Interligand interactions dictate the regioselectivity of trans-hydrometalations and related reactions catalyzed by [Cp∗RuCl]. Hydrogen bonding to a chloride ligand as a steering principle in catalysis

Journal of the American Chemical Society

Volumn 137, Issue 16, 2015, Pages 5506-5519

  Rummelt, Stephan M ^a   Radkowski, Karin ^a   Roşca, Dragoş Adrian ^a   Fürstner, Alois ^a  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; CHEMICAL BONDS; CHLORINE; FUNCTIONAL GROUPS; GERMANIUM; HYDROCARBONS; HYDROGEN; HYDROGEN BONDS; ORGANOMETALLICS; REGIOSELECTIVITY; RUBIDIUM COMPOUNDS; RUTHENIUM; RUTHENIUM COMPOUNDS;

CHLORIDE LIGANDS; COORDINATION SPHERE; HIGH SELECTIVITY; INTERNAL ALKYNES; ORGANOMETALLIC CHEMISTRY; REACTIVE INTERMEDIATE; SECONDARY INTERACTIONS; SIGMA COMPLEXES;

CHLORINE COMPOUNDS;

ACETYLENE DERIVATIVE; ALKYNE DERIVATIVE; CHLORIDE; FUNCTIONAL GROUP; HYDROGEN; RUTHENIUM COMPLEX;

ACIDITY; ADDITION REACTION; ARTICLE; CATALYSIS; CATALYST; COMPLEX FORMATION; CONTROLLED STUDY; CRYSTAL STRUCTURE; CYCLOADDITION; HYDROGEN BOND; HYDROSILYLATION; MOLECULAR INTERACTION; POLARIZATION; SILYLATION; SOLID STATE; SOLUBILITY; STEREOCHEMISTRY; X RAY;

EID: 84928727743     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b01475     Document Type: Article

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