. Chem. C 114, 13329 (2010).
16. M.T. Alam, M.M. Islam, T. Okajima and T. Oshaka, Electrochem. Commun. 9, 2370 (2007).
17. M.M. Islam, M.T. Alam and T. Oshaka, J. Phys. Chem. C 112, 16568 (2008).
18. M.T. Alam, M.M. Islam, T. Okajima and T. Oshaka, J. Phys. Chem. C 112, 16600 (2008).
19. C. Nanjundiah, S.F. MvDevitt and V.R. Koch, J. Electrochem. Soc. 144, 3392 (1997).
20. V. Lockett, R. Sedev, J. Ralston, M. Horne and T. Rodopoulos, J. Phys. Chem. C 112, 7486 (2008).
21. G.M. Torrie, J.P. Valleau and G.N. Patey, J. Chem. Phys. 76, 4615 (1982).
22. M. Alawneh and D. Henderson, Mol. Sim. 33, 541 (2007).
23. L.B. Bhuiyan, C.W. Outhwaite, D. Henderson and M. Alawneh, Mol. Phys. 105, 1395 (2007).
24. M. Alawneh, D. Henderson, C.W. Outhwaite and L.B. Bhuiyan, Mol. Sim. 34, 501 (2008).
25. C.W. Outhwaite and L.B. Bhuiyan, J. Chem. Soc. Faraday Trans. 2 79, 707 (1983).
26. J. Fischer, Mol. Phys. 33, 75 (1977).
27. R. Bellman and R. Kalaba, Quasilinerization and Nonlinear Boundary Value Problems (Elsevier, New York, 1965).
28. C.W. Outhwaite, L.B. Bhuiyan and S. Levine, J. Chem. Soc. Faraday Trans. 2 76, 1388 (1980).
29. W.R. Fawcett and P.J. Ryan, Collect. Czech. Chem. Commun. 74, 1665 (2009).
30. M. Eigen and E. Wicke, J. Phys. Chem. 58, 702 (1954).