A new perfluorinated F21-Tp scorpionate ligand: Enhanced alkane functionalization by carbene insertion with (F21-Tp)M catalysts (M = Cu, Ag)

Organometallics

Volumn 27, Issue 18, 2008, Pages 4779-4787

  Despagnet Ayoub, Emmanuelle ^a   Jacob, Kane ^a   Vendier, Laure ^a   Etienne, Michel ^a   Álvarez, Eleuterio ^c   Caballero, Ana ^b   Díaz Requejo, M Mar ^b   Pérez, Pedro J ^b  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b INSTITUTO DE INVESTIGACIONES QUÍMICAS   (Spain)

^c UNIVERSITY OF HUELVA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

PERFLUORINATED;

EID: 53849149326     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800531a     Document Type: Article

References (47)

1. (a) Shilov, A. E.; Shul'pin, G. B. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes; Kluwer: Dordrecht 2000.
2. (b) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH Publishers: New York, 1990.
3. (c) Shilov, A. E.; Shul'pin, G. B. Chem. Rev. 1997, 97, 2879.
4. (d) Arndtsen, B. A.; Bergman, R. G.; Mobleyand, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
5. (a) Bergman, R. G. Nature 2007, 446, 391.
6. (b) Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507.
7. (a) Doyle, M. P.; McKervey, M. A.; Ye, T. Modern Catalytic Methods for Organic Synthesis with Diazo Compounds; John Wiley & Sons: New York, 1998.
8. (a) Davies, H. M. L. Nature 2008, 451, 417.
9. (b) Davies, H. M. L.; Beckwith, R. E. J. Chem. Rev. 2003, 103, 2861. For specific work of asymmetric induction with alkanes see:
10. (c) Davies, H. M. L.; Hansen, T. J. Am. Chem. Soc. 1997, 119, 9075.
11. (d) Davies, H. M. L.; Hansen, T.; Churchill, M. R. J. Am. Chem. Soc. 2000, 122, 3063.
12. (a) Demonceau, A.; Noels, A. F.; Hubert, A.; Teyssié, P. J Chem. Soc., Chem. Commun. 1981, 688.
13. (b) Callot, H. J.; Metz, F. Nouv. J. Chim. 1985, 9, 167.
14. (c) Endres, A.; Maas, G. J. Organomet. Chem. 2002, 643, 174.
15. Díaz-Requejo, M. M.; Belderrain, T. R.; Nicasio, M. C.; Pérez, P. J. Dalton Trans. 2006, 5559.
16. (a) Díaz-Requejo, M. M.; Belderrain, T. R.; Nicasio, M. C.; Trofimenko, S.; Pérez, P. J. J. Am. Chem. Soc. 2002, 124, 896.
17. (b) Caballero, A.; Díaz-Requejo, M. M.; Belderrain, T. R.; Nicasio, M. C.; Trofimenko, S.; Pérez, P. J. J. Am. Chem. Soc. 2003, 125, 1446.
18. (c) Caballero, A.; Díaz-Requejo, M. M.; Belderrain, T. R.; Nicasio, M. C.; Trofimenko, S.; Pérez, P. J. Organometallics 2003, 22, 4145.
19. (a) Dias, H. V. R.; Browning, R. G.; Richey, S. A.; Lovely, C. J. Organometallics 2004, 23, 1200.
20. (b) Dias, H. V. R.; Browning, R. G.; Richey, S. A.; Lovely, C. J. Organometallics 2005, 24, 5784.
21. Urbano, J.; Belderrain, T. R.; Nicasio, M. C.; Trofimenko, S.; Díaz-Requejo, M. M.; Pérez, P. J. Organometallics 2005, 24, 1528.
22. Fructos, M. R.; Frémont, P. de; Nolan, S. P.; Díaz-Requejo, M. M.; Pérez, P. J. Organometallics 2006, 25, 2237.
23. Teichert, J.; Oulié, P.; Jacob, K.; Vendier, L.; Etienne, M.; Claramunt, R. M.; López, C.; Medina, C. P.; Alkorta, I.; Elguero, J. New J. Chem. 2007, 31, 936.
24. (a) Reichenbächer, K.; Süss, H. I.; Hulliger, J. Chem. Soc. Rev. 2005, 34, 22.
25. (b) Hunter, C. A.; Lawson, K. R.; Perkins, J.; Urch, C. J. J. Chem. Soc., Perkin Trans. 2 2001, 651.
26. Renn, O.; Venanzi, L. M.; Marteletti, A.; Gramlich, V. Helv. Chim. Acta 1995, 78, 993.
27. Trofimenko, S. Scorpionates: The Coordination Chemistry of Polypyrazolylborate Ligands; Imperial College Press: London. 1999.
28. Dias, H. V. R.; Wang, Z.; Jin, W. Inorg. Chem. 1997, 36, 6205.
29. Fujisawa, K.; Ono, T.; Ishikawa, Y.; Amir, N.; Miyashita, Y.; Okamoto, K.; Lehnen, N. Inorg. Chem. 2006, 45, 1698.
30. Weber, L. Angew. Chem., Int. Ed. Engl. 1994, 33, 1077.
31. (a) Bruce, M. I.; Ostazewski, A. P. P. J. Chem. Soc., Dalton Trans. 1973, 2433.
32. (b) Churchill, M. R.; DeBoer, B. G.; Rotella, F. J.; Abu.Salah, O. M.; Bruce, M. I. Inorg. Chem. 1975, 14, 2051.
33. (a) Dias, R. H. V.; Kim, H.-J.; Lu, H.-L.; Rajeshwar, K.; de.Tacconi, N. R.; Derecskei-Kovacs, A.; Marynick, D. S. Organometallics 1996, 15, 2994.
34. (b) Dias, H. V. R.; Lu, H.-L. Inorg. Chem. 1995, 34, 5380.
35. (c) Dias, H. V. R.; Wang, X. Dalton Trans. 2005, 2985.
36. Braterman, P. S. Metal Carbonyl Spectra; Academic Press: New York, 1975; p 177.
37. Lupinetti, A. J.; Strauss, S. H.; Frenking, G. Prog. Inorg. Chem. 2001, 49, 1.
38. Dias, H. V. R.; Jin, W. Inorg. Chem. 1996, 35, 3687.
39. 591 structures with terminal metal carbonyl complexes with C-O distances between 1.06 and 1.075 Å were found in the Cambridge Crystallographic Data Base.
40. Braga, A. A. C.; Maseras, F.; Urbano, J.; Caballero, A.; Díaz-Requejo, M. M.; Pérez, P. J. Organometallics 2006, 25, 5292.
41. (a) Altomare, A.; Cascarano, G.; Giacovazzo, G.; Guagliardi, A.; Burla, M. C.; Polidori, G.; Camalli, M. J. Appl. Crystallogr. 1994, 27, 435.
42. (b) Burla, M. C.; Camalli, M.; Carrozzini, B.; Cascarano, G. L.; Giacovazzo, C.; Polidori, G.; Spagna, R. SIR.2002: the program. J. Appl. Crystallogr. 2003, 36, 1103.
43. Sheldrick, G. M. SHELX97. [includes SHELXS97, SHELXL97, CIFTAB], Programs for Crystal Structure Analysis (Release 97-2); Institut für Anorganische Chemie der Universität: Göttingen, Germany, 1998.
44. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837.
45. Bruker, Apex 2, version 2.1 ; Bruker AXS Inc.: Madison, WI, 2004.
46. Blessing, R. H. MULTI SCAN. Acta Crystallogr. 1995, A51, 33.
47. Spek, A. L. Acta Crystallogr. 1990, A46, C-34.