Graphene-metal oxide nanohybrids for toxic gas sensor: A review

Sensors and Actuators, B: Chemical

Volumn 221, Issue , 2015, Pages 1170-1181

  Gupta Chatterjee, Shyamasree ^a,b   Chatterjee, Somenath ^b   Ray, Ajoy K ^b   Chakraborty, Amit K ^a  

^a NATIONAL INSTITUTE OF TECHNOLOGY   (India)

^b SIKKIM MANIPAL INSTITUTE OF TECHNOLOGY   (India)

Author keywords

Carbon nanotube; Functionalization; Gas sensor; Graphene; Metal oxide; Nanocomposite; Nanohybrid; Reduced graphene oxide

Indexed keywords

BLENDING; CARBON; CARBON NANOTUBES; CHEMICAL DETECTION; CHEMICAL SENSORS; ELECTRONIC PROPERTIES; GAS DETECTORS; GAS SENSING ELECTRODES; GASES; IONIZATION OF GASES; MEDICAL APPLICATIONS; METAL NANOPARTICLES; METALLIC COMPOUNDS; METALS; MOLECULES; NANOCOMPOSITES; NANOSTRUCTURED MATERIALS; YARN;

ENVIRONMENTAL MONITORING; FUNCTIONALIZATIONS; HYBRID ARCHITECTURES; HYBRID NANOSTRUCTURES; METAL OXIDES; NANO HYBRIDS; REDUCED GRAPHENE OXIDES; SENSOR SELECTIVITY;

GRAPHENE;

EID: 84938824953     PISSN: 09254005     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.snb.2015.07.070     Document Type: Review

References (132)

1. R. Atkinson Atmospheric chemistry of VOCs and NOx Atmos. Environ. 34 2000 2063 2101
2. D. Zhang, Z. Liu, C. Li, T. Tang, X. Liu, S. Han, B. Lei, and C. Zhou Detection of NO2 down to ppb levels using individual and multiple In2O3 nanowire devices Nano Lett. 4 10 2004 1919 1924
3. L. Wang, H. Dou, Z. Lou, and T. Zhang Encapsuled nanoreactors (Au@ SnO2): A new sensing material for chemical sensors Nanoscale 5 2013 2686 2691
4. Q.M. Konopacky, T.S. Barman, B.A. Macintosh, and C. Marois Detection of carbon monoxide and water absorption lines in an exoplanet atmosphere Science 339 6126 2013 1398 1401
5. J. Yu, D. Zhao, X.L. Xu, X. Wang, and N. Zhang Study on RuO2/SnO2: Novel and active catalysts for CO and CH4 oxidation ChemCatChem 4 8 2012 1122 1132
6. X. Liu, S. Chang, H. Liu, S. Hu, D. Zhang, and H. Ning A survey on gas sensing technology Sensors 12 2012 9635 9665
7. G. Jiménez-Cadena, J. Riu, and F.X. Riusa Gas sensors based on nanostructured materials Analyst 132 2007 1083 1099
8. Y. Wang, Z. Zhou, Z. Yang, X. Chen, D. Xu, and Y. Zhang Gas sensors based on deposited single walled carbon nanotube networks for DMMP detection Nanotechnology 20 34 2009 345502 (8pp)
9. Y. Wang, Z. Yang, Z. Hou, D. Xu, L. Wei, E. Siu-Wai Kong, and Y. Zhang Flexible gas sensors with assembled carbon nanotube thin films for DMMP vapor detection Sens. Actuators B 150 2 2010 708 714
10. Y. Wang, N. Hu, Z. Zhou, D. Xu, Z. Wang, Z. Yang, H. Wei, E. Siu-Wai Kong, and Y. Zhang Single walled carbon nanotube/cobalt phthalocyanine derivative hybrid material: Preparation, characterization and its gas sensing properties J. Mater. Chem. 21 11 2011 3779 3787
11. B.K. Miremadi, and K. Colbow A hydrogen selective gas sensor from highly oriented films of carbon, obtained by fracturing of charcoal Sens. Actuators B 46 1998 30 34
12. G. Lu, K. Yu, L.E. Ocola, and J. Chen Ultrafast room temperature NH3 sensing with positively gated reduced graphene oxide field-effect transistors Chem. Commun. 47 27 2011 7761 7763
