Direct Detection of a Hydrogen Ligand in the [NiFe] Center of the Regulatory H2-Sensing Hydrogenase from Ralstonia eutropha in Its Reduced State by HYSCORE and ENDOR Spectroscopy

Journal of the American Chemical Society

Volumn 125, Issue 43, 2003, Pages 13075-13083

  Brecht, Marc ^a,d   Van Gastel, Maurice ^b   Buhrke, Thorsten ^c   Friedrich, Bärbel ^c   Lubitz, Wolfgang ^b  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^c HUMBOLDT UNIVERSITY   (Germany)

^d FREIE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ANISOTROPY; CHEMICAL BONDS; CRYSTAL STRUCTURE; MAGNETIC FIELDS; PROTONS; SPECTROSCOPY; THERMAL EFFECTS;

COUPLING CONSTANTS;

ENZYMES;

BACTERIAL ENZYME; CARBON; HYDROGEN; HYDROGENASE; IRON; LITHIUM; NICKEL; PROTON;

ARTICLE; CORRELATION ANALYSIS; CRYSTAL STRUCTURE; DESULFOVIBRIO VULGARIS; HYDROGEN BOND; LOW TEMPERATURE; MAGNETIC FIELD; NONHUMAN; PROTON TRANSPORT; SPECTROSCOPY; STRUCTURE ANALYSIS; WAUTERSIA EUTROPHA;

COMPUTER SIMULATION; CUPRIAVIDUS NECATOR; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDROGEN; HYDROGEN BONDING; HYDROGENASE; LIGANDS; MODELS, MOLECULAR; OXIDATION-REDUCTION;

EID: 0142152415     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036624x     Document Type: Article

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