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84855556874
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For recent contribution in the synthesis of trifluoromethyl pyrazole derivatives, see
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For recent contribution in the synthesis of trifluoromethyl pyrazole derivatives, see: I.G. Gerus, R.X. Mironetz, I.S. Kondratov, A.I. Bezdudny, Y.V. Dmytriv, O.V. Shishkin, V.S. Starova, O.A. Zaporezhets, A.A. Tolmachev, and P.V. Mykhailiuk Journal of Organic Chemistry 77 2012 47 56
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Starova, V.S.7
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Tolmachev, A.A.9
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30
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84943407995
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See: A.R. Katritzky, C.W. Rees, Pergamon Press Oxford
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See: J. Elguero A.R. Katritzky, C.W. Rees, Comprehensive Heterocyclic Chemistry vol. 5 1984 Pergamon Press Oxford 167 334
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Elguero, J.1
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38
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0033428816
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See:, Actually, on the basis of its value of vapour pressure, 2 can be classified as a medium volatility organic compound (MVOC) exerting a vapour pressure @ STP conditions in the 266.6 Pa to 10.66 kPa range.
-
See: I. Aikorta, J. Elguero, B. Donnadieu, M. Etienne, J. Jaffart, D. Schagen, and H.-H. Limbach New Journal of Chemistry 23 1999 1231 1237 Actually, on the basis of its value of vapour pressure, 2 can be classified as a medium volatility organic compound (MVOC) exerting a vapour pressure @ STP conditions in the 266.6 Pa to 10.66 kPa range.
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New Journal of Chemistry
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Jaffart, J.5
Schagen, D.6
Limbach, H.-H.7
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39
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84861184842
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Hexafluoroacetylacetone (98+%) is also commercially available (Sigma Aldrich) at 209/25 g
-
Hexafluoroacetylacetone (98+%) is also commercially available (Sigma Aldrich) at 209/25 g.
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42
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84861184024
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With trifluoromethyl substituted azoles, considerable caution must be also exercised in using bases, see
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With trifluoromethyl substituted azoles, considerable caution must be also exercised in using bases, see
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44
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84861184116
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US Patent 2,004,162,282(A1)
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To the best of our knowledge, there is only one literature report of a chlorination of 2, but all attempts to isolate pure 4 according this patented procedure have as yet been unsuccessful: A.M.K. Pennell, J.B. Aggen, J.J. Kim, S. Subhabrata, B.E. McMaster, D.J. Duraghi, US Patent 2,004,162,282(A1), 2004.
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