13. X. Huang, N. Hu, R. Gao, Y. Yu, Y. Wang, Z. Yang, E. Siu-Wai Kong, H. Wei, and Y. Zhang Reduced graphene oxide/polyaniline hybrid: Preparation, characterization and its applications for ammonia gas sensing, J. Mater. Chem. 22 42 2012 22488 22495
14. P.A. Russo, N. Donato, S.G. Leonardi, S. Baek, D.E. Conte, G. Neri, and N. Pinna Room-temperature hydrogen sensing with heteronanostructures based on reduced graphene oxide and tin oxide Angew. Chem. Int. Ed. 51 44 2012 11053 11057
15. N. Hu, Y. Wang, J. Chai, R. Gao, Z. Yang, E. Siu-Wai Kong, and Y. Zhang Gas sensor based on p-phenylenediamine reduced graphene oxide Sens. Actuators B 163 1 2012 107 114
16. N. Hu, Z. Yang, Y. Wang, L. Zhang, Y. Wang, X. Huang, H. Wei, L. Wei, and Y. Zhang Ultrafast and sensitive room temperature NH3 gas sensors based on chemically reduced graphene oxide Nanotechnology 25 2013 025502
17. F. Niu, J.-M. Liu, L.-M. Tao, W. Wang, and W.-G. Song Nitrogen and silica codoped graphene nanosheets for NO2 gas sensing J. Mater. Chem. A 1 2013 6130 6133
18. Y. Lu, B.R. Goldsmith, N.J. Kybert, and A.T.C. Johnson DNA decorated graphene chemical sensors Appl. Phys. Lett. 97 8 2010 083107 (1-3)
19. A. Gutés, B. Hsia, A. Sussman, W. Mickelson, A. Zettl, C. Carraro, and R. Maboudian Graphene decoration with metal nanoparticles: Towards easy integration for sensing applications Nanoscale 4 2 2012 438 440
20. R.K. Paul, S. Badhulika, N.M. Saucedo, and A. Mulchandani Graphene nanomesh as highly sensitive chemiresistor gas sensor Anal. Chem. 84 19 2012 8171 8178
21. A. Salehi-Khojin, D. Estrada, K.Y. Lin, M.-H. Bae, F. Xiong, E. Pop, and R.I. Masel Polycrystalline graphene ribbons as chemiresistors Adv. Mater. 24 2012 53 57
22. F. Schedin, A.K. Geim, S.V. Morozov, E.W. Hill, P. Blake, M.I. Katsnelson, and K.S. Novoselov Detection of individual gas molecules adsorbed on graphene Nat. Mater. 6 2007 652 655
23. K.R. Ratinac, W. Yang, S.P. Ringer, and F. Braet Toward ubiquitous environmental gas sensors - Capitalizing on the promise of graphene Environ. Sci. Technol. 44 4 2010 1167 1176
24. K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, M.I. Katsnelson, V. Grigorieva, S.V. Dubonos, and A.A. Firsov Electric field effect in atomically thin carbon films Science 306 5696 2004 666 669
25. M. Segal Selling graphene by the ton Nat. Nanotechnol. 4 2009 612 614
26. Y.M. Lin, and P. Avouris Strong suppression of electrical noise in bilayer graphene nanodevices Nano Lett. 8 8 2008 2119 2125
27. E.W. Hill, A. Vijayaragahvan, and K. Novoselov Graphene sensors IEEE Sens. J. 11 12 2011 3161 3170
28. T.J. Booth, P. Blake, R.R. Nair, D. Jiang, E.W. Hill, U. Bangert, A. Bleloch, M. Gass, K.S. Novoselov, M.I. Katsnelson, and A.K. Geim Macroscopic graphene membranes and their extraordinary stiffness Nano Lett. 8 2008 2442 2448
29. S.K. Pati, T. Enoki, and C.N.R. Rao Graphene and Its Fascinating Attributes 2011 World Scientific Publishing Co Pte. Ltd. Singapore
30. M. Pumera, A. Ambrosi, A. Bonanni, E.L.K. Chng, and H.L. Poh Graphene for electrochemical sensing and biosensing TrAC Trends Anal. Chem. 29 9 2010 954 965
31. K.T. Lam, D. Seah, S.K. Chin, S.B. Kumar, G. Samudra, Y.C. Yeo, and G. Liang A simulation study of graphene-nanoribbon tunneling FET with heterojunction channel IEEE Electron. Device Lett. 31 2010 555 557
