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ed. by M. Beller, Springer. Berlin
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0025959704
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Related bis(alkoxycarbonylation); Y. Tamaru, M. Hojo, Z. Yoshida, J. Org. Chem. 1991. 56, 1099;
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Related bis(alkoxycarbonylation); Y. Tamaru, M. Hojo, Z. Yoshida, J. Org. Chem. 1991. 56, 1099;
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16
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0037067563
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0001654443
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a) Y. Ukaji. M. Miyamoto, M. Mikuni, S. Takeuchi, K. Inomata, Bull. Chem. Soc. Jpn. 1996, 69. 735.
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Ukaji, Y.1
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0034861554
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b) S. Takeuchi, Y. Ukaji, K. Inomata, Bull. Chem. Soc. Jpn. 2001, 74, 955.
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19
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84858493814
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1-2 5.12 Hz for 2f (cis) with 8.54 Hz for trans isomer.
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1-2 5.12 Hz for 2f (cis) with 8.54 Hz for trans isomer.
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20
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84858494076
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The representative procedure for If (Entry II, Under an Ar atmosphere, CuOTf(C6H6)0.5 (186 mg. 0.74 mmol) was placed in a flask and a MeOH (6 mL) solution of If (235 mg, 1.47 mmol) and a THF (6 mL) solution of 3 (19 mg, 0.059 mmol) was added. To the mixture. PdCl2 (5.32 mg, 0.030 mmol) was added. The Ar atmosphere was replaced with CO/O2 (ca. 1/1, v/v) and the reaction mixture was stirred for 2d at 60°C. A saturated aqueous solution of NaHCO3 was added and the insoluble substance was filtered off. After the filtrate was extracted with ethyl acetate, the extracts were washed with water and brine, dried over Na2SO4, and condensed in vacuo. The residue was purified by column chromatography and further recycle HPLC to give 2f 245 mg. 60, 92% ee
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4), and condensed in vacuo. The residue was purified by column chromatography and further recycle HPLC to give 2f (245 mg. 60%. 92% ee).
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21
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33244484834
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3-character of benzylic Pd species. A. M. Johns, M. Utsunomiya, C. D. Incarvito, J. F. Hartwig, J. Am. Chem. Soc. 2006, 128, 1828.
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3-character of benzylic Pd species. A. M. Johns, M. Utsunomiya, C. D. Incarvito, J. F. Hartwig, J. Am. Chem. Soc. 2006, 128, 1828.
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22
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0034692176
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M. D. Meyer. R. J. Altenbach, F. Z. Basha, W. A. Carroll, S. Condon, S. W. Elmore, J. F. Kerwin, Jr., K. B. Sippy, K. Tietje, M. D. Wendt, A. A. Hancock, M. E. Brune, S. A. Buckner, I. Drizin, J Med. Chem. 2000, 43, 1586.
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J Med. Chem
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Meyer, M.D.1
Altenbach, R.J.2
Basha, F.Z.3
Carroll, W.A.4
Condon, S.5
Elmore, S.W.6
Kerwin Jr., J.F.7
Sippy, K.B.8
Tietje, K.9
Wendt, M.D.10
Hancock, A.A.11
Brune, M.E.12
Buckner, S.A.13
Drizin, I.14
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23
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36849053962
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The combined substrates obtained from experiments of Entries 10 and 11 in Table 1 were used.
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The combined substrates obtained from experiments of Entries 10 and 11 in Table 1 were used.
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