Direct, catalytic monofluorination of sp3 c-h bonds: A radical-based mechanism with ionic selectivity

Journal of the American Chemical Society

Volumn 136, Issue 27, 2014, Pages 9780-9791

  Pitts, Cody Ross ^a   Bloom, Steven ^a   Woltornist, Ryan ^a   Auvenshine, Dillon Jay ^a   Ryzhkov, Lev R ^b   Siegler, Maxime A ^a   Lectka, Thomas ^a  

^a JOHNS HOPKINS UNIVERSITY   (United States)

^b TOWSON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MECHANISMS;

C-H BOND; COMPUTATIONAL STUDIES; DETAILED REACTION MECHANISMS; IONIC CHARACTER; RADICAL CHAIN MECHANISMS; RADICAL-BASED MECHANISMS; SELECTFLUOR; TRANSITION STATE;

COPPER;

CUPROUS ION; RADICAL;

ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL PROCEDURES; CHEMICAL REACTION KINETICS; ELECTROCHEMICAL ANALYSIS; ELECTRON SPIN RESONANCE; FLUORINATION; HYDROGEN BOND; MATHEMATICAL ANALYSIS; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; ULTRAVIOLET RADIATION;

EID: 84904015912     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja505136j     Document Type: Article

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