Agglomerative sintering of an atomically dispersed ir1/zeolite y catalyst: Compelling evidence against ostwald ripening but for bimolecular and autocatalytic agglomeration catalyst sintering steps

ACS Catalysis

Volumn 5, Issue 6, 2015, Pages 3514-3527

  Bayram, Ercan ^a   Lu, Jing ^b   Aydin, Ceren ^b   Browning, Nigel D ^b,c   Özkar, Saim ^d   Finney, Eric ^a   Gates, Bruce C ^b   Finke, Richard G ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

^b University of California   (United States)

^c PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^d MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

Author keywords

agglomeration; catalyst; cluster; kinetics; mononuclear; nanoparticle; Ostwald ripening; sintering

Indexed keywords

AGGLOMERATION; CATALYST SUPPORTS; CATALYSTS; CHEMICAL REACTIONS; CYCLOHEXANE; DISPERSIONS; ENZYME KINETICS; ETHYLENE; EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY; NANOPARTICLES; OSTWALD RIPENING; SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; X RAY ABSORPTION; ZEOLITES;

AUTOCATALYTIC AGGLOMERATIONS; BALANCED CHEMICAL EQUATIONS; BIMOLECULAR AGGLOMERATIONS; CLUSTER; HIGH-ANGLE ANNULAR DARK FIELDS; MONONUCLEAR; PARTICLE MIGRATION AND COALESCENCES; QUANTITATIVE INVESTIGATION;

SINTERING;

EID: 84930619658     PISSN: None     EISSN: 21555435     Source Type: Journal    
DOI: 10.1021/acscatal.5b00321     Document Type: Article

References (95)

