Silver(I)-mediated C-H amination of 2-alkenylanilines: Unique solvent-dependent migratory aptitude

Advanced Synthesis and Catalysis

Volumn 357, Issue 1, 2015, Pages 227-234

  Youn, So Won ^a   Ko, Tae Yun ^a   Jang, Min Jung ^a   Jang, Su San ^a  

^a Hanyang University   (South Korea)

Author keywords

Cyclization; Indoles; Migration; Oxidation; Silver

Indexed keywords

EID: 84920717918     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201400759     Document Type: Review

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73. 3 in substrate 5). Another conceivable mechanism involves the initial activation of alkene by coordination to Ag(I) (G) which is followed by nucleophilic attack by either sulfonamide (path f) or ipso carbon of arene.