Discovery of Dark pH-Dependent H+ Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate

Journal of the American Chemical Society

Volumn 137, Issue 26, 2015, Pages 8484-8489

  Murphy, Bonnie J ^a   Hidalgo, Ricardo ^a   Roessler, Maxie M ^a,b   Evans, Rhiannon M ^a   Ash, Philip A ^a   Myers, William K ^a   Vincent, Kylie A ^a   Armstrong, Fraser A ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b QUEEN MARY UNIVERSITY OF LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ACIDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ESCHERICHIA COLI; LIGANDS; PHOTOLYSIS; SPECTROSCOPIC ANALYSIS;

CATALYTIC INTERMEDIATES; CONTRIBUTORY FACTORS; ELECTRON TRANSFER; INFRARED SPECTROSCOPIC STUDIES; INTERCONVERSIONS; PROTON MIGRATION; REDUCTION POTENTIAL; [NIFE]-HYDROGENASE;

NICKEL;

AMINO ACID; CARBON; FERROUS ION; LIGAND; NICKEL; NICKEL IRON HYDROGENASE; PROTON; SULFUR; ESCHERICHIA COLI PROTEIN; HYDROGEN; HYDROGENASE; HYDROGENASE 1, E COLI; METAL; NICKEL-IRON HYDROGENASE; NITROGEN; OXYGEN;

ARTICLE; ARTIFACT; CATALYSIS; DARKNESS; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ESCHERICHIA COLI; INFRARED SPECTROSCOPY; LOW TEMPERATURE; MOBILIZATION; PH; PHOTOLYSIS; PROTON TRANSPORT; REDUCTION; CHEMISTRY; ELECTRON; ENZYME ACTIVE SITE; ENZYMOLOGY; OXIDATION REDUCTION REACTION; TEMPERATURE;

CARBON; CATALYTIC DOMAIN; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; ESCHERICHIA COLI; ESCHERICHIA COLI PROTEINS; HYDROGEN; HYDROGEN-ION CONCENTRATION; HYDROGENASE; LIGANDS; METALS; NICKEL; NITROGEN; OXIDATION-REDUCTION; OXYGEN; PHOTOLYSIS; PROTONS; TEMPERATURE;

EID: 84936792013     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b03182     Document Type: Article

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