1. For TEM investigations of sintering, in which Ostwald ripening processes are proposed, see: Simonsen, S. B.; Chorkendorff, I.; Dahl, S.; Skoglundh, M.; Sehested, J.; Helveg, S. J. Am. Chem. Soc. 2010, 132, 7968-7975 10.1021/ja910094r
2. Bartholomew, C. H. Appl. Catal., A 2001, 212, 17-60 10.1016/S0926-860X(00)00843-7
3. nd ed.; Ertl, G.; Knözinger, H.; Schüth, F.; Weitkamp, J., Eds.; Wiley-VCH: Weinheim, 2008.
4. nd ed.; Wiley: Hoboken, NJ, 2006.
5. For nanoplasmonic spectroscopy studies of sintering, in which Ostwald ripening is proposed as the main sintering mechanism, see: Larsson, E. M.; Millet, J.; Gustafsson, S.; Skoglundh, M.; Zhdanov, V. P.; Langhammer, C. ACS Catal. 2012, 2, 238-245 10.1021/cs200583u
6. Bartholomew, C. H. Kirk-Othmer Encyclopedia of Chemical Technology; Wiley: New York, 2003; Vol. 5; p 255.
7. Campbell, C. T. Acc. Chem. Res. 2013, 46, 1712-1719 10.1021/ar3003514
8. Parker, S. C.; Campbell, C. T. Top. Catal. 2007, 44, 3-13 10.1007/s11244-007-0274-z
9. Campbell, C. T.; Parker, S. C.; Starr, D. E. Science 2002, 298, 811-814 10.1126/science.1075094
10. Yang, S.; Qiu, P.; Yang, G. Carbon 2014, 77, 1123-1131 10.1016/j.carbon.2014.06.030
11. Liu, H.; Zhang, L.; Wang, N.; Su, D. S. Angew. Chem., Int. Ed. 2014, 53, 12634-12638 10.1002/anie.201406490
12. Moonen, P. F.; Bat, E.; Voorthuijzen, W. P.; Huskens, J. RSC Adv. 2013, 3, 18498-18505 10.1039/c3ra43926g
13. Yoon, K.; Yang, Y.; Lu, P.; Wan, D. H.; Peng, H. C.; Masias, K. S.; Fanson, P. T.; Campbell, C. T.; Xia, Y. N. Angew. Chem., Int. Ed. 2012, 51, 9543-9546 10.1002/anie.201203755
14. Datye, A. K.; Xu, Q.; Kharas, K. C.; McCarty, J. M. Catal. Today 2006, 111, 59-67 10.1016/j.cattod.2005.10.013
15. Hansen, T. W.; DeLaRiva, A. T.; Challa, S. R.; Datye, A. K. Acc. Chem. Res. 2013, 46, 1720-1730 10.1021/ar3002427
16. DeLaRiva, A. T.; Hansen, T. W.; Challa, S. R.; Datye, A. K. J. Catal. 2013, 308, 291-305 10.1016/j.jcat.2013.08.018
17. Xu, Q.; Kharas, K. C.; Croley, B. J.; Datye, A. K. Top. Catal. 2012, 55, 78-83 10.1007/s11244-012-9770-x
18. Bartholomew, C. H. Appl. Catal., A 1993, 107, 1-57 10.1016/0926-860X(93)85114-5
19. Lee, H. H. J. Catal. 1980, 63, 129-137 10.1016/0021-9517(80)90066-4
20. Stassinos, E. C.; Lee, H. H. Chem. Eng. Sci. 1995, 50, 1337-1345 10.1016/0009-2509(95)98845-6
21. Manninger, I. J. Catal. 1984, 89, 164-167 10.1016/0021-9517(84)90291-4
22. Fuentes, G. A. Appl. Catal. 1985, 15, 33-40 10.1016/S0166-9834(00)81484-0
23. Fuentes, G. A.; Salinas-Rodriguez, E. Stud. Surf. Sci. Catal. 2001, 139, 503-510
24. Bartholomew, C. H. Stud. Surf. Sci. Catal. 1997, 111, 585-592 10.1016/s0167-2991(01)80236-6
25. Spivey, J. J.; Agarwal, S. K.; Bartholomew, C. H. Catalysis 1993, 10, 41-82 10.1039/9781847553225-00041
26. Zhai, Y.; Pierre, D.; Si, R.; Deng, W.; Ferrin, P.; Nilekar, A. U.; Peng, G.; Herron, J. A.; Bell, D. C.; Saltsburg, H.; Mavrikakis, M.; Flytzani-Stephanopoulos, M. Science 2010, 329, 1633-1636 10.1126/science.1192449
27. Aydin, C.; Lu, J.; Liang, A. J.; Chen, C.-Y.; Browning, N. D.; Gates, B. C. Nano Lett. 2011, 11, 5537-5541 10.1021/nl2034305
28. Lu, J.; Aydin, C.; Browning, N. D.; Gates, B. C. J. Am. Chem. Soc. 2012, 134, 5022-5025 10.1021/ja211380p
29. Ratnasamy, P.; Srinivas, D.; Knözinger, H. Adv. Catal. 2004, 48, 1-169 10.1016/s0360-0564(04)48001-8
30. Uzun, A.; Gates, B. C. J. Am. Chem. Soc. 2009, 131, 15887-15894 10.1021/ja906553n
31. Uzun, A.; Dixon, D. A.; Gates, B. C. ChemCatChem 2011, 3, 95-107 10.1002/cctc.201000271
32. Xu, Z.; Xiao, F.-S.; Purnell, S. K.; Alexeev, O.; Kawi, S.; Deutsch, S. E.; Gates, B. C. Nature 1994, 372, 346-348 10.1038/372346a0
33. Argo, A. M.; Odzak, J. F.; Lai, F. S.; Gates, B. C. Nature 2002, 415, 623-626 10.1038/415623a
34. Yang, X.-F.; Wang, A.; Qiao, B.; Li, J.; Liu, J.; Zhang, T. Acc. Chem. Res. 2013, 46, 1740-1748 10.1021/ar300361m
35. Schüth, F. Angew. Chem., Int. Ed. 2014, 53, 8599-8604 10.1002/anie.201402251
