Molecular insights into the potential and temperature dependences of the differential capacitance of a room-temperature ionic liquid at graphite electrodes

Journal of the American Chemical Society

Volumn 132, Issue 42, 2010, Pages 14825-14833

  Vatamanu, Jenel ^a   Borodin, Oleg ^a   Smith, Grant D ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COUNTERIONS; DIFFERENTIAL CAPACITANCE; DIFFERENTIAL CAPACITANCE (DC); ELECTRODE POLARITIES; ELECTRODE POTENTIALS; ELECTRODE SURFACES; INTERFACIAL LAYER; ION ORIENTATION; MOLECULAR DYNAMICS SIMULATIONS; MOLECULAR INSIGHTS; MULTILAYER STRUCTURES; POSITIVE POTENTIAL; POTENTIAL OF ZERO CHARGE; ROOM TEMPERATURE IONIC LIQUIDS; STRONG INTERACTION; SULFONYL IMIDE; TEMPERATURE DEPENDENCE; TRIFLUOROMETHANE; VOLUME EFFECT;

CAPACITANCE; ELECTROCHEMICAL ELECTRODES; ELECTROLYSIS; FLUORINE; GRAPHITE; IONIC LIQUIDS; IONS; MOLECULAR DYNAMICS;

GRAPHITE ELECTRODES;

ELECTROLYTE; GRAPHITE; IONIC LIQUID; N METHYL N PROPYLPYRROLIDINIUM BIS(TRIFLUOROMETHANE)SULFONYL IMIDE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; ELECTROCHEMISTRY; ELECTRODE; ENTROPY; MOLECULAR DYNAMICS; MOLECULAR MODEL; ROOM TEMPERATURE; TEMPERATURE;

EID: 77958461486     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja104273r     Document Type: Article

References (95)

