-
1
-
-
33645912614
-
-
For recent discussions of nonclassical Si, H interligand interactions, see
-
For recent discussions of nonclassical Si. .H interligand interactions, see: Nikonov, G. I. Adv. Organomet. Chem. 2005, 53, 217-309.
-
(2005)
Adv. Organomet. Chem
, vol.53
, pp. 217-309
-
-
Nikonov, G.I.1
-
4
-
-
0003471615
-
-
For a more general discussion of nonclassical interligand bonding see:, Kluwer Academic/Plenum: New York;
-
For a more general discussion of nonclassical interligand bonding see: Kubas, G. J. Metal Dihydrogen and s-Bond Complexes; Kluwer Academic/Plenum: New York; 2001.
-
(2001)
Metal Dihydrogen and s-Bond Complexes
-
-
Kubas, G.J.1
-
6
-
-
0037250334
-
-
Only in a few cases were silane σ-complexes established as precursors or intermediates in hydrosilylation. See, for instance: Lachaize, S, Sabo-Etienne, S, Donnadieu, B, Chadret, B. Chem. Commun. 2003, 214
-
Only in a few cases were silane σ-complexes established as precursors or intermediates in hydrosilylation. See, for instance: Lachaize, S.; Sabo-Etienne, S.; Donnadieu, B.; Chadret, B. Chem. Commun. 2003, 214.
-
-
-
-
7
-
-
67749133709
-
-
Yang, J.; White, P. S.; Brookhart, M. J. Am. Chem. Soc. 2008, 130, 17509.
-
(2008)
J. Am. Chem. Soc
, vol.130
, pp. 17509
-
-
Yang, J.1
White, P.S.2
Brookhart, M.3
-
8
-
-
31444433512
-
-
3-coordination has been reported recently: Thomas, C. M.; Peters, J. C. Angew. Chem., Int. Ed. 2006, 45, 776-780.
-
3-coordination has been reported recently: Thomas, C. M.; Peters, J. C. Angew. Chem., Int. Ed. 2006, 45, 776-780.
-
-
-
-
9
-
-
0034647243
-
-
Atheaux, I.; Donnadieu, B.; Daran, J.-C.; Sabo-Etienne, S.; Chaudret, B.; Hussein, K.; Barthelat, J.-C. J. Am. Chem. Soc. 2000, 122, 5664-5665.
-
(2000)
J. Am. Chem. Soc
, vol.122
, pp. 5664-5665
-
-
Atheaux, I.1
Donnadieu, B.2
Daran, J.-C.3
Sabo-Etienne, S.4
Chaudret, B.5
Hussein, K.6
Barthelat, J.-C.7
-
11
-
-
34547487884
-
-
Lachaize, S.; Caballero, A.; Vendier, L.; Sabo-Etienne, S. Organometallics 2007, 26, 3713-3721.
-
(2007)
Organometallics
, vol.26
, pp. 3713-3721
-
-
Lachaize, S.1
Caballero, A.2
Vendier, L.3
Sabo-Etienne, S.4
-
12
-
-
34250809604
-
-
Perutz, R.; Sabo-Etienne, S. Angew. Chem., Int. Ed. 2007, 46, 2578-2592.
-
(2007)
Angew. Chem., Int. Ed
, vol.46
, pp. 2578-2592
-
-
Perutz, R.1
Sabo-Etienne, S.2
-
13
-
-
3042628833
-
-
2-dihydrogen ligands and other ligands (hydrides, halides, etc.) are well-known: Barrio, P.; Esteruelas, M. A.; Lledòs, A.; Oñate, E.; Tomàs, J. Organometallics 2004, 23, 3008.
-
2-dihydrogen ligands and other ligands (hydrides, halides, etc.) are well-known: Barrio, P.; Esteruelas, M. A.; Lledòs, A.; Oñate, E.; Tomàs, J. Organometallics 2004, 23, 3008.
-
-
-
-
14
-
-
0040070427
-
-
Van der Sluys, L. S.; Eckert, J.; Eisenstein, O.; Hall, J. H.; Huffman, J. C.; Jackson, S. A.; Koetzle, T. F.; Kubas, G. J.; Vergamini, P. J.; Caulton, K. G. J. Am. Chem. Soc. 1990, 113, 4831.