32. X. Li, X. Wang, L. Zhang, S. Lee, and H. Dai Chemically derived, ultrasmooth graphene nanoribbon semiconductors Science 319 5867 2008 1229 1232
33. C. Wang, L. Yin, L. Zhang, D. Xiang, and R. Gao Metal oxide gas sensors: Sensitivity and influencing factors Sensors 10 2010 2088 2106
34. N. Barsan, and U. Weimar Understanding the fundamental principles of metal oxide based gas sensors; the example of CO sensing with SnO2 sensors in the presence of humidity J. Phys. Condens. Matter 15 2003 R813 R839
35. A. Lassesson, M. Schulze, J. van Lith, and S.A. Brown Tin oxide nanocluster hydrogen and ammonia sensors Nanotechnology 19 2008 015502
36. F. Gyger, M. Hubner, C. Feldmann, N. Barsan, and U. Weimar Nanoscale SnO2 hollow spheres and their application as a gas-sensing material Chem. Mater. 22 2010 4821 4827
37. X.M. Yin, C.C. Li, M. Zhang, Q.Y. Hao, S. Liu, Q.H. Li, L.B. Chen, and T.H. Wang SnO2 monolayer porous hollow spheres as a gas sensor Nanotechnology 20 2009 455503
38. Z.W. Chen, D.Y. Pan, B. Zhao, G.J. Ding, Z. Jiao, M.H. Wu, C.H. Shek, L.C.M. Wu, and J.K.L. Lai Insight on fractal assessment strategies for tin dioxide thin films ACS Nano 4 2010 1202 1208
39. G.K. Fan, Y. Wang, M. Hu, Z.Y. Luo, and G. Li Synthesis of flowerlike nano-SnO2 and a study of its gas sensing response Measur. Sci. Technol. 22 2011 045203
40. A. Gurlo Nanosensors: Towards morphological control of gas sensing activity. SnO2, In2O3, ZnO and WO3 case studies Nanoscale 3 2011 154 165
41. J. Yi, J.M. Lee, and W. Park Vertically aligned ZnO nanorods and graphene hybrid architectures for high-sensitive flexible gas sensors Sens. Actuators B 155 2011 264 269
42. G. Singh, A. Choudhary, D. Haranath, A.G. Joshi, N. Singh, S. Singh, and R. Pasricha ZnO decorated luminescent graphene as a potential gas sensor at room temperature Carbon 50 2012 385 394
43. S.J. Sun, and C.Y. Lin Hybrid-graphene gas sensor - Model simulation Europhys. Lett. 96 2011 10002 10006
44. T.V. Cuong, V.H. Pham, J.S. Chung, E.W. Shin, D.H. Yoo, S.H. Hahn, J.S. Huh, G.H. Rue, E.J. Kim, S.H. Hur, and P.A. Kohl Solution-processed ZnO chemically converted graphene gas sensor Mater. Lett. 64 2010 2479 2482
45. Z.Y. Zhang, R.J. Zou, G.S. Song, L. Yu, Z.G. Chen, and J.Q. Hu Highly aligned SnO2 nanorods on graphene sheets for gas sensors J. Mater. Chem. 21 2011 17360 17365
46. S. Deng, V. Tjoa, H.M. Fan, H.R. Tan, D.C. Sayle, M. Olivo, S. Mhaisalkar, J. Wei, and C.H. Sow Reduced graphene oxide conjugated Cu2O nanowire meso-crystals for high-performance NO2 gas sensor J. Am. Chem. Soc. 134 2012 4905 4917
47. I. Jung, D.A. Dikin, R.D. Piner, and R.S. Ruoff Tunable electrical conductivity of individual graphene oxide sheets reduced at "low" temperatures Nano Lett. 8 12 2008 4283 4287
48. W. Choi, I. Lahiri, R. Seelaboyina, and Y.S. Kang Synthesis of graphene and its applications: A review Crit. Rev. Solid State Mater. Sci. 35 2010 52 71
49. S. Basu, and S. Bhattacharya Recent developments on graphene and graphene oxide based solid state gas sensors Sens. Actuators B 173 2012 1 21