36. Cao, X.; Ji, Y.; Luo, Y. J. Phys. Chem. C 2015, 119, 1016-1023 10.1021/jp508625b
37. Li, F.; Li, Y.; Zeng, X. C.; Chen, Z. ACS Catal. 2015, 5, 544-552 10.1021/cs501790v
38. Flytzani-Stephanopoulos, M.; Gates, B. C. Annu. Rev. Chem. Biomol. Eng. 2012, 3, 545-574 10.1146/annurev-chembioeng-062011-080939
39. Parkinson, G. S.; Novotny, Z.; Argentero, G.; Schmid, M.; Pavelec, J.; Kosak, R.; Blaha, P.; Diebold, U. Nat. Mater. 2013, 12, 724-728 10.1038/nmat3667
40. Kyriakou, G.; Boucher, M. B.; April, D.; Jewell, A. D.; Lewis, E. A.; Lawton, T. J.; Baber, A. E.; Tierney, H. L.; Flytzani-Stephanopoulos, M.; Sykes, E. C. H. Science 2012, 335, 1209-1212 10.1126/science.1215864
41. Qiao, B.; Wang, A.; Yang, X.; Allard, L. F.; Jiang, Z.; Cui, Y.; Liu, J.; Li, J.; Zhang, T. Nat. Chem. 2011, 3, 634-641 10.1038/nchem.1095
42. McDaniel, M. P. Adv. Catal. 2010, 53, 123-606
43. Uzun, A.; Gates, B. C. Angew. Chem., Int. Ed. 2008, 47, 9245-9248 10.1002/anie.200802140
44. Lu, J.; Aydin, C.; Browning, N. D.; Gates, B. C. J. Am. Chem. Soc. 2011, 133, 16186-16195 10.1021/ja206486j
45. Bayram, E.; Lu, J.; Aydin, C.; Uzun, A.; Browning, N. D.; Gates, B. C.; Finke, R. G. ACS Catal. 2012, 2, 1947-1957 10.1021/cs300366w
46. Watzky, M. A.; Finke, R. G. J. Am. Chem. Soc. 1997, 119, 10382-10400 10.1021/ja9705102
47. Watzky, M. A.; Finke, R. G. Chem. Mater. 1997, 9, 3083-3095 10.1021/cm9704387
48. Aiken, J. D., III; Finke, R. G. J. Am. Chem. Soc. 1998, 120, 9545-9554 and references therein. 10.1021/ja9719485
49. Widegren, J. A.; Aiken, J. D., III; Özkar, S.; Finke, R. G. Chem. Mater. 2001, 13, 312-324 and references therein. 10.1021/cm0006852
50. Argo, A. M.; Odzak, J. F.; Gates, B. C. J. Am. Chem. Soc. 2003, 125, 7107-7115 10.1021/ja027741f
51. Grundwaldt, J.-D.; Kappen, P.; Basini, L.; Clausen, B. S. Catal. Lett. 2002, 78, 13-21 10.1023/A:1014909415661
52. Li, F.; Gates, B. C. J. Phys. Chem. B 2003, 107, 11589-11596 10.1021/jp035813z
53. Ortalan, V.; Uzun, A.; Gates, B. C.; Browning, N. D. Nat. Nanotechnol. 2010, 5, 506-510 10.1038/nnano.2010.92
54. Okamoto, N. L.; Reed, B. W.; Mehraeen, S.; Kulkarni, A.; Morgan, D. G.; Gates, B. C.; Browning, N. D. J. Phys. Chem. C 2008, 112, 1759-1763 10.1021/jp710959x
55. Gates, B. C. J. Mol. Catal. A: Chem. 2000, 163, 55-65 10.1016/S1381-1169(00)00399-X
56. th ed.; Lide, D. R.; Frederikse, H. P. R., Eds.; CRC Press: Boca Raton, FL, 1996.
57. Lu, J.; Aydin, C.; Browning, N. D.; Wang, L.; Gates, B. C. Catal. Lett. 2012, 142, 1445-1451 10.1007/s10562-012-0928-8
58. ∼40 nanoparticles have even been observed to bounce off each other in STEM images: Aydin, C.; Lu, J.; Browning, N. D.; Gates, B. C. Angew. Chem., Int. Ed. 2012, 51, 5929-5934 10.1002/anie.201201726
59. Crooks, A.; Yih, K.-H.; Li, L.; Yang, J. C.; Özkar, S.; Finke, R. G. ACS Catal. 2015, 5, 3342-3353 10.1021/acscatal.5b00347
60. Pawluk, T.; Hirata, Y.; Wang, L. J. Phys. Chem. B 2005, 109, 20817-20823 10.1021/jp053563b
61. Besson, C.; Finney, E. E.; Finke, R. G. J. Am. Chem. Soc. 2005, 127, 8179-8184 10.1021/ja0504439
62. Besson, C.; Finney, E. E.; Finke, R. G. Chem. Mater. 2005, 17, 4925-4938 10.1021/cm050207x
63. Ott, L. S.; Finke, R. G. Chem. Mater. 2008, 20, 2592-2601 10.1021/cm062001h
64. Shields, S.; Buhro, W. E.; Finney, E. E.; Finke, R. G. Chem. Mater. 2012, 24, 1718-1725 10.1021/cm203186y
65. To drive home the significance of knowing the starting point here, if it was "A", then the 2 steps and associated correct words and descriptors that should have been used to fit the data would have been bimolecular nucleation,(50b) A + A → 2B, and autocatalytic growth, A + B → 2B. Moreover, we know from experience that the associated diameter vs time equation for these two steps is very similar to eq 1 so that the fit to the observed diameter vs time data would be indistinguishable from that observed for the B + B → 2B, B + C → 1.5 C diameter equation. We have discussed previously the enormous significance to understanding chemistry and chemical mechanisms of using the proper balanced equations that not only define the rate constants, but also define the proper words and concepts to be used when talking about the underlying chemistry and associated mechanism.(50b, 50c)
