Enantioselective Synthesis of exo -4-Nitroprolinates from Nitroalkenes and Azomethine Ylides Catalyzed by Chiral Phosphoramidite·Silver(I) or Copper(II) Complexes

Synthesis (Germany)

Volumn 47, Issue 7, 2015, Pages 934-943

  Castelló, Luis M ^a   Nájera, Carmen ^a   Sansano, José M ^a   Larrañaga, Olatz ^b   De Cózar, Abel ^b,c   Cossío, Fernando P ^b,c  

^a UNIVERSITY OF ALICANTE   (Spain)

^b UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^c BASQUE FOUNDATION FOR SCIENCE   (Spain)

Author keywords

asymmetric catalysis; azomethine ylides; copper; dipolar cycloaddition; phosphoramidite; silver

Indexed keywords

AMINO ACIDS; CATALYSIS; CATALYSTS; COPPER; CYCLOADDITION; ENANTIOSELECTIVITY; SYNTHESIS (CHEMICAL);

1 ,3-DIPOLARCYCLOADDITION; ASYMMETRIC CATALYSIS; AZOMETHINE YLIDES; DIASTEREO-SELECTIVITY; DIPOLAR CYCLOADDITIONS; ENANTIOSELECTIVE SYNTHESIS; HIGH ENANTIOSELECTIVITY; PHOSPHORAMIDITES;

SILVER;

ALKENE DERIVATIVE; AZOMETHINE YLIDE; COPPER ION; EXO 4 NITROPROLINATE DERIVATIVE; IMINE; ISOPROPYL 4 NITRO 3,5 DIPHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 2 BENZYL 4 NITRO 3,5 DIPHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 2 ISOBUTYL 4 NITRO 3,5 DIPHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 2 METHYL 4 NITRO 3,5 DIPHENYLPIRROLIDINE 2 CARBOXYLATE; METHYL 3 (2 BROMOPHENYL) 4 NITRO 5 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 3 (3 BROMOPHENYL) 4 NITRO 5 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 3 (4 BROMOPHENYL) 4 NITRO 5 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 3 (4 FLUOROPHENYL) 4 NITRO 5 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 3 (FURAN 2 YL) 4 NITRO 5 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 3 CYCLOHEXYL 4 NITRO 5 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 4 NITRO 3 PHENYL 5 (2 TOLYL)PYRROLIDINE 2 CARBOXYLATE; METHYL 4 NITRO 3 PHENYL 5 (3 TOLYL)PYRROLIDINE 2 CARBOXYLATE; METHYL 4 NITRO 3 PHENYL 5 (4 TOLYL)PYRROLIDINE 2 CARBOXYLATE; METHYL 4 NITRO 3,5 DIPHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 4 NITRO 5 PHENYL 3 (4 TOLYL)PYRROLIDINE 2 CARBOXYLATE; METHYL 5 (4 BROMOPHENYL) 4 NITRO 3 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 5 (4 FLUOROPHENYL) 4 NITRO 3 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 5 (4 METHOXYPHENYL) 4 NITRO 3 PHENYLPYRROLIDINE 2 CARBOXYLATE; METHYL 5 (NAPHTH 2 YL) 4 NITRO 3 PHENYLPYRROLIDINE 2 CARBOXYLATE; NITROALKENE DERIVATIVE; PHOSPHORAMIDOUS ACID; SILVER; UNCLASSIFIED DRUG;

1,3 DIPOLAR CYCLOADDITION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; COMPLEX FORMATION; CYCLOADDITION; DIASTEREOSELECTIVITY; ENANTIOSELECTIVITY; INFRARED SPECTROSCOPY; MASS SPECTROMETRY; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE; SENSITIVITY ANALYSIS; STEREOCHEMISTRY; STRUCTURE ACTIVITY RELATION; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 84925250300     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0034-1380158     Document Type: Article

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