50. V. Singh, D. Joung, L. Zhai, S. Das, S.I. Khondaker, and S. Seal Graphene based materials: Past, present and future Prog. Mater. Sci. 56 2011 1178 1271
51. A.K. Ray, R.K. Sahu, V. Rajinikanth, H. Bapari, M. Ghosh, and P. Paul Preparation and characterization of graphene and Ni-decorated graphene using flower petals as the precursor material Carbon 50 2012 4123 4129
52. A.K. Ray, S. Chatterjee, J.K. Singh, and H. Bapari Thermal exfoliation of natural cellulosic material for graphene synthesis J. Mater. Eng. Performance 24 2015 80 84
53. A.K. Chakraborty, C. Anderson, J. Jacobs, C. Roberts, and M.R.C. Hunt CVD growth of carbon nanotubes on Si substrate using Fe catalyst: What happens at nanotube/Fe/Si interface J. Appl. Phys. 100 2006 084321
54. A.K. Chakraborty, R.A.J. Woolley, Y.V. Butenko, L. Siller, V.R. Dhanak, and M.R.C. Hunt Ion irradiation induced defects in carbon nanotubes: A photoelectron spectroscopy study Carbon 45 2007 2744
55. A.K. Chakraborty, V.R. Dhanak, and K.S. Coleman Electronic fine structure of 4-nitrophenyl functionalized SWCNTs Nanotechnology 20 2009 155704
56. A. Suri, A.K. Chakraborty, and K.S. Coleman A facile, solvent-free, non-covalent, and non-disruptive route to functionalize single-wall carbon nanotubes by tertiary phosphines Chem. Mater. 20 2008 1705
57. K.S. Coleman, A.K. Chakraborty, S.R. Bailey, J. Sloan, and M. Alexander Iodination of single walled carbon nanotubes Chem. Mater. 19 2007 1076
58. R.K. Agrawalla, S. Paul, P.K. Sahoo, A.K. Chakraborty, and A.K. Mitra A facile synthesis of a novel 3-phase nanocomposite: Single wall carbon nanotube/silver nanohybrid fibres embedded in sulfonated polyaniline J. Appl. Polym. Sci. 132 2015 41692
59. V. Meriga, V. Sreeramulu, S. Sundaresan, C. Cahill, V.R. Dhanak, and A.K. Chakraborty Optical, electrical and electrochemical properties of graphene based water soluble polyaniline composites J. Appl. Polym. Sci. 2015 (in press)
60. W. Yuan, and G. Shi Graphene-based gas sensors J. Mater. Chem. A 1 2013 10078 10091
61. T.A. Miller, S.D. Bakrania, C. Perez, and M.S. Wooldridge Nanostructured tin dioxide materials for gas sensor applications K.E. Geckeler, E. Rosenberg, Functional Nanomaterials 2006 American Scientific Publishers Valencia, USA 1 24
62. S. Mao, S. Cui, G. Lu, K. Yu, Z. Wen, and J. Chen Tuning gas-sensing properties of reduced graphene oxide using tin oxide nanocrystals J. Mater. Chem. 22 2012 11009 11013
63. G. Lu, L.E. Ocola, and J. Chen Room-temperature gas sensing based on electron transfer between discrete tin oxide nanocrystals and multiwalled carbon nanotubes Adv. Mater. 21 24 2009 2487 2491
64. G. Neri, S.G. Leonardi, M. Latino, N. Donato, S. Baek, D.E. Conte, P.A. Russo, and N. Pinna Sensing behavior of SnO2/reduced graphene oxide nanocomposites toward NO2 Sens. Actuators B 179 2013 61 68
65. H. Zhang, J. Feng, T. Fei, S. Liu, and T. Zhang SnO2 nanoparticles-reduced graphene oxide nanocomposites for NO2 sensing at low operating temperature Sens. Actuators B 190 2014 472 478
66. S. Cui, Z. Wen, E.C. Mattson, S. Mao, J. Chang, M. Weinert, C.J. Hirschmugl, M. Gajdardziska-Josifovskab, and J. Chen Indium-doped SnO2 nanoparticle-graphene nanohybrids: Simple one-pot synthesis and their selective detection of NO2 J. Mater. Chem. A 1 2013 4462 4467
