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Volumn 5, Issue 6, 2015, Pages 3726-3730

Discovering copper for methane C-H bond functionalization

Author keywords

C H activation; carbene insertion; copper catalysis; methane activation; supercritical carbon dioxide

Indexed keywords

ACTIVATION ANALYSIS; CARBON; CARBON DIOXIDE; CATALYSIS; CATALYSTS; CHEMICAL ACTIVATION; COPPER; METHANE; PARAFFINS; SUPERCRITICAL FLUID EXTRACTION;

EID: 84930650411     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/acscatal.5b00718     Document Type: Article
Times cited : (61)

References (41)
  • 33
    • 0042467244 scopus 로고
    • Since the ν(CO) frequency lies above that of free CO, the term non-classical metal-carbonyls is employed. See
    • Since the ν (CO) frequency lies above that of free CO, the term non-classical metal-carbonyls is employed. See: Hurlburt, P. K.; Rack, J. J.; Luck, J. S.; Dec, S. F.; Webb, J. D.; Anderson, O. P.; Strauss, S. H. J. Am. Chem. Soc. 1994, 116, 10003-10014 10.1021/ja00101a021
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 10003-10014
    • Hurlburt, P.K.1    Rack, J.J.2    Luck, J.S.3    Dec, S.F.4    Webb, J.D.5    Anderson, O.P.6    Strauss, S.H.7
  • 36
    • 84909942980 scopus 로고    scopus 로고
    • The presence of a large concentration of the hydrocarbon precludes secondary reaction on the products, ethylpropionate or diethyl fumarate or maleate. A recent study from our laboratory has shown that when employed in large amounts, the esters react with EDA with this family of catalysts through O-ylide intermediates and loss of ethanol in the presence of adventitious water. See
    • The presence of a large concentration of the hydrocarbon precludes secondary reaction on the products, ethylpropionate or diethyl fumarate or maleate. A recent study from our laboratory has shown that when employed in large amounts, the esters react with EDA with this family of catalysts through O-ylide intermediates and loss of ethanol in the presence of adventitious water. See: Gava, R.; Fuentes, M. A.; Besora, M.; Belderrain, T. R.; Jacob, K.; Maseras, F.; Etienne, M.; Caballero, A.; Pérez, P. J. ChemCatChem 2014, 6, 2206-2210 10.1002/cctc.201402241
    • (2014) ChemCatChem , vol.6 , pp. 2206-2210
    • Gava, R.1    Fuentes, M.A.2    Besora, M.3    Belderrain, T.R.4    Jacob, K.5    Maseras, F.6    Etienne, M.7    Caballero, A.8    Pérez, P.J.9


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.