An autocatalytic mechanism for NiFe-hydrogenase: Reduction to Ni(I) followed by oxidative addition

Biochemistry

Volumn 48, Issue 5, 2009, Pages 1056-1066

  Lill, Sten O Nilsson ^a   Siegbahn, Per E M ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

[NIFE]-HYDROGENASE; AUTOCATALYTIC; CATALYTIC TURNOVERS; ELECTROSTATIC INTERACTIONS; FORCE FIELDS; HETEROLYTIC CLEAVAGES; HYBRID DFT; ONIOM APPROACHES; OXIDATION STATE; OXIDATIVE ADDITIONS; POLARIZATION EFFECTS; REACTION MECHANISMS;

HYDROGEN; NICKEL ALLOYS; PROBABILITY DENSITY FUNCTION;

NICKEL;

HYDROGENASE; IRON COMPLEX; NICKEL COMPLEX; NICKEL; NICKEL IRON HYDROGENASE; NICKEL-IRON HYDROGENASE;

ADDITION REACTION; ARTICLE; CATALYSIS; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ENZYME METABOLISM; ENZYME STRUCTURE; OXIDATION; PRIORITY JOURNAL; REDUCTION; CHEMICAL STRUCTURE; CHEMISTRY; DESULFOVIBRIO; ENZYMOLOGY; METABOLISM; OXIDATION REDUCTION REACTION; X RAY CRYSTALLOGRAPHY;

CATALYSIS; CRYSTALLOGRAPHY, X-RAY; DESULFOVIBRIO; HYDROGENASE; MODELS, MOLECULAR; NICKEL; OXIDATION-REDUCTION;

EID: 61449143522     PISSN: 00062960     EISSN: None     Source Type: Journal    
DOI: 10.1021/bi801218n     Document Type: Article

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