Catalyzed dehydrogenation of amnionia-borane by iridium dihydrogen pincer complex differs from ethane dehydrogenation

Angewandte Chemie - International Edition

Volumn 46, Issue 43, 2007, Pages 8153-8156

  Paul, Ankan ^a   Musgrave, Charles B ^a  

^a Stanford University   (United States)

Author keywords

Ammonia borane; Dehydrogenation; Density functional calculations; Hydrogen storage; Iridium

Indexed keywords

CATALYSIS; DEHYDROGENATION; DENSITY FUNCTIONAL THEORY; DESIGN FOR TESTABILITY; ETHANE; HYDRIDES; HYDROGEN STORAGE; IRIDIUM;

DIHYDROGEN PINCER COMPLEX; IRIDIUM PINCER COMPLEXES;

AMMONIA;

EID: 36049047625     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200702886     Document Type: Article

References (28)

1. a) The Hydrogen Economy: NRC and NAE, The National Academies Press, Washington, DC, 2004;
2. b) The Hydrogen Initiative; http://www.aps.org/public_affairs/index.cfm; The American Physical Society, 2004;
3. c) Basic Research Needs for the Hydrogen Economy; http://www.sc.doe.gov/ bes/reports/files/NHE_rpt.pdf; Office of Science at the U.S. DOE, 2004.
4. C. A. Jaska, K. Temple, A. J. Lough, I. Manners, J. Am. Chem. Soc. 2003, 125, 9424-9434.
5. C. A. Jaska, I. Manners, J. Am. Chem. Soc. 2004, 126, 9776-9785.
6. Y. Chen, J. L. Fulton, J. C. Linehan, T. Autrey, J. Am. Chem. Soc. 2005, 127, 3254-3255.
7. F. H. Stephens, R. T. Baker, M. H. Matus, D. J. Grant. D. A. Dixon, Angew. Chem. 2007, 119, 760-763;
8. Angew. Chem. Int. Ed. 2007, 46, 746-749.
9. M. C. Denney, V. Pons. T. J. Hebden, D. M. Heinekey, K. I. Goldberg, J. Am. Chem. Soc. 2006, 128, 12048-12049.
10. R. J. Keaton, J. M. Blacquiere, R. T. Baker, J. Am. Chem. Soc. 2007, 129, 1844-1845.
11. T. J. Clark, K. Lee, I. Manners, Chem. Eur. J. 2006, 12, 8634-8648.
12. M. E. Bluhm, M. G. Bradley, R. Butterick, U. Kusari, L. G. Sneddon, J. Am. Chem. Soc. 2006, 128, 7748-7749.
13. K. Zhu, P. D. Achord, X. Zhang, K. Krogh-Jespersen, A. S. Goldman, J. Am. Chem. Soc. 2004, 126, 13044-13053.
14. K. Krogh-Jespersen, M. Czerw, K. Zhu, B. Singh, M. Kanzelberger, N. Darji, P. D. Achord, K. B. Renkema, A. S. Goldman, J. Am. Chem. Soc. 2002, 124, 10797-10809.
15. K. Krogh-Jespersen, M. Czerw, M. Kanzelberger, A. S. Goldman, J. Chem. Inf. Comput. Sci. 2001, 41, 56-63.
16. K. Krogh-Jespersen, M. Czerw. N. Summa, K. B. Renkema, P. D. Achord, A. S. Goldman, J. Am. Chem. Soc. 2002, 124, 11404-11416.
17. I. Gottker-Schnetmann, P. S. White. M. Brookhart, J. Am. Chem. Soc. 2004, 126, 1804-1811.
18. I. Gottker-Schnetmann, P. S. White, M. Brookhart, Organometallics 2004, 23, 1766-1776.
19. A. S. Goldman, A. H. Roy, Z. Huang, R. Ahuja, W. Schinski, M. Brookhart, Science 2006, 312, 257-261.
20. S. Li, M. B. Hall, Organometallics 2001, 20, 2153-2160.
21. S. Niu, M. B. Hall, J. Am. Chem. Soc. 1999, 121, 3992-3999.
22. Gaussian 03, revision C.02, M.J. Frisch, etal. (see Supporting Information, Gaussian, Inc., Wallingford, CT, 2004.
23. M. Cossi, N. Rega, G. Scalmani, V. Barone, J. Comput. Chem. 2003, 24, 669-681.
24. I. Gottker-Schnetmann, D. M. Heinekey, M. Brookhart, J. Am. Chem. Soc. 2006, 128, 17114-17119.
25. M. Shimoi, S. Nagai, M. Ichikawa, Y. Kawano, K. Katoh, M. Uruichi, H. Ogino, J. Am. Chem. Soc. 1999, 121, 11704-11712.
26. R. T. Baker, D. W. Ovenall, J. C. Calabrese, S. A. Westcott, N. J. Taylor, I. D. Williams, T. B. Marder, J. Am. Chem. Soc. 1990, 112, 9399-9400.
27. K. W. Boddeker, S. G. Shore, R. K. Bunting, J. Am. Chem. Soc. 1966, 88, 4396-4401.
28. Y. Luo, K. Ohno, Organometallics 2007, 26, 3597-3600.