1. Chmiola, J., Yushin, G., Gogotsi, Y., Portet, C., Simon, P., and Taberna, P. L. Science 2006, 313, 1760
2. Largeot, C., Portet, C., Chmiola, J., Taberna, P. L., Gogotsi, Y., and Simon, P. J. Am. Chem. Soc. 2008, 130, 2730
3. Simon, P. and Gogotsi, I. Nat. Mater. 2008, 7, 845
4. Cyr, M. D., Venkataraman, B., Flynn, G. W., Black, A., and Whitesides, G. M. J. Phys. Chem. 1996, 100, 13747
5. Tao, F. and Bernasek, S. L. J. Am. Chem. Soc. 2005, 127, 12750
6. Su, Y.-Z., Fu, Y.-C., Yan, J.-W., Chen, Z.-B., and Mao, B.-W. Angew. Chem., Int. Ed. 2009, 48, 5148
7. Pei, Y. and Ma, J. J. Am. Chem. Soc. 2005, 127, 6802
8. Fedorov, M. V. and Kornyshev, A. A. J. Phys. Chem. B 2008, 112, 11868
9. Kislenko, S. A., Samoylov, I. S., and Amirov, R. H. Phys. Chem. Chem. Phys. 2009, 11, 5584
10. Dong, K., Ahou, G., Liu, X., Yao, X., Shang, S., and Lyubartsev, A. J. Phys. Chem. C. 2009, 113, 10013
11. Sieffert, N. and Wipff, G. J. Phys. Chem. C. 2008, 112, 19590
12. Goel, T., Patra, N. C., Ghosh, K. S., and Mukherjee, T. J. Chem. Phys. 2008, 129, 154707
13. Kornyshev, A. A. J. Phys. Chem. B 2007, 111, 5545
14. Pandolfo, A. G. and Hollemkamp, A. F. J. Power Sources 2006, 157, 11
15. Yang, C. M., Kim, Y.-J., Endo, M., Kanoh, H., Yudasaka, M., Iijima, S., and Kaneko, K. J. Am. Chem. Soc. 2007, 129, 20
16. Anderson, J. L., Armstrong, D. W., and Wei, G.-T. Anal. Chem. 2006, 2893
17. Hapiot, P. and Lagrost, C. Chem. Rev. 2008, 108, 2238
18. Parsons, R. Chem. Rev. 1990, 90, 813
19. Schmickler, W. Chem. Rev. 1996, 96, 3177
20. McCreery, R. L. Chem. Rev. 2008, 108, 2646
21. Kötz, R. and Press, M. C. Electrochim. Acta 2000, 45, 2483
22. Conway, B. E. Electrochemical Capacitors: Scientific Fundamentals and Technological Applications; Kluwer: Dordrecht, The Netherlands, 1999.
23. Arico, A. S., Bruce, P., Scrosati, B., Tarascon, J.-M., and Schalkwijk, W. V. Nat. Mater. 2005, 4, 366
24. Seki, S., Kobayashi, Y., Miyashiro, H., Ohno, Y., Usami, A., Mita, Y., Kihira, N., Watanabe, M., and Terada, N. J. Phys. Chem. C 2009, 113, 6596
25. Fuller, J., Carlin, R. T., and Osteryoung, R. A. J. Electrochem. Soc. 1997, 144, 3881
26. Castriota, M., Caruso, T., Agostino, R. G., Cazzanelli, E., Henderson, W. A., and Passerini, S. J. Phys. Chem. A 2005, 109, 92
27. Hayashi, K., Nemoto, Y., Akuto, K., and Sakurai, Y. J. Power Sources 2005, 146, 689
28. Garcia, B., Lavallée, S., Perron, G., Michot, C., and Armand, M. Electrochim. Acta 2004, 49, 4583
29. Sato, T., Maruo, T., Marukane, S., and Takagi, K. J. Power Sources 2004, 138, 253
30. Souza, R F., Padilha, J. C., Gonçalves, R. S., and Dupont, J. Electrochem. Commun. 2003, 5, 728
31. Hagiwara, R., Nohira, T., Matsumoto, K., and Tamba, Y. Electrochem. Solid States Lett. 2005, 8, A321
32. Dupont, J., de Souza, R. F., and Suarez, P. A. Z. Chem. Rev. 2002, 102, 3667
33. Noda, A., Susan, M. A. B. H., Kudo, K., Mitsushima, S., Hayamizu, K., and Watanabe, M. J. Phys. Chem. B 2003, 107, 4024
34. Bai, Y., Cao, Y., Zhang, J., Wang, M., Li, R., Wang, P., Shaik, M., Zakeeruddin, S. M., and Grätzel, M. Nature Mater. 2008, 7, 626
35. Alam, M. T., Islam, M. M., Okijima, T., and Ohsaka, T. J. Phys. Chem. C 2009, 113, 6569
36. Paynem, R. Trans. Faraday Soc. 1965, 61, 316
37. Doubova, L. M. and Trasatti, S. Condens. Matter Phys. 2001, 4, 759
38. Langkau, T. and Baltruschat, H. Electrochim. Acta 2002, 47, 1595
39. Lockett, V., Sedev, R., Ralston, J., Horne, M., and Rodopoulos, T. J. Phys. Chem. C 2008, 112, 7486
40. Grahame, D. C. J. Am. Chem. Soc. 1954, 76, 4819
41. Grahame, D. C. J. Am. Chem. Soc. 1956, 79, 2093
42. Islam, M. M., Alam, M. T., Okijima, T., and Oshaka, T. J. Phys. Chem. C 2009, 113, 3386
43. Islam, M. M., Alam, M. T., Okijima, T., and Oshaka, T. Electrochem. Commun. 2007, 9, 2370
44. Figueiredo, M., Gomes, C., Costa, R., Martis, A., Pereora, C. M., and Silva, F. Electrochim. Acta 2009, 54, 2630
45. Silva, F., Gomes, C., Figueiredo, M., Renata, C., Martins, A., and Pereira, C. M. J. Electroanal. Chem. 2008, 662, 153
46. Hills, G. and Silva, F. Can. J. Chem. 1981, 59, 1835