67. Q. Lin, Y. Li, and M. Yang Tin oxide/graphene composite fabricated via a hydrothermal method for gas sensors working at room temperature Sens. Actuators B 173 2012 139 147
68. J.-Q. He, J. Yin, D. Liu, L.-X. Zhang, F.-S. Cai, and L.-J. Bie Enhanced acetone gas-sensing performance of La2O3-doped flowerlike ZnO structure composed of nanorods Sens. Actuators B 182 2013 170 175
69. C.W. Na, S.Y. Park, and J.H. Lee Punched ZnO nanobelt networks for highly sensitive gas sensors Sens. Actuators B 174 2012 495 499
70. S. Liu, B. Yu, H. Zhang, T. Fei, and T. Zhang Enhancing NO2 gas sensing performances at room temperature based on reduced graphene oxide-ZnO nanoparticles hybrids Sens. Actuators B 202 2014 272 278
71. J. Su, L. Guo, N. Bao, and C.A. Grimes Nanostructured WO3/BiVO4 heterojunction films for efficient photoelectrochemical water splitting Nano Lett. 11 5 2011 1928 1933
72. E. Rossinyol, A. Prim, E. Pellicer, J. Arbiol, F. Hernandez-Ramirez, F. Peiro, A. Cornet, J. Morante, L. Solovyov, B. Tian, T. Bo, and D. Zhao Synthesis and characterization of chromium-doped mesoporous tungsten oxide for gas sensing applications Adv. Funct. Mater. 17 2007 1801
73. S. Srivastava, K. Jain, V.N. Singh, S. Singh, N. Vijayan, N. Dilawar, G. Gupta, and T.D. Senguttuvan Faster response of NO2 sensing in graphene-WO3 nanocomposites Nanotechnology 23 2012 205501 (7pp)
74. X. An, J.C. Yu, Y. Wang, Y. Hu, X. Yu, and G. Zhang WO3 nanorods/graphene nanocomposites for high-efficiency visible-light-driven photocatalysis and NO2 gas sensing J. Mater. Chem. 22 2012 8525 8531
75. A. Esfandiar, A. Irajizad, O. Akhavan, S. Ghasemi, and M.R. Gholami Pd-WO3/reduced graphene oxide hierarchical nanostructures as efficient hydrogen gas sensors Int. J. Hydrogen Energy 39 2014 8169 8179
76. L. Zhou, F. Shen, X. Tian, D. Wang, T. Zhang, and W. Chen Stable Cu2O nano-crystals grown on functionalized graphene sheets and room temperature H2S gas sensing with ultrahigh sensitivity Nanoscale 5 2013 1564 1569
77. H. Yamaura, K. Moriy, N. Miura, and N. Yamazoe Mechanism of sensitivity promotion in CO sensor using indium oxide and cobalt oxide Sens. Actuators B 65 2000 39 41
78. J. Wollenstein, M. Burgmair, G. Plescher, T. Sulima, J. Hildenbrand, H. Bottner, and I. Eisele Cobalt oxide based gas sensors on silicon substrate for operation at low temperatures Sens. Actuators B 93 2003 442 448
79. S.D. Choi, and B.K. Min Co3O4-based isobutane sensor operating at low temperatures Sens. Actuators B 77 2000 330 333
80. U.S. Choi, G. Sakai, K. Shimanoe, and N. Yamazoe Sensing properties of SnO2-Co3O4 composites to CO and H2 Sens. Actuators B 98 2004 166 173
81. A.M. Cao, J.S. Hu, H.P. Liang, W.G. Song, L.J. Wan, X.L. He, X.G. Gao, and S.H. Xia Hierarchically structured cobalt oxide (Co3O4): The morphology control and its potential in sensors J. Phys. Chem. B 110 2006 15858 15863
82. N. Chen, X. Li, X. Wang, J. Yu, J. Wang, Z. Tang, and S.A. Akbar Enhanced room temperature sensing of Co3O4-intercalated reduced graphene oxide based gas sensors Sens. Actuators B 188 2013 902 908
