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Volumn 28, Issue 9, 2009, Pages 2655-2657

Steric and electronic effects in half-sandwich ruthenium silane #-complexes with Si#H and Si#Cl interligand interactions

Author keywords

[No Author keywords available]

Indexed keywords

CHLOROSILANES; ELECTRONIC EFFECTS; HALF-SANDWICH;

EID: 66149092638     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om801192b     Document Type: Article
Times cited : (21)

References (47)
  • 1
    • 33645912614 scopus 로고    scopus 로고
    • For recent discussions of nonclassical Si, H interligand interactions, see
    • For recent discussions of nonclassical Si. .H interligand interactions, see: Nikonov, G. I. Adv. Organomet. Chem. 2005, 53, 217-309.
    • (2005) Adv. Organomet. Chem , vol.53 , pp. 217-309
    • Nikonov, G.I.1
  • 4
    • 0003471615 scopus 로고    scopus 로고
    • For a more general discussion of nonclassical interligand bonding see:, Kluwer Academic/Plenum: New York;
    • For a more general discussion of nonclassical interligand bonding see: Kubas, G. J. Metal Dihydrogen and s-Bond Complexes; Kluwer Academic/Plenum: New York; 2001.
    • (2001) Metal Dihydrogen and s-Bond Complexes
    • Kubas, G.J.1
  • 6
    • 0037250334 scopus 로고    scopus 로고
    • Only in a few cases were silane σ-complexes established as precursors or intermediates in hydrosilylation. See, for instance: Lachaize, S, Sabo-Etienne, S, Donnadieu, B, Chadret, B. Chem. Commun. 2003, 214
    • Only in a few cases were silane σ-complexes established as precursors or intermediates in hydrosilylation. See, for instance: Lachaize, S.; Sabo-Etienne, S.; Donnadieu, B.; Chadret, B. Chem. Commun. 2003, 214.
  • 8
    • 31444433512 scopus 로고    scopus 로고
    • 3-coordination has been reported recently: Thomas, C. M.; Peters, J. C. Angew. Chem., Int. Ed. 2006, 45, 776-780.
    • 3-coordination has been reported recently: Thomas, C. M.; Peters, J. C. Angew. Chem., Int. Ed. 2006, 45, 776-780.
  • 13
    • 3042628833 scopus 로고    scopus 로고
    • 2-dihydrogen ligands and other ligands (hydrides, halides, etc.) are well-known: Barrio, P.; Esteruelas, M. A.; Lledòs, A.; Oñate, E.; Tomàs, J. Organometallics 2004, 23, 3008.
    • 2-dihydrogen ligands and other ligands (hydrides, halides, etc.) are well-known: Barrio, P.; Esteruelas, M. A.; Lledòs, A.; Oñate, E.; Tomàs, J. Organometallics 2004, 23, 3008.
  • 32
    • 66149114898 scopus 로고    scopus 로고
    • 3).
    • 3).
  • 35
    • 0006457269 scopus 로고    scopus 로고
    • With smaller phosphines, such as R3P, MeiPr 2P, the monomer exists in an equilibrium with a chloride-bridged dimer: Tenorio, M. J, Puerta, M. C, Valerga, P. J. Organomet. Chem. 2000, 609, 161
    • 2P, the monomer exists in an equilibrium with a chloride-bridged dimer: Tenorio, M. J.; Puerta, M. C.; Valerga, P. J. Organomet. Chem. 2000, 609, 161.
  • 36
    • 0038651046 scopus 로고    scopus 로고
    • n is formed: Braun, T.; Münch, G.; Windmüller, B.; Gevert, O.; Laubender, M.; Werner, H. Chem. Eur. J. 2003, 9, 2516.
    • n is formed: Braun, T.; Münch, G.; Windmüller, B.; Gevert, O.; Laubender, M.; Werner, H. Chem. Eur. J. 2003, 9, 2516.
  • 40
    • 0000116492 scopus 로고    scopus 로고
    • Other silane complexes of Ru: Yin, J.; Klosin, J.; Abboud, K. A.; Jones, W. M. J. Am. Chem. Soc. 1995, 117, 3298.
    • Other silane complexes of Ru: Yin, J.; Klosin, J.; Abboud, K. A.; Jones, W. M. J. Am. Chem. Soc. 1995, 117, 3298.
  • 43
    • 66149153150 scopus 로고    scopus 로고
    • In the case of 4d, the diastereotopic SiH2 protons, observed at 5.78 and 5.26 ppm, are integrated as one proton each and are coupled to the hydride at-10.30 ppm, thus ruling out the alternative formulation of 4das the dihydride Cp(Pri 3P)RuH 2SiClHPh. See the Supporting Information for further details
    • 2SiClHPh. See the Supporting Information for further details.
  • 47
    • 66149106385 scopus 로고    scopus 로고
    • The M-Si bond length is the most sensitive indicator of the extent of Si-H oxidative addition to metal.1a
    • 1a


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.