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Investigation of AB dehydrogenation activity with Fe and Ni phosphine complexes shows extensive precipitation of black inactive solids and formation of phosphine-borane see Figures S1 and S2
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Investigation of AB dehydrogenation activity with Fe and Ni phosphine complexes shows extensive precipitation of black inactive solids and formation of phosphine-borane (see Figures S1 and S2).
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13
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0001285636
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2 using Enders' carbene, isolated solid was only ca. 90% pure and very air sensitive so catalysts were generated in situ.
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2 using Enders' carbene, isolated solid was only ca. 90% pure and very air sensitive so catalysts were generated in situ.
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14
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33847245266
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In parallel experiments with and without added mercury, no difference in rate, selectivity, or extent of AB dehydrogenation was observed
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In parallel experiments with and without added mercury, no difference in rate, selectivity, or extent of AB dehydrogenation was observed.
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3 using a Cu-NHC catalyst in Supporting Information (Figure S3).
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3 using a Cu-NHC catalyst in Supporting Information (Figure S3).
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