-
(1990)
J. Am. Chem. Soc
, vol.113
, pp. 4831
-
-
Van der Sluys, L.S.1
Eckert, J.2
Eisenstein, O.3
Hall, J.H.4
Huffman, J.C.5
Jackson, S.A.6
Koetzle, T.F.7
Kubas, G.J.8
Vergamini, P.J.9
Caulton, K.G.10
-
15
-
-
22544480537
-
-
Osipov, A. L.; Vyboishchikov, S. F.; Dorogov, K. Y.; Kuzmina, L. G.; Howard, J. A. K.; Lemenovskii, D. A.; Nikonov, G. I. Chem. Commun. 2005, 3349.
-
(2005)
Chem. Commun
, pp. 3349
-
-
Osipov, A.L.1
Vyboishchikov, S.F.2
Dorogov, K.Y.3
Kuzmina, L.G.4
Howard, J.A.K.5
Lemenovskii, D.A.6
Nikonov, G.I.7
-
16
-
-
34250660011
-
-
Deglmann, P.; Ember, E.; Hofmann, P.; Pitter, S.; Walter, O. Chem. Eur. J. 2007, 13, 2864.
-
(2007)
Chem. Eur. J
, vol.13
, pp. 2864
-
-
Deglmann, P.1
Ember, E.2
Hofmann, P.3
Pitter, S.4
Walter, O.5
-
17
-
-
14544290512
-
-
Osipov, A. L.; Gerdov, S. M.; Kuzmina, L. G.; Howard, J. A. K.; Nikonov, G. I. Organometallics 2005, 24, 587.
-
(2005)
Organometallics
, vol.24
, pp. 587
-
-
Osipov, A.L.1
Gerdov, S.M.2
Kuzmina, L.G.3
Howard, J.A.K.4
Nikonov, G.I.5
-
18
-
-
0033835035
-
-
Duckett, S. B.; Kuzmina, L. G.; Nikonov, G. I. Inorg. Chem. Commun. 2000, 3/3, 126.
-
(2000)
Inorg. Chem. Commun
, vol.3
, Issue.3
, pp. 126
-
-
Duckett, S.B.1
Kuzmina, L.G.2
Nikonov, G.I.3
-
19
-
-
66149094755
-
-
Gutsulyak, D. V.; Osipov, A. L.; Kuzmina, L. G.; Howard, J. A. K.; Vyboishchikov, S. F.; Nikonov, G. I. Dalton Trans. 2008, 6843.
-
(2008)
Dalton Trans
, pp. 6843
-
-
Gutsulyak, D.V.1
Osipov, A.L.2
Kuzmina, L.G.3
Howard, J.A.K.4
Vyboishchikov, S.F.5
Nikonov, G.I.6
-
21
-
-
0002217755
-
-
Bakhmutov, V. I.; Howard, J. A. K.; Keen, D. A.; Kuzmina, L G.; Leech, M. A.; Nikonov, G. I.; Vorontsov, E. V.; Wilson, C. C. Dalton Trans. 2000, 1631.
-
(2000)
Dalton Trans
, pp. 1631
-
-
Bakhmutov, V.I.1
Howard, J.A.K.2
Keen, D.A.3
Kuzmina, L.G.4
Leech, M.A.5
Nikonov, G.I.6
Vorontsov, E.V.7
Wilson, C.C.8
-
22
-
-
0000609844
-
-
Nikonov, G. I.; Kuzmina, L. G.; Vyboishchikov, S. F.; Lemenovskii, D. A.; Howard, J. A. K. Chem. Eur. J. 1999, 5, 2497.
-
(1999)
Chem. Eur. J
, vol.5
, pp. 2497
-
-
Nikonov, G.I.1
Kuzmina, L.G.2
Vyboishchikov, S.F.3
Lemenovskii, D.A.4
Howard, J.A.K.5
-
23
-
-
2942733365
-
-
Dorogov, K. Yu.; Dumont, E.; Ho, N.-N.; Churakov, A. V.; Kuzmina, L. G.; Poblet, J.-M.; Schultz, A. J.; Howard, J. A. K.; Bau, R.; Lledos, A.; Nikonov, G. I. Organometallics 2004, 23, 2845.
