Gold nanocluster agglomeration kinetic studies: Evidence for parallel bimolecular plus autocatalytic agglomeration pathways as a mechanism-based alternative to an Avrami-based analysis

Chemistry of Materials

Volumn 24, Issue 10, 2012, Pages 1718-1725

  Finney, Eric E ^a,b   Shields, Shawn P ^a,b   Buhro, William E ^a,b   Finke, Richard G ^a,b  

^a WASHINGTON UNIVERSITY   (United States)

^b Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

2 and 4 step mechanisms of nanocluster nucleation; autocatalytic agglomeration; autocatalytic growth and agglomeration; bimolecular agglomeration; mechanism based nanocluster size vs time equation; mechanism based substitute for Avrami equation analyses

Indexed keywords

AGGLOMERATION KINETICS; AGGLOMERATION RATE; AUTOCATALYTIC; AVRAMI EQUATIONS; BIMOLECULAR RATE CONSTANTS; CHEMICAL EQUATIONS; CURVE-FIT; DATA SETS; DIPHENYLMETHANE; DOUBLE LAYERS; GOLD NANOCLUSTER; MECHANISM-BASED NANOCLUSTER SIZE VS TIME EQUATION; NANOCLUSTER NUCLEATION; NANOPARTICLE SIZES; RATE CONSTANT K; SEMI-EMPIRICAL; TETRAOCTYLAMMONIUM BROMIDE;

AGGLOMERATION; BROMINE COMPOUNDS; GOLD; IRIDIUM; NANOCLUSTERS; NANOPARTICLES; PLATINUM;

RATE CONSTANTS;

EID: 84861398927     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm203186y     Document Type: Article

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