83. M.H. Seo, M. Yuasa, T. Kida, J.S. Huh, K. Shimanoe, and N. Yamazoe Gas sensing characteristics and porosity control of nanostructured films composed of TiO2 nanotubes Sens. Actuators B 137 2009 513 520
84. J.H. Lee Gas sensors using hierarchical and hollow oxide nanostructures: Overview Sens. Actuators B 140 2009 319 336
85. M. Tiemann Porous metal oxides as gas sensors Chem. Eur. J. 13 2007 8376 8388
86. Y. Shimizu, T. Hyodo, and M. Egashira Meso- to macro-porous oxides as semiconductor gas sensors Catal. Surveys Asia 8 493 2004 127 135
87. Y.Y. Liang, Y.G. Li, H.L. Wang, J.G. Zhou, J. Wang, T. Regier, and H.J. Dai Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction Nat. Mater. 10 2011 780 786
88. F. Schedin, A.K. Geim, S.V. Morozov, E.W. Hill, P. Blake, and M.I. Katsnelson Detection of individual gas molecules adsorbed on graphene Nat. Mater. 6 2007 652 655
89. J.T. Robinson, F.K. Perkins, E.S. Snow, Z.Q. Wei, and P.E. Sheehan Reduced graphene oxide molecular sensors Nano Lett. 8 10 2008 3137 3140
90. S.-J. Choi, W.-H. Ryu, S.-J. Kim, H.-J. Cho, and II-Doo Kim Bi-functional co-sensitization of graphene oxide sheets and Ir nanoparticles on p-type Co3O4 nanofibers for selective acetone detection J. Mater. Chem. B 2 2014 7160 7167
91. L.T. Hoa, H.N. Tien, V.H. Luan, J.S. Chung, and S.H. Hur Fabrication of a novel 2D-graphene/2D-NiO nanosheet-based hybrid nanostructure and its use in highly sensitive NO2 sensors Sens. Actuators B 185 2013 701 705
92. F. Gu, R. Nie, D. Han, and Z. Wang In2O3-graphene nanocomposite based gas sensor for selective detection of NO2 at room temperature Sens. Actuators B 219 2015 94 99
93. S. Bai, C. Chen, R. Luo, A. Chen, and D. Li Synthesis of MoO3/reduced graphene oxide hybrids and mechanism of enhancing H2S sensing performances Sens. Actuators B 216 2015 113 120
94. V.V. Quang, N.V. Dung, N.S. Trong, N.D. Hoa, N.V. Duy, and N.V. Hieu Outstanding gas-sensing performance of graphene/SnO2 nanowire Schottky junctions Appl. Phys. Lett. 105 2014 013107
95. S. Liu, Z. Wang, Y. Zhang, C. Zhang, and T. Zhang High performance room temperature NO2 sensors based on reduced graphene oxide-multiwalled carbon nanotubes-tin oxide nanoparticles hybrids Sens. Actuators B 211 2015 318 324
96. J.-H. Lee, A. Katoch, S.-W. Choi, J.-H. Kim, H.W. Kim, and S.S. Kim Extraordinary improvement of gas-sensing performances in SnO2 nanofibers due to creation of local p-n heterojunctions by loading reduced graphene oxide nanosheets ACS Appl. Mater. Interface 7 2015 3101 3109
97. Y. Chang, Y. Yao, B. Wang, H. Luo, T. Li, and L. Zhi Reduced graphene oxide mediated SnO2 nanocrystals for enhanced gas-sensing properties J. Mater. Sci. Technol. 29 2 2013 157 160
98. Z. Ye, Y. Jiang, H. Tai, N. Guo, G. Xie, and Z. Yuan The investigation of reduced graphene oxide@ SnO2-polyaniline composite thin films for ammonia detection at room temperature Mater. Sci.: Mater. Electron. 26 2015 833 841
99. Z. Zhang, R. Zou, G. Song, L. Yu, Z. Chen, and J. Hu Highly aligned SnO2 nanorods on graphene sheets for gas sensors J. Mater. Chem. 21 2011 17360 17365
100. H. Zhang, L. Wang, and T. Zhang Reduced graphite oxide/SnO2/Au hybrid nanomaterials for NO2 sensing performance at relatively low operating temperature RSC Adv. 4 2014 57436 57441
