Variously substituted phenyl hepta cyclopentyl-polyhedral oligomeric silsesquioxane (ph,hcp-POSS)/polystyrene (PS) nanocomposites: The influence of substituents on the thermal stability

Journal of Thermal Analysis and Calorimetry

Volumn 112, Issue 1, 2013, Pages 421-428

  Blanco, Ignazio ^a   Abate, Lorenzo ^a   Bottino, Francesco Agatino ^a  

^a UNIVERSITY OF CATANIA   (Italy)

Author keywords

Polystyrene nanocomposites; POSS; Thermal degradation; Thermogravimetric analysis

Indexed keywords

CALORIMETRIC GLASS TRANSITION; COMPARATIVE STUDIES; FILLER CONCENTRATION; FILLER-POLYMER INTERACTION; FLUORINATED DERIVATIVES; IN-SITU POLYMERIZATION; POLYSTYRENE NANOCOMPOSITES; POSS;

FOURIER TRANSFORM INFRARED SPECTROSCOPY; OLIGOMERS; POLYSTYRENES; PYROLYSIS; STYRENE; THERMODYNAMIC STABILITY; THERMOGRAVIMETRIC ANALYSIS;

NANOCOMPOSITES;

EID: 84875472655     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-013-2997-3     Document Type: Conference Paper

References (37)