-
(2004)
Organometallics
, vol.23
, pp. 2845
-
-
Dorogov, K.Y.1
Dumont, E.2
Ho, N.-N.3
Churakov, A.V.4
Kuzmina, L.G.5
Poblet, J.-M.6
Schultz, A.J.7
Howard, J.A.K.8
Bau, R.9
Lledos, A.10
Nikonov, G.I.11
-
24
-
-
7044286430
-
-
Ignatov, S. K.; Rees, N. H.; Tyrrell, B. R.; Dubberley, S. R.; Razuvaev, A. G.; Mountford, P.; Nikonov, G. I. Chem. Eur. J. 2004, 10, 4991.
-
(2004)
Chem. Eur. J
, vol.10
, pp. 4991
-
-
Ignatov, S.K.1
Rees, N.H.2
Tyrrell, B.R.3
Dubberley, S.R.4
Razuvaev, A.G.5
Mountford, P.6
Nikonov, G.I.7
-
25
-
-
0037460135
-
-
Dubberley, S. R.; Ignatov, S. K.; Rees, N. H.; Razuvaev, A. G.; Mountford, P.; Nikonov, G. I. J. Am. Chem. Soc. 2003, 125, 644.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 644
-
-
Dubberley, S.R.1
Ignatov, S.K.2
Rees, N.H.3
Razuvaev, A.G.4
Mountford, P.5
Nikonov, G.I.6
-
26
-
-
2442491642
-
-
Nikonov, G. I.; Mountford, P.; Dubberley, S. R. Inorg. Chem. 2003, 42, 58.
-
(2003)
Inorg. Chem
, vol.42
, pp. 58
-
-
Nikonov, G.I.1
Mountford, P.2
Dubberley, S.R.3
-
27
-
-
0034740906
-
-
Nikonov, G. I.; Mountford, P.; Ignatov, S. K.; Green, J. C.; Cooke, P. A.; Leech, M. A.; Kuzmina, L. G.; Razuvaev, A. G.; Rees, N. H.; Blake, A. J.; Howard, J. A. K.; Lemenovskii, D. A. Dalton Trans. 2001, 2903.
-
(2001)
Dalton Trans
, pp. 2903
-
-
Nikonov, G.I.1
Mountford, P.2
Ignatov, S.K.3
Green, J.C.4
Cooke, P.A.5
Leech, M.A.6
Kuzmina, L.G.7
Razuvaev, A.G.8
Rees, N.H.9
Blake, A.J.10
Howard, J.A.K.11
Lemenovskii, D.A.12
-
28
-
-
38049155480
-
-
Ignatov, S. K.; Merkoulov, A. A.; Dubberley, S. R.; Cowley, A. R.; Rees, N. H.; Razuvaev, A. G.; Mountford, P.; Nikonov, G. I. Chem. Eur. J. 2008, 14, 296.
-
(2008)
Chem. Eur. J
, vol.14
, pp. 296
-
-
Ignatov, S.K.1
Merkoulov, A.A.2
Dubberley, S.R.3
Cowley, A.R.4
Rees, N.H.5
Razuvaev, A.G.6
Mountford, P.7
Nikonov, G.I.8
-
31
-
-
41149146497
-
-
Gutsulyak, D. V.; Guzmina, L. G.; Howard, J. A. K.; Vyboishchikov, S. F.; Nikonov, G. I. J. Am. Chem. Soc. 2008, 130, 3732.
-
(2008)
J. Am. Chem. Soc
, vol.130
, pp. 3732
-
-
Gutsulyak, D.V.1
Guzmina, L.G.2
Howard, J.A.K.3
Vyboishchikov, S.F.4
Nikonov, G.I.5
-
32
-
-
66149114898
-
-
3).
-
3).