101. K. Inyawilert, A. Wisitsoraat, C. Sriprachaubwong, A. Tuantranont, S. Phanichphant, and C. Liewhiran Rapid ethanol sensor based on electrolytically-exfoliated graphene-loaded flame-made In-doped SnO2 composite film Sens. Actuators B 209 2015 40 55
102. D. Zhang, J. Liu, H. Chang, A. Liu, and B. Xia Characterization of a hybrid composite of SnO2 nanocrystal-decorated reduced graphene oxide for ppm-level ethanol gas sensing application RSC Adv. 5 2015 18666 18672
103. D. Zhang, A. Liu, H. Chang, and B. Xia Room-temperature high-performance acetone gas sensor based on hydrothermal synthesized SnO2-reduced graphene oxide hybrid composite RSC Adv. 5 2015 3016 3022
104. A.S.M.I. Uddin, K.-W. Lee, and G.-S. Chung Acetylene gas sensing properties of an Ag-loaded hierarchical ZnO nanostructure-decorated reduced graphene oxide hybrid Sens. Actuators B 216 2015 33 40
105. A.S.M.I. Uddin, D.-T. Phan, and G.-S. Chung Low temperature acetylene gas sensor based on Ag nanoparticles-loaded ZnO-reduced graphene oxide hybrid Sens. Actuators B 207 2015 362 369
106. N. Song, H. Fan, and H. Tian PVP assisted in situ synthesis of functionalized graphene/ZnO (FGZnO) nanohybrids with enhanced gas-sensing property J. Mater. Sci. 50 2015 2229 2238
107. R.J. Zou, G.J. He, K.B. Xu, Q. Liu, Z.Y. Zhang, and J.Q. Hu ZnO nanorods on reduced graphene sheets with excellent field emission, gas sensor and photocatalytic properties J. Mater. Chem. A 1 2013 8445 8452
108. Y.J. Yang, X.J. Yang, W.Y. Yang, S.B. Li, J.H. Xu, and Y.D. Jiang Porous conducting polymer and reduced graphene oxide nanocomposites for room temperature gas detection RSC Adv. 4 2014 42546 42553
109. X. Liu, J. Sun, and X. Zhang Novel 3D graphene aerogel-ZnO composites as efficient detection for NO2 at room temperature Sens. Actuators B 211 2015 220 226
110. K. Anand, O. Singh, M. Pal Singh, J. Kaur, and R.C. Singh Hydrogen sensor based on graphene/ZnO nanocomposite Sens. Actuators B 195 2014 409 415
111. N. Kumar, A.K. Srivastava, H.S. Patel, B.K. Gupta, and G. Das Varma Facile synthesis of ZnO-reduced graphene oxide, nanocomposites for NO2 gas sensing applications Eur. J. Inorg. Chem. 2015 2015 1912 1923
112. T.V. Cuong, V.H. Pham, J.S. Chung, E.W. Shin, D.H. Yoo, S.H. Hahn, J.S. Huh, G.H. Rue, E.J. Kim, S.H. Hur, and P.A. Kohl Solution-processed ZnO-chemically converted graphene gas sensor Mater. Lett. 64 2010 2479 2482
113. J. Qin, M. Cao, N. Li, and C. Hu Graphene-wrapped WO3 nanoparticles with improved performances in electrical conductivity and gas sensing properties J. Mater. Chem. 21 2011 17167 17171
114. Pi-Guey Su, and Shih-Liang Peng Fabrication NO2 gas-sensing properties of reduced graphene oxide/WO3 nanocomposite films Talanta 132 2015 398 405
115. A. Esfandiar, A. Irajizad, O. Akhavan, S. Ghasemi, and M.R. Gholami Pd-WO3/reduced graphene oxide hierarchical nanostructures as efficient hydrogen gas sensors Int. J. Hydrogen Energy 39 2014 8169 8179
116. H. Meng, W. Yang, K. Ding, L. Feng, and Y. Guan Cu2O nanorods modified by reduced graphene oxide for NH3 sensing at room temperature J. Mater. Chem. A 3 2015 1174 1181
