Dumbbell-shaped polyhedral oligomeric silsesquioxanes/polystyrene nanocomposites: The influence of the bridge rigidity on the resistance to thermal degradation

Journal of Composite Materials

Volumn 49, Issue 20, 2015, Pages 2509-2517

  Blanco, Ignazio ^a   Abate, Lorenzo ^a   Bottino, Francesco A ^a   Cicala, Gianluca ^a   Latteri, Alberta ^a  

^a UNIVERSITY OF CATANIA   (Italy)

Author keywords

Dumbbell shaped polyhedral oligomeric silsesquioxane; nanocomposites; polystyrene; thermal stability

Indexed keywords

AROMATIZATION; DIFFERENTIAL SCANNING CALORIMETRY; FILLERS; GLASS TRANSITION; NANOCOMPOSITES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLIGOMERS; POLYSTYRENES; RIGIDITY; SCANNING ELECTRON MICROSCOPY; STYRENE; THERMODYNAMIC STABILITY; THERMOGRAVIMETRIC ANALYSIS;

1H NMR SPECTROSCOPY; AGGREGATION PHENOMENA; COMPARATIVE STUDIES; DIFFERENTIAL THERMOGRAVIMETRIC; IN-SITU POLYMERIZATION; POLYHEDRAL OLIGOMERIC SILSESQUIOXANES; POLYMERIC MATRICES; THERMO-GRAVIMETRIC;

SULFUR COMPOUNDS;

EID: 84938501888     PISSN: 00219983     EISSN: 1530793X     Source Type: Journal    
DOI: 10.1177/0021998314549616     Document Type: Article

References (46)