1. Gupta RK, Kennel E, Kim KJ, editors. Polymer nanocomposites handbook. Boca Raton: CRC Press Inc; 2010.
2. Pellice SA, Fasce DP, Williams RJJ. Properties of epoxy networks derived from the reaction of diglycidyl ether of bisphenol A with polyhedral oligomeric silsesquioxanes bearing OH-functionalized organic substituents. J Polym Sci Part B. 2003;41(13):1451-61.
3. Philips SH, Gonzalez RI, Chaffee KP, Haddad TS, Hoflund GB, Hsiao BS, Fu BX. Remarkable AO resistance of POSS inorganic/organic polymer. In: Loud S, editor. Bridging the centuries with SAMPE's materials and processes technology. 45th International SAMPE symposium and exhibition. Society for the Advancement of Material and Process Engineering (SAMPE), Covina, California. 2000;45:1921-31.
4. 2 nanoparticle addition on the characteristics of a new organic-inorganic hybrid membrane. Polymer. 2009;50:553-9.
5. Chrissafis K, Paraskevopoulos KM, Tsiaoussis I, Bikiaris D. Comparative study of the effect of different nanoparticles on the mechanical properties, permeability, and thermal degradation mechanism of HDPE. J Appl Polym Sci. 2009;112:1606-18.
6. 3 nanoparticles shape on thermal and crystallization behaviour of isotactic polypropylene based nanocomposites. J Therm Anal Calorim. 2005;80(1):131-6.
7. Jiao C, Chen X. Synergistic effects of zinc oxide with layered double hydroxides in EVA/LDH composites. J Therm Anal Calorim. 2009;98(3):813-8.
8. Ramezanzadeh B, Attar MM, Farzam M. Effect of ZnO nanoparticles on the thermal and mechanical properties of epoxy-based nanocomposite. J Therm Anal Calorim. 2011;103(2):731-9.
9. Viratyaporn W, Lehman RL. Effect of nanoparticles on the thermal stability of PMMA nanocomposites prepared by in situ bulk polymerization. J Therm Anal Calorim. 2011;103(1):267-73.
10. Hu S, Hu Y, Song L, Lu H. Effect of modified organic-inorganic hybrid materials on thermal properties of cotton fabrics. J Therm Anal Calorim. 2011;103(2):423-7.
11. Kannan RY, Salacinski HJ, Odlyha M, Butler PE, Seifalian AM. The degradative resistance of polyhedral oligomeric silsesquioxane nanocore integrated polyurethanes: an in vitro study. Biomaterials. 2006;27(9):1971-9.
12. Kannan RY, Salacinski HJ, Ghanavi J, Narula A, Odlyha M, Peirovi H, Butler PE, Seifalian AM. Silsesquioxane nanocomposites as tissue implants. Plast Reconstr Surg. 2007;119(6):1653-62.
13. Mather PT, Jeon HG, Haddad TS. Strain recovery in POSS hybrid thermoplastics. Polym Prepr. 2000;41(1):528-9.
14. Fina A, Tabuani D, Carniato F, Frache A, Boccaleri E, Camino G. Polyhedral oligomeric silsesquioxanes (POSS) thermal degradation. Thermochim Acta. 2006;440(1):36-42.
15. Abate L, Blanco I, Bottino FA, Di Pasquale G, Fabbri E, Orestano A, Pollicino A. Kinetic study of the thermal degradation of PS/MMT nanocomposites prepared with imidazolium surfactants. J Therm Anal Calorim. 2008;91(3):681-6.
16. Fina A, Monticelli O, Camino G. POSS-based hybrids by melt/reactive blending. J Mater Chem. 2010;20:9297-305.
17. Fina A, Tabuani D, Frache A, Boccaleri E, Camino G. In: Le Bras M, Wilkie C, Bourbigot S, editors. Fire retardancy of polymers: new applications of mineral fillers. Cambridge, UK: Royal Society of Chemistry; 2005. p. 202-20.
18. Blanco I, Abate L, Bottino FA, Bottino P, Chiacchio MA. Thermal degradation of differently substituted cyclopentyl polyhedral oligomeric silsesquioxane (CP-POSS) nanoparticles. J Therm Anal Calorim. 2012;107(3):1083-91.
19. Blanco I, Abate L, Bottino FA, Bottino P. Hepta isobutyl polyhedral oligomeric silsesquioxanes (hib-POSS): a thermal degradation study. J Therm Anal Calorim. 2012;108(2):807-15.
20. Blanco I, Abate L, Bottino FA, Bottino P. Thermal degradation of hepta cyclopentyl, mono phenyl-polyhedral oligomeric silsesquioxane (hcp-POSS)/polystyrene (PS) nanocomposites. Polym Degrad Stab. 2012;97(6):849-55.
21. Blanco I, Bottino FA, Bottino P. Influence of symmetry/asymmetry of the nanoparticles structure on the thermal stability of polyhedral oligomeric silsesquioxane/polystyrene nanocomposites. Polym Compos. 2012;33(11):1903-10.
22. Blanco I, Bottino FA. Thermal study on phenyl, hepta isobutyl-polyhedral oligomeric silsesquioxane/polystyrene nanocomposites. Polym Compos. 2013;34(2):225-32.
23. Rosenberg SD, Walburn JJ, Ramsden HE. Preparation of some arylchlorosilanes with arylmagnesium chlorides. J Org Chem. 1957;22(12):1606-7.
24. Breed LW, Haggerty WJ Jr. Aryl and alkylchlorodialkoxysilanes. J Org Chem. 1960;25(1):126-8.
25. Feher FJ, Newman DA. Enhanced silylation reactivity of a model for silica surfaces. J Am Chem Soc. 1990;112(5):1931-6.
26. 4]. Organometallics. 1991;10(7):2526-8.
27. User's manual TA 3000 System. Greifensee: Mettler Instr., AG, 1984.
28. Della Gatta G, Richardson MJ, Sarge SM, Stølen S. Standards, calibration, and guidelines in microcalorimetry. Part 2. Calibration standards for differential scanning calorimetry (IUPAC Technical Report). Pure Appl Chem. 2006;78(7):1455-76.
29. Abate L, Badea E, Blanco I, Della Gatta G. Heat capacities and enthalpies of solid-solid transitions and fusion of a series of eleven primary alkylamides by differential scanning calorimetry. J Chem Eng Data. 2008;53:959-65.
30. Csaba N. Handbook of thermal analysis and calorimetry. In: Gallagher Patrick K, Brown Michael E, editors. Principles and practice, vol. 1. Amsterdam: Elsevier; 1998.
31. Blanco I, Oliveri L, Cicala G, Recca A. Effects of novel reactive toughening agent on thermal stability of epoxy resin. J Therm Anal Calorim. 2012;108:685-93.
32. Blanco I, Siracusa V. Kinetic study of the thermal and thermo-oxidative degradations of polylactide-modified films for food packaging. J Therm Anal Calorim. doi: 10.1007/s10973-012-2535-8.
33. Abate L, Blanco I, Cicala G, La Spina R, Restuccia CL. Thermal and rheological behaviour of some random aromatic polyethersulfone/ polyetherethersulfone copolymers. Polym Degrad Stab. 2006;91(4):924-30.
34. Abate L, Blanco I, Cicala G, Recca A, Restuccia CL. Thermal and rheological behaviours of some random aromatic amino-ended polyethersulfone/ polyetherethersulfone copolymers. Polym Degrad Stab. 2006;91(12):3230-6.
35. Abate L, Blanco I, Cicala G, Recca G, Scamporrino A. The influence of chain ends on the thermal and rheological properties of some 40/60 PES/PEES copolymers. Polym Eng Sci. 2009;49(8):1477-83.
36. Abate L, Blanco I, Cicala G, Mamo A, Recca G, Scamporrino A. The influence of chain rigidity on the thermal properties of some novel random copolyethersulfones. Polym Degrad Stab. 2010;95:798-802.
37. Chartoff RP. Thermoplastic Polymers. In: Turi A, editor. Thermal characterization of polymeric materials. 2nd ed. San Diego: Academic Press; 1997.