-
-
-
-
34
-
-
33751154664
-
-
PR, PPhPr
-
2).
-
(1995)
Inorg. Chem
, vol.34
, pp. 488
-
-
Johnson, T.J.1
Foltig, K.2
Streib, W.E.3
Martin, J.D.4
Huffman, J.C.5
Jackson, S.A.6
Eisenstein, O.7
Caulton, K.G.8
-
35
-
-
0006457269
-
-
With smaller phosphines, such as R3P, MeiPr 2P, the monomer exists in an equilibrium with a chloride-bridged dimer: Tenorio, M. J, Puerta, M. C, Valerga, P. J. Organomet. Chem. 2000, 609, 161
-
2P, the monomer exists in an equilibrium with a chloride-bridged dimer: Tenorio, M. J.; Puerta, M. C.; Valerga, P. J. Organomet. Chem. 2000, 609, 161.
-
-
-
-
36
-
-
0038651046
-
-
n is formed: Braun, T.; Münch, G.; Windmüller, B.; Gevert, O.; Laubender, M.; Werner, H. Chem. Eur. J. 2003, 9, 2516.
-
n is formed: Braun, T.; Münch, G.; Windmüller, B.; Gevert, O.; Laubender, M.; Werner, H. Chem. Eur. J. 2003, 9, 2516.
-
-
-
-
38
-
-
0001194256
-
-
For similar cationic diamine complexes, see
-
For similar cationic diamine complexes, see: Gemel, C.; Sapunov, V. N.; Mereiter, K.; Ferencic, M.; Schmid, R.; Kirchner, K. Inorg. Chim. Acta 1999, 286, 114.
-
(1999)
Inorg. Chim. Acta
, vol.286
, pp. 114
-
-
Gemel, C.1
Sapunov, V.N.2
Mereiter, K.3
Ferencic, M.4
Schmid, R.5
Kirchner, K.6
-
39
-
-
20544451120
-
-
Rankin, M. A.; McDonald, R.; Ferguson, M. J.; Stradiotto, M. Angew. Chem., Int. Ed. 2005, 44, 3603.
-
(2005)
Angew. Chem., Int. Ed
, vol.44
, pp. 3603
-
-
Rankin, M.A.1
McDonald, R.2
Ferguson, M.J.3
Stradiotto, M.4
-
40
-
-
0000116492
-
-
Other silane complexes of Ru: Yin, J.; Klosin, J.; Abboud, K. A.; Jones, W. M. J. Am. Chem. Soc. 1995, 117, 3298.
-
Other silane complexes of Ru: Yin, J.; Klosin, J.; Abboud, K. A.; Jones, W. M. J. Am. Chem. Soc. 1995, 117, 3298.
-
-
-
-
41
-
-
0037899267
-
-
Freeman, S. T. N.; Lemke, F. R.; Brammer, L. Organometallics 2002, 21, 2030.
-
(2002)
Organometallics
, vol.21
, pp. 2030
-
-
Freeman, S.T.N.1
Lemke, F.R.2
Brammer, L.3
-
43
-
-
66149153150
-
-
In the case of 4d, the diastereotopic SiH2 protons, observed at 5.78 and 5.26 ppm, are integrated as one proton each and are coupled to the hydride at-10.30 ppm, thus ruling out the alternative formulation of 4das the dihydride Cp(Pri 3P)RuH 2SiClHPh. See the Supporting Information for further details
-
2SiClHPh. See the Supporting Information for further details.
-
-
-
-
46
-
-
2442486429
-
-
Ignatov, S. K.; Dubberley, S. R.; Rees, N. H.; Razuvaev, A. G.; Mountford, P.; Nikonov, G. I. Chem. Commun. 2004, 952.
-
(2004)
Chem. Commun
, pp. 952
-
-
Ignatov, S.K.1
Dubberley, S.R.2
Rees, N.H.3
Razuvaev, A.G.4
Mountford, P.5
Nikonov, G.I.6
-
47
-
-
66149106385
-
-
The M-Si bond length is the most sensitive indicator of the extent of Si-H oxidative addition to metal.1a
-
1a
-
-
-
|