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1H NMR spectra is not reliable, because of the very broad peak of 1 at the temperatures at which it is present during this reaction.
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1H NMR spectra is not reliable, because of the very broad peak of 1 at the temperatures at which it is present during this reaction.
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The dataset for the Arrhenius fitting is limited because of the narrow working temperature range of 2. In fact, for T<298 K the rate is too low for the reaction to be monitored in a reasonable timescale, whereas at T>310 K the reaction is too fast, and it is impossible to collect the first experimental points accurately (and these are the most critical figures in an initial rate experiment).
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The dataset for the Arrhenius fitting is limited because of the narrow working temperature range of 2. In fact, for T<298 K the rate is too low for the reaction to be monitored in a reasonable timescale, whereas at T>310 K the reaction is too fast, and it is impossible to collect the first experimental points accurately (and these are the most critical figures in an initial rate experiment).
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