Synthesis, characterization and thermal stability of new dumbbell-shaped isobutyl-substituted POSSs linked by aromatic bridges

Journal of Thermal Analysis and Calorimetry

Volumn 117, Issue 1, 2014, Pages 243-250

  Blanco, Ignazio ^a   Abate, Lorenzo ^a   Bottino, Francesco A ^a   Bottino, Paola ^a  

^a UNIVERSITY OF CATANIA   (Italy)

Author keywords

Aromatic bridge; Corner capping reaction; Dumbbell shaped POSS; Thermal properties

Indexed keywords

AROMATIC COMPOUNDS; COMPLEXATION; NITROGEN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SILICON OXIDES; SULFUR DIOXIDE; SYNTHESIS (CHEMICAL); THERMODYNAMIC PROPERTIES;

CORNER CAPPING REACTION; DUMBBELL SHAPED POSS; H NMR SPECTRA; ISOBUTYL; MASS LOSS; POLYHEDRAL OLIGOMERIC SILSESQUIOXANES; SILICON CAGES; STATIC AIR;

AROMATIZATION;

EID: 84904461189     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-014-3641-6     Document Type: Article

References (23)

1. Harrison PG. Silicate cages: precursors to new materials. J Organomet Chem. 1997;547:141-7.
2. Pielichowski K, Njuguna J, Janowski B, Pielichowski J. Polyhedral oligomeric silsesquioxanes (POSS)-containing nanohybrid polymers. Adv Polym Sci. 2006;201:225-96.
3. Baney RH, Itoh M, Sakakibara S, Suzuki T. Silsesquioxanes. Chem Rev. 1995;95:1409-30.
4. Kickelbick G. Silsesquioxanes. Struct Bond. 2013;. doi: 10.1007/430-2013-108.
5. Fina A, Tabuani D, Carniato F, Frache A, Boccaleri E, Camino G. Polyhedral oligomeric silsesquioxanes (POSS) thermal degradation. Thermochim Acta. 2006;440(1):36-42.
6. Shea KJ, Loy DA. Bridged polysilsesquioxanes. Molecular-engineered hybrid organic-inorganic materials. Chem Mater. 2001;13:3306-19.
7. Jian KH, Qun CZ, Shu LG. Bridged polyhedral oligomeric silsesquioxane (POSS): a potential member of silsesquioxanes. Chin Chem Lett. 2012;23:181-4.
8. Blanco I, Abate L, Bottino FA. Synthesis and thermal properties of new dumbbell-shaped isobutyl-substituted POSSs linked by aliphatic bridges. J Therm Anal Calorim. 2013. doi: 10.1007/s10973-013-3487-3.
9. Blanco I, Abate L, Bottino FA, Bottino P, Chiacchio MA. Thermal degradation of differently substituted cyclopentyl polyhedral oligomeric silsesquioxane (CP-POSS) nanoparticles. J Therm Anal Calorim. 2012;107:1083-91.
10. Blanco I, Abate L, Bottino FA, Bottino P. Hepta isobutyl polyhedral oligomeric silsesquioxanes (hib-POSS): a thermal degradation study. J Therm Anal Calorim. 2012;108:807-15.
11. Hunks WJ, Ozin GA. Periodic mesoporous phenylenesilicas with ether or sulfide hinge groups - a new class of PMOs with ligand channels. Chem Commun. 2004;21:2426-7.
12. Lichtenhan JD, Schwab JJ, Reinerth W, Carr MJ, An YZ, Feher FJ. Process for the formation of polyhedral oligomeric silsesquioxanes, US Patent WO 01/10871 A1 (2001).
13. Abate L, Badea E, Blanco I, Della Gatta G. Heat capacities and enthalpies of solid-solid transitions and fusion of a series of eleven primary alkylamides by differential scanning calorimetry. J Chem Eng Data. 2008;53(4):959-65.
14. Lichtenhan JD, Schwab JJ, An YZ, Liu Q, Haddad TS. Process for the functionalization of polyhedral oligomeric silsesquioxanes, US Patent US 2003/0055193 A1 (2003).
15. Abate L, Blanco I, Motta O, Pollicino A, Recca A. The isothermal degradation of some polyetherketones: a comparative kinetic study between long-term and short-term experiments. Polym Degrad Stab. 2002;75:465-71.
16. Abate L, Blanco I, Orestano A, Pollicino A, Recca A. Kinetics of the isothermal degradation of model polymers containing ether, ketone and sulfone groups. Polym Degrad Stab. 2005;87:271-8.
17. Blanco I, Siracusa V. Kinetic study of the thermal and thermo-oxidative degradations 4 of polylactide-modified films for food packaging. J Therm Anal Calorim. 2013;112:1171-7.
18. Blanco I, Cicala G, Latteri A, Mamo A, Recca A. Thermal and thermo-oxidative degradations of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO)/copoly(aryl ether sulfone) P(ESES-co-EES) block copolymers: a kinetic study. J Therm Anal Calorim. 2013;112:375-81.
19. Blanco I, Abate L, Bottino FA. Variously substituted phenyl hepta cyclopentyl: polyhedral oligomeric silsesquioxane (ph, hcp-POSS)/polystyrene (PS) nanocomposites. The influence of substituents on the thermal stability. J Therm Anal Calorim. 2013;112:421-8.
20. Chartoff RP. Thermoplastic polymers. In: Turi A, editor. Thermal characterization of polymeric materials, vol. 1. 2nd ed. San Diego: Academic Press; 1997. p. 688-93.
21. Orita H, Kondoh H, Nozoye H. Decomposition of saturated hydrocarbons adsorbed on Ni(755): comparison of decomposition starting temperatures among cyclic and straight-chain hydrocarbons. J Phys Chem (B). 2000;104:8692-703.
22. Whitten KW, Davis RE, Peck L. General chemistry. 7th ed. Hampshire: Thomson Brooks/Cole; 2004.
23. Bruinsma OSL, Geertsma RS, Bank P, Moulijn JA. Gas phase pyrolysis of coal-related aromatic compounds in a coiled tube flow reactor. 1. Benzene and derivatives. Fuel. 1988;67(3):327-33.