47. Hamelin, A., Stoicoviciu, L., and Silva, F. J. Electroanal. Chem. 1987, 229, 107
48. Caprio, D., Stafiej, J., and Borkowska, Z. J. Electroanal. Chem. 2005, 582, 41
49. Fawcett, W. R. and Borkowska, Z. J. Phys. Chem. 1983, 87, 4861
50. Lamperski, S., Outhwaite, C. W., and Bhuiyan, L. B. J. Phys. Chem. B 2009, 113, 8925
51. Lauw, Y., Horne, M. D., Rodopoulos, T., and Leermarks, F. A. M. Phys. Rev. Lett. 2009, 103, 117801
52. Trulsson, M., Algotsson, J., Forsman, J., and Woodward, C. E. J. Phys. Chem. Lett. 2010, 1, 1191
53. Fedorov, M. V., Georgi, N., and Kornyshev, A. A. Electrochem. Commun. 2010, 12, 296
54. Georgi, N., Kornyshev, A. A., and Fedorov, M. V. J. Electroanal. Chem. 2010, in press, corrected proof, doi: 10.1016/j.jelechem.2010.07.004.
55. Feng, G., Zhang, J. S., and Qiao, R. J. Phys. Chem. C 2009, 113, 4549
56. Kislenko, S. A., Samoylov, I. S., and Amirov, R. H. Phys. Chem. Chem. Phys. 2009, 11, 5584
57. Yang, L., Fishbine, B. H., Migliori, A., and Pratt, L. R. J. Am. Chem. Soc. 2009, 131, 12373
58. Pringle, J. M., Golding, J., Baranyai, K., Forsyth, C. M., Deacon, G. B., Scott, J. L., and MacFarlane, D. R. New J. Chem. 2003, 27, 1504
59. Borodin, O. J. Phys. Chem. B 2009, 113, 11463
60. Borodin, O. and Smith, G. D. J. Phys. Chem. B 2006, 110, 11481
61. Borodin, O., Gorecki, W., Smith, G. D., and Armand, M. J. Phys. Chem. B 2010, 114, 6786
62. Reed, S. K., Lanning, O. J., and Madden, P. A. J. Chem. Phys. 2007, 126 084704
63. Vatamanu, J., Borodin, O., and Smith., G. D. Phys. Chem. Chem. Phys. 2010, 12, 183
64. Siepmann, J. I. and Sprik, M. J. Chem. Phys. 1995, 102, 511
65. Heyes, D. M. Phys. Rev. B: Condens. Matter 1994, 49, 755
66. Parry, D. E. Surf. Sci. 1975, 49, 433
67. Heyes, D. M., Barber, M., and Clarke, J. H. R. J. Chem. Soc., Faraday Trans. 2 1977, 73, 148
68. Heyes, D. M. J. Phys. Chem. Solids 1980, 41, 291
69. Heyes, D. M. and van Swol, F. J. Chem. Phys. 1981, 75, 5051
70. Heyes, D. M. J. Chem. Phys. 1983, 79, 4010
71. Heyes, D. M. Phys. Rev. B: Condens. Matter 1984, 30, 2182
72. Kawata, M. and Mikami, M. Chem. Phys. Lett. 2001, 340, 157
73. Kawata, M. and Nagashima, U. Chem. Phys. Lett. 2001, 340, 165
74. Kawata, M., Mikami, M., and Nagashima, U. J. Chem. Phys. 2002, 116, 3430
75. Kawata, M., Mikami, M., and Nagashima, U. J. Chem. Phys. 2002, 117, 3526
76. Kawata, M., Mikami, M., and Nagashima, U. J. Chem. Phys. 2001, 115, 4457
77. Tuckerman, X. M. E., Berne, B. J., and Martyna, G. J. J. Chem. Phys. 1990, 97, 1990
78. Alam, M. T., Islam, M., Okajima, T., and Ohsaka, T. J. Phys. Chem. C 2008, 112, 16600
79. Islam, M., Alam, M. T., and Ohsaka, T. J. Phys. Chem. C 2008, 112, 16568
80. Locket, V., Sedev, R., Ralston, J., Horne, M., and Rodopoulos, T. J. Phys. Chem. C 2008, 112, 7486
81. Alam, M. T., Islam, Md. M., Okijima, T., and Ohsaka, T. J. Phys. Chem. C 2007, 111, 18326
82. Kisza, A. Electrochim. Acta 2006, 51, 2315
83. Boda, D., Henderson, D., and Chan, K.-Y. J. Chem. Phys. 1999, 110, 5346
84. Bhuiyan, L. B., Outhwaite, C. W., and Henderson, D. J. Chem. Phys. 2005, 123, 34704
85. Reszko-Zygmunt, J. and Sokolowski, S. J. Chem. Phys. 2005, 123, 16101
86. Holovsko, M., Kapko, V., Henderson, D., and Boda, D. Chem. Phys. Lett. 2001, 341, 363
87. Reszko-Zygmunt, J., Sokolowski, S., Henderson, D., and Boda, D. J. Chem. Phys. 2005, 122, 84504
88. Desai, T. G. J. Chem. Phys. 2007, 127, 154707
89. Baldelli, S. Acc. Chem. Res. 2008, 41, 421
90. Nanbu, N., Sasaki, Y., and Kitamura, F. Electrochem. Commun. 2003, 5, 383
91. Nanbu, N., Kato, T., Sasaki, Y., and Kitamura, F. Electrochemistry 2005, 73, 610
92. Smith, G. D., Borodin, O., Russo, S. P., Rees, R. J., and Hollenkamp, A. F. Phys. Chem. Chem. Phys. 2009, 11, 9884
93. 0.5, is equivalent to the conservation of electric charge for saturated surfaces.
94. Fedorov, M. V. and Kornyshev, A. A. Electrochim. Acta 2008, 53, 6835
95. We concentrated on the limiting behavior of DC for positive electrode potentials because more data points are available for the electrode potential beyond double-layer saturation compared to the negative electrode.