1. Lee JH, Kim WC, Min SK,. Synthesis of poly(methyl- co -trifluoropropyl)silsesquioxanes and their thin films for low dielectric application. Macromol Mater Eng 2003; 288: 455-461.
2. Ree M, Yoon J, Heo K,. Imprinting well-controlled closed-nanopores in spin-on polymeric dielectric thin films. J Mater Chem 2006; 16: 685-697.
3. Hartmann-Thompson C, Keeley D, Pollock K,. One- and two-photon fluorescent polyhedral oligosilsesquioxane (POSS) nanosensor arrays for the remote detection of analytes in clouds, in solution, and on surfaces. Chem Mater 2008; 20: 2829-2838.
4. Hartmann-Thompson C, Merrington A, Carver PI,. Proton-conducting polyhedral oligosilsesquioxane nanoadditives for sulfonated polyphenylsulfone hydrogen fuel cell proton exchange membranes. J Appl Polym Sci 2008; 110: 958-974.
5. Zhang B, Zhang Q, Zhang H,. Preparation of diamine-POSS/Ag hybrid microspheres and its application in epoxy resin. J Polym Res 2012; 19: 9986-9993.
6. Song X, Zhou S, Wang Y,. Mechanical and electret properties of polypropylene unwoven fabrics reinforced with POSS for electret filter materials. J Polym Res 2012; 19: 9812-9819.
7. Baney RH, Itoh M, Sakakibara S,. Silsesquioxanes. Chem Rev 1995; 95: 1409-1430.
8. Wang XT, Yang YK, Yang ZF,. Thermal properties and liquid crystallinity of side-chain azobenzene copolymer containing pendant polyhedral oligomeric silsequioxanes. J Therm Anal Calorim 2010; 102: 739-744.
9. Sellinger A, Laine RM,. Silsesquioxanes as synthetic platforms. Thermally curable and photocurable inorganic/organic hybrids. Macromolecules 1996; 29: 2327-2330.
10. x (x = 6, 8, 10) octasilsesquioxanes. J Mater Chem 2005; 15: 3725-3744.
11. Cordes DB, Lickiss PD, Rataboul F,. Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes. Chem Rev 2010; 110: 2081-2173.
12. Zhang XZ, Huang YD, Wang TY,. Influence of silsesquioxane coatings on interfacial and impact properties of carbon fiber-polyarylacetylene composites. J Compos Mater 2007; 41: 1559-1577.
13. Liu L, Hu Y, Song L,. Fabrication of lamellar nanostructure from cage-like poly-anion silicate and surfactant by template-directed synthesis. J Compos Mater 2011; 45: 307-319.
14. Chandramohan A, Nagendiran S, Alagar M,. Synthesis and characterization of polyhedral oligomeric silsesquioxane-siloxane-modified polyimide hybrid nanocomposites. J Compos Mater 2012; 46: 773-781.
15. Zhang M-M, Yan H-X, Gong C,. Hyperbranched polysiloxane functionalization of graphene oxide for improved mechanical properties of cyanate ester nanocomposites. J Compos Mater. 2015; 49: 939-948.
16. Harrison PG,. Silicate cages: Precursors to new materials. J Organomet Chem 1997; 542: 141-183.
17. Fina A, Tabuani D, Carniato F,. Polyhedral oligomeric silsesquioxanes (POSS) thermal degradation. Thermochim Acta 2006; 440: 36-42.
18. Mather PT, Jeon HG, Haddad TS,. Strain recovery in POSS hybrid thermoplastics. Polym Prepr 2000; 41: 528-529.
19. th International SAMPE symposium and exhibition 2000; Vol 45 Covina, CA: Society for the Advancement of Material and Process Engineering (SAMPE), pp. 1921-1931.
20. Blanski RL, Phillips SH, Chaffee K,. The synthesis of hybrid materials by the blending of polyhedral oligosilsesquioxanes into organic polymers. Polym Prepr 2000; 41: 585-586.
21. Haddad TS, Stapleton R, Jeon HG,. Nanostructured hybrid organic/inorganic materials: Silsesquioxane modified plastics. Polym Prepr 1999; 40: 496-497.
22. Lee A, Lichtenhan JD,. Viscoelastic responses of polyhedral oligosilsesquioxane reinforced epoxy systems. Macromolecules 1998; 31: 4970-4974.
23. Blanco I, Abate L, Bottino FA,. Thermal degradation of differently substituted cyclopentyl polyhedral oligomeric silsesquioxane (CP-POSS) nanoparticles. J Therm Anal Calorim 2012; 107: 1083-1091.
24. Blanco I, Abate L, Bottino FA,. Hepta isobutyl polyhedral oligomeric silsesquioxanes (hib-POSS): A thermal degradation study. J Therm Anal Calorim 2012; 108: 807-815.
25. Blanco I, Abate L, Bottino FA,. Thermal degradation of hepta cyclopentyl, mono phenyl-polyhedral oligomeric silsesquioxane (hcp-POSS)/polystyrene (PS) nanocomposites. Polym Degrad Stab 2012; 97: 849-855.
