메뉴 건너뛰기




Volumn 357, Issue 1, 2015, Pages 177-184

Selective aryl α-diimine/palladium-catalyzed bis-alkoxycarbonylation of olefins for the synthesis of substituted succinic diesters

Author keywords

Alkenes; Aryl diimine ligands; Carbonylation; Oxidative carbonylation; Palladium; Succinic acid esters

Indexed keywords


EID: 84920736192     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201400501     Document Type: Article
Times cited : (21)

References (61)
  • 55
    • 84920736907 scopus 로고    scopus 로고
    • note
    • b) Other quinones were tested but only benzoquinone was able to function as oxidant.
  • 56
    • 84920736906 scopus 로고    scopus 로고
    • note
    • 2, were not active in the bis-alkoxycarbonylation of the styrene, see Table S2 in the Supporting Information.
  • 57
    • 84920736905 scopus 로고    scopus 로고
    • note
    • Isoprene and 4-vinylcyclohexene monoxide were also tested in the bis-alkoxycarbonylation of styrene. Although conversions of 90% and 20% were achieved, respectively (with 2 mol% of catalyst loading), in both cases complex mixtures of products were attained.
  • 58
    • 84920736904 scopus 로고    scopus 로고
    • note
    • Using the more sterically hindered t-BuOH as nucleophile the reaction was much slower, even with 2 mol% of catalyst loading. A conversion of 40% of 2a was attained leading to the 4,4′-1,4-phenylene 1-tert-butyl bis(2-phenylsuccinate) in 35% isolated yield.
  • 61
    • 84920736903 scopus 로고    scopus 로고
    • note
    • 2. Unfortunately the addition of methanol produced an immediate decomposition of the complex to palladium black.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.