66. Laxson, W. W.; Finke, R. G. J. Am. Chem. Soc. 2014, 136, 17601-17615 10.1021/ja510263s
67. Finney, E. E.; Finke, R. G. Chem. Mater. 2009, 21, 4692-4705 10.1021/cm9018716
68. Breck, D. W. Zeolite Molecular Sieves; Wiley: New York, 1974.
69. Tong, Y. Y.; van der Klink, J. J.; Clugnet, G.; Renouprez, A. J.; Laub, D.; Buffat, P. A. Surf. Sci. 1993, 292, 276-288 10.1016/0039-6028(93)90333-F
70. Rathousky, J.; Zukal, A.; Jaeger, N.; Schulz-Ekloff, G. Nanostruct. Mater. 1992, 1, 355-360 10.1016/0965-9773(92)90042-V
71. We use the term "pseudo-elementary" as first defined by Noyes in his studies of complex, many-step oscillating reactions, that is, where one can use a reaction that is a sum of more than one elementary reaction, plus faster reactions, the sum of which is by definition a pseudo-elementary reaction that can be used in a kinetically useful way.
72. Noyes, R. M.; Field, R. J. Acc. Chem. Res. 1977, 10, 214-221 10.1021/ar50114a004
73. Noyes, R. M.; Field, R. J. Acc. Chem. Res. 1977, 10, 273-280 10.1021/ar50116a001
74. Field, R. J.; Noyes, R. M. Nature 1972, 237, 390-392 10.1038/237390a0
75. See also our prior uses of the pseudo-elementary reaction concept in the formation and agglomeration of nanoparticles.(32, 33, 48, 49)
76. Wang, F.; Richards, V. N.; Shields, S. P.; Buhro, W. E. Chem. Mater. 2013, 26, 5-21 10.1021/cm402139r
77. Jiang, F.; Muscat, A. J. Langmuir 2012, 28, 12931-12940 10.1021/la301186n
78. An, K.; Alayoglu, S.; Ewers, T.; Somorjai, G. J. Colloid Interface Sci. 2012, 373, 1-13 10.1016/j.jcis.2011.10.082
79. Lilly, G. D.; Lee, J.; Sun, K.; Tang, Z.; Kim, K.-S.; Kotov, N. A. J. Phys. Chem. C 2008, 112, 370-377 10.1021/jp075112s
80. Qu, L.; Yu, W. W.; Peng, X. Nano Lett. 2004, 4, 465-469 10.1021/nl035211r
81. Mondloch, J. E.; Finke, R. G. J. Am. Chem. Soc. 2011, 133, 7744-7756 10.1021/ja110550h
82. Guo, S.; Fang, G.; Li, G.; Ma, H.; Fan, H.; Yu, L.; Ma, C.; Wu, X.; Deng, D.; Wei, M.; Tan, D.; Si, R.; Zhang, S.; Li, J.; Sun, L.; Tang, Z.; Pan, X.; Bao, X. Science 2014, 344, 616-619 10.1126/science.1253150
83. Lin, Y.; Finke, R. G. J. Am. Chem. Soc. 1994, 116, 8335-8353 10.1021/ja00097a047
84. Özkar, S.; Finke, R. G. J. Am. Chem. Soc. 2002, 124, 5796-5810 10.1021/ja012749v
85. Özkar, S.; Finke, R. G. Langmuir 2002, 18, 7653-7662 10.1021/la020225i
86. nd Ed.; VCH; Weinheim, 1991.
87. Bhirud, V. A.; Uzun, A.; Kletnieks, P. W.; Craciun, R.; Haw, J. F.; Dixon, D. A.; Olmstead, M. M.; Gates, B. C. J. Organomet. Chem. 2007, 692, 2107-2113 10.1016/j.jorganchem.2007.01.008
88. Jentoft, M.; Deutsch, S. E.; Gates, B. C. Rev. Sci. Instrum. 1996, 67, 2111-2113 10.1063/1.1147023
89. Newville, M.; Ravel, B.; Haskel, D.; Rehr, J. J.; Stern, E. A.; Yacoby, Y. Phys. B 1995, 208/209, 154-156 10.1016/0921-4526(94)00655-F
90. Newville, M. J. Synchrotron Radiat. 2001, 8, 96-100 10.1107/S0909049500016290
91. Vaarkamp, M.; Linders, J. C.; Koningsberger, D. C. Phys. B 1995, 209, 159-160 10.1016/0921-4526(94)00658-I
92. Koningsberger, D. C.; Mojet, B. L.; van Dorssen, G. E.; Ramaker, D. E. Top. Catal. 2000, 10, 143-155 10.1023/A:1019105310221
93. Zabinsky, S. E.; Rehr, J. J.; Ankudinov, A.; Albers, R. C.; Eller, M. J. Phys. Rev. B: Condens. Matter Mater. Phys. 1995, 52, 2995-3009 10.1103/PhysRevB.52.2995
94. Pearson, W. B.; Calvert, L. D.; Villars, P. Pearson's Handbook of Crystallographic Data for Intermetallic Phases; American Society for Metals: Metals Park, OH, 1985.
95. Lytle, F. W.; Sayers, D. E.; Stern, E. A. Physica B 1989, 158, 701-722 10.1016/0921-4526(89)90447-X