26. Blanco I, Bottino FA, Bottino P,. Influence of symmetry/asymmetry of the nanoparticles structure on the thermal stability of polyhedral oligomeric silsesquioxane/polystyrene nanocomposites. Polym Compos 2012; 33: 1903-1910.
27. Blanco I, Bottino FA,. Effect of the substituents on the thermal stability of hepta cyclopentyl, phenyl substituted-polyhedral oligomeric silsesquioxane (hcp-POSS)/polystyrene (PS) nanocomposites. AIP Conf Proc 2012; 1459: 247-249.
28. Blanco I, Abate L, Antonelli ML,. Phenyl hepta cyclopentyl-polyhedral oligomeric silsesquioxane (ph,hcp-POSS)/Polystyrene (PS) nanocomposites: The influence of substituents in the phenyl group on the thermal stability. eXPRESS Polym Lett 2012; 6: 997-1006.
29. Blanco I, Bottino FA,. Thermal study on phenyl, hepta isobutyl-polyhedral oligomeric silsesquioxane/polystyrene nanocomposites. Polym Compos 2013; 34: 225-232.
30. Blanco I, Abate L, Bottino FA,. Variously substituted phenyl hepta cyclopentyl-polyhedral oligomeric silsesquioxane (ph,hcp-POSS)/polystyrene (PS) nanocomposites. J Therm Anal Calorim 2013; 112: 421-428.
31. Blanco I, Bottino FA, Cicala G,. Synthesis and characterization of differently substituted phenyl hepta isobutyl-polyhedral oligomeric silsesquioxane/polystyrene nanocomposites. Polym Compos 2014; 35: 151-157.
32. Shea KJ, Loy DA,. Bridged polysilsesquioxanes. Molecular engineered hybrid organic-inorganic materials. Chem Mater 2001; 13: 3306-3319.
33. Hu JK, Zhang QC, Gong SL,. Bridged polyhedral oligomeric silsesquioxane (POSS): A potential member of silsesquioxanes. Chin Chem Lett 2012; 23: 181-184.
34. Lee W, Ni S, Deng J,. Telechelic poly(ethylene glycol)-POSS amphiphiles at the air/water interface. Macromolecules 2007; 40: 682-688.
35. Su X, Guang S, Xu H,. Controllable preparation and optical limiting properties of POSS-based functional hybrid nanocomposites with different molecular architectures. Macromolecules 2009; 42: 8969-8976.
36. Araki H, Naka K,. Syntheses of dumbbell-shaped trifluoropropyl-substituted POSS derivatives linked by simple aliphatic chains and their optical transparent thermoplastic films. Macromolecules 2011; 44: 6039-6045.
37. Spoljaric S, Genovese A, Shanks RA,. Novel elastomer-dumbbell functionalized POSS composites: Thermomechanical and morphological properties. J Appl Polym Sci 2012; 123: 585-600.
38. Blanco I, Abate L, Bottino FA,. Synthesis and thermal properties of new dumbbell-shaped isobutyl-substituted POSSs linked by aliphatic bridges. J Therm Anal Calorim 2013; 116: 5-13.
39. Blanco I, Abate L, Bottino FA,. Synthesis, characterization and thermal stability of new dumbbell-shaped isobutyl-substituted POSSs linked by aromatic bridges. J Therm Anal Calorim 2014; 117: 243-250.
40. Blanco I, Abate L, Bottino FA,. Thermal behaviour of a series of novel aliphatic bridged polyhedral oligomeric silsesquioxanes (POSSs)/polystyrene (PS) nanocomposites: The influence of the bridge length on the resistance to thermal degradation. Polym Degrad Stab 2014; 102: 132-137.
41. Abate L, Blanco I, Cicala G,. Thermal and rheological behaviour of some random aromatic polyethersulfone/polyetherethersulfone copolymers. Polym Degrad Stab 2006; 91: 924-930.
42. Abate L, Asarisi V, Blanco I,. The influence of sulfonation degree on the thermal behaviour of sulfonated poly (arylene ethersulfone)s. Polym Degrad Stab 2010; 95: 1568-1574.
43. Abate L, Badea E, Blanco I,. Heat capacities and enthalpies of solid-solid transitions and fusion of a series of eleven primary alkylamides by differential scanning calorimetry. J Chem Eng Data 2008; 53: 959-965.
44. Della Gatta G, Richardson MJ, Sarge SM,. Standards, calibration, and guidelines in microcalorimetry. Part 2. Calibration standards for differential scanning calorimetry. Pure Appl Chem 2006; 78: 1455-1476.
45. Fina A, Monticelli O, Camino G,. POSS-based hybrids by melt/reactive blending. J Mater Chem 2010; 20: 9297-9305.
46. Carlier V, Devaux J, Lepas R,. Percentage of rigid chain length, a new concept for predicting glass transition temperatures and melting points of poly(aryl ether ketone)s and poly(aryl ether sulfone)s. Macromolecules 1992; 25: 6646-6650.