117. G. Konvalina, and H. Haick Sensors for breath testing: From nanomaterials to comprehensive disease detection Acc. Chem. Res. 47 2014 66 76
118. G. Konvalina, and H. Haick Effect of humidity on nanoparticle-based chemiresistors: A comparison between synthetic and real-world samples ACS Appl. Mater. Interface 4 1 2012 317 325
119. P.-G. Su, W.-L. Shiu, and M.-S. Tsai Flexible humidity sensor based on Au nanoparticles/graphene oxide/thiolated silica sol-gel film Sens. Actuators B 216 2015 467 475
120. N. Li, X.-D. Chen, X.-P. Chen, X. Ding, and X.-Y. Li Subsecond response of humidity sensor based on graphene oxide, quantum dots IEEE Electron. Dev. Lett. 36 2015 615 617
121. V. Ruiz, I. Fernández, P. Carrasco, G. Cabañero, H.J. Grande, and J. Herrán Graphene quantum dots as a novel sensing material for low-cost resistive and fast-response humidity sensors Sens. Actuators B 218 2015 73 77
122. D. Zhang, J. Tong, and B. Xia Humidity-sensing properties of chemically reduced graphene oxide/polymer nanocomposite film sensor based on layer-by-layer nano self-assembly Sens. Actuators B 197 2014 66 72
123. D. Zhang, J. Tong, B. Xia, and Q. Xue Ultrahigh performance humidity sensor based on layer-by-layer self-assembly of graphene oxide/polyelectrolyte nanocomposite film Sens. Actuators B 203 2014 263 270
124. M.C. Chen, C.-L. Hsu, and T.-J. Hsueh Fabrication of humidity sensor based on bilayer graphene IEEE Electron. Dev. Lett. 35 2014 590 592
125. S. Borini, R. White, D. Wei, M. Astley, S. Haque, E. Spigone, N. Harris, J. Kivioja, and T. Ryhänen Ultrafast graphene oxide humidity sensors ACS Nano 7 2013 11166 11173
126. U. Tisch, and H. Haick Nanomaterials for cross-reactive sensor arrays MRS Bull. 35 2010 797 803
127. Y. Zilberman, U. Tisch, G. Shuster, W. Pisula, X. Feng, K. Müllen, and H. Haick Carbon nanotube/hexa-peri-hexabenzocoronene bilayers for discrimination between nonpolar volatile organic compounds of cancer and humid atmospheres Adv. Mater. 22 2010 4317 4320
128. C.-H. Kim, S.-W. Yoo, D.-W. Nam, S. Seo, and J.-H. Lee Effect of temperature and humidity on NO2 and NH3 Gas sensitivity of bottom-gate graphene FETs prepared by ICP-CVD IEEE Electron. Dev. Lett. 33 2012 1084 1086
129. G. Peng, E. Trock, and H. Haick Detecting simulated patterns of lung cancer biomarkers by random network of single-walled carbon nanotubes coated with nonpolymeric organic materials Nano Lett. 8 11 2008 3631 3635
130. G. Peng, U. Tisch, and H. Haick Detection of nonpolar molecules by means of carrier scattering in random networks of carbon nanotubes: Toward diagnosis of diseases via breath samples Nano Lett. 9 4 2009 1362 1368
131. Y. Zilberman, R. Ionescu, X. Feng, K. Muellen, and H. Haick Nanoarray of polycyclic aromatic hydrocarbons and carbon nanotubes for accurate and predictive detection in real-world environmental humidity ACS Nano 5 8 2011 6743 6753
132. J.S. Cooper, M. Myers, E. Chow, L.J. Hubble, J.M. Cairney, B. Pejcic, Karl-H. Mueller, L. Wieczorek, and B. Raguse Performance of graphene, carbon nanotube, and gold nanoparticle chemiresistor sensors for the detection of petroleum hydrocarbons in water J. Nanopart. Res. 16